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1.发明授权公开(公告)号：US08918226B2
公开(公告)日：2014-12-23
申请号：US13055973
申请日：2009-07-28
CPC分类号： G01B21/085 , B29C55/06 , B29C55/08 , G01D3/0365 , G01K1/20 , G01K13/06
摘要： A temperature measuring method accurately measures a sheet-like object even when the sheet-like object has an uneven temperature distribution throughout. In this method, temperature measurement is conducted in a measuring area where the sheet-like object is to be measured for its physical quantity or in the vicinity of the measuring area during determination of the physical quantity by a physical quantity measuring device. One or more temperature sensors are located at a position proximal to each sheet-like object that streams in a predetermined direction relative to the temperature sensors, and air is jetted out toward the sheet-like object for creating an air curtain that surrounds each temperature sensor so that a gauge workspace substantially confining the atmosphere therein is defined over one or both of the opposite surfaces of the sheet-like object. The temperature sensors detect the temperature in the measuring area or its vicinity within the gauge workspace.
摘要翻译： 即使片状物体的温度分布不均匀，也可以精确地测量片状物体。 在该方法中，在通过物理量测量装置确定物理量期间，在要测量片状物体的物理量的测量区域或测量区域附近进行温度测量。 一个或多个温度传感器位于靠近每个片状物体的位置，其相对于温度传感器沿预定方向流动，并且向片状物体喷射空气以形成围绕每个温度传感器的气帘 使得基本上限制其中的气氛的测量工作空间被限定在片状物体的相对表面的一个或两个上。 温度传感器检测测量工作区内测量区域或其附近的温度。
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2.发明申请公开(公告)号：US20120052412A1
公开(公告)日：2012-03-01
申请号：US13213413
申请日：2011-08-19
申请人： Yoshitaka YAMAKAWA , Toshiaki KADOTA , Takuya MURAKAMI , Yuuji TSUNODA , Masaru IGUCHI , Kaoru FUKUDA
发明人： Yoshitaka YAMAKAWA , Toshiaki KADOTA , Takuya MURAKAMI , Yuuji TSUNODA , Masaru IGUCHI , Kaoru FUKUDA
CPC分类号： H01M8/1023 , C08G65/4006 , C08G75/23 , H01M2300/0082
摘要： A polyarylene copolymer having a sulfonic acid group which has high proton conductivity and reduced swelling in hot water and reduced shrinkage in drying; a solid polymer electrolyte and a proton conductive membrane comprising the copolymer; and a membrane-electrode assembly using these.The polyarylene block copolymer comprises a polymer segment (A) having a sulfonic acid group, and a polymer segment (B) having substantially no sulfonic acid group, the polymer segment (B) having substantially no sulfonic acid group comprising a structural unit represented by the following formula (1).
摘要翻译： 具有磺酸基的聚亚芳基共聚物，其具有高质子传导性，并且在热水中膨胀减少并且减少了干燥收缩; 固体聚合物电解质和包含所述共聚物的质子传导膜; 以及使用这些的膜 - 电极组件。 聚亚芳基嵌段共聚物包含具有磺酸基的聚合物链段（A）和基本上不具有磺酸基的聚合物链段（B），所述聚合物链段（B）基本上不含磺酸基，所述链段包含由 以下公式（1）。
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3.发明授权Polymer electrolyte, proton conductive membrane and membrane-electrode assembly 有权聚合物电解质，质子传导膜和膜 - 电极组件公开(公告)号：US07211203B2
公开(公告)日：2007-05-01
申请号：US10768151
申请日：2004-02-02
CPC分类号： H01M8/1004 , C08G65/48 , C08G73/10 , C08G75/23 , C08G2650/02 , C08G2650/40 , C08L71/00 , C08L81/06 , C25B13/08 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032
摘要： Disclosed are a polymer electrolyte having improved hot water resistance and radical resistance, a proton conductive membrane comprising the polymer electrolyte, and a membrane-electrode assembly including the proton conductive membrane.The polymer electrolyte comprises at least one polymer selected from polyether, polyketone, polyetherketone, polysulfone, polyethersulfone, polyimide, polyetherimide, polybenzimidazole, polybenzothiazole, polybenzoxazole and the like. The polymer comprises a repeating structural unit with either or both of an aromatic ring and a heterocyclic ring, and a repeating structural unit represented by the formula (1): wherein X is a single bond, an electron-withdrawing group or an electron-donating group; R is a single bond, —(CH2)q— or —(CF2)q— where q ranges from 1 to 10; m is from 0 to 10; k is from 0 to 5; l is from 0 to 4; and k+1≧1.
摘要翻译： 公开了具有改善的耐热水性和耐自由基性的聚合物电解质，包含聚合物电解质的质子传导膜和包括质子传导膜的膜 - 电极组件。 聚合物电解质包含至少一种选自聚醚，聚酮，聚醚酮，聚砜，聚醚砜，聚酰亚胺，聚醚酰亚胺，聚苯并咪唑，聚苯并噻唑，聚苯并恶唑等的聚合物。 聚合物包含具有芳环和杂环中的任一个或两者的重复结构单元和由式（1）表示的重复结构单元：其中X是单键，吸电子基团或给电子 组; R是单键， - （CH 2 CH 2）q - 或 - （CF 2 CH 2）q - 其中 q范围从1到10; m为0〜10; k为0〜5; l为0〜4; 和k + 1> = 1。
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公开(公告)号：US20060280991A1
公开(公告)日：2006-12-14
申请号：US11447002
申请日：2006-06-06
申请人： Nagayuki Kanaoka , Masaru Iguchi , Hiroshi Sohma
发明人： Nagayuki Kanaoka , Masaru Iguchi , Hiroshi Sohma
IPC分类号： H01M8/10
CPC分类号： C08J5/2256 , C08J2371/12 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032
摘要： A membrane-electrode assembly having superior hot water resistance has a membrane containing an aromatic polymer having a repeating unit expressed by general formula (1): in which A represents independently either —CO— or —SO2—; B represents independently an oxygen atom or sulfur atom; R1 to R8, which may be identical or different from each other, represent a hydrogen atom, fluorine atom, alkyl group, phenyl group or nitrile group; R9 to R24, which may be identical or different from each other, represent a hydrogen atom, alkyl group or phenyl group; and ‘a’ represents an integer of 0 to 4.
摘要翻译： 具有优异的耐热水性的膜 - 电极组件具有含有具有由通式（1）表示的重复单元的芳族聚合物的膜：其中A独立地表示-CO-或-SO 2 - ; B独立地表示氧原子或硫原子; R 1至R 8可以相同或不同，表示氢原子，氟原子，烷基，苯基或腈基; R 9〜R 24可以相同或不同，表示氢原子，烷基或苯基; 'a'表示0〜4的整数。
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公开(公告)号：US07125617B2
公开(公告)日：2006-10-24
申请号：US10460992
申请日：2003-06-13
申请人： Masaru Iguchi
发明人： Masaru Iguchi
CPC分类号： H01M8/103 , H01M8/04089 , H01M8/04238 , H01M8/086 , H01M8/1048
摘要： Before a phosphoric acid fuel cell generates electric energy, a cathode is supplied with a hydrogen gas (fuel gas) and air (oxygen-containing gas) to cause a reaction between hydrogen and oxygen. At this time, the hydrogen and the oxygen are caused to react with each other under a condition in which the concentration of phosphoric acid at the time the amount of water produced by the reaction (liquid water) for reducing the concentration of phosphoric acid and the amount of water evaporated from phosphoric acid are in equilibrium is equal to or greater than a reference phosphoric acid concentration which is capable of keeping the fuel cell at a desired performance level. The temperature of an electrolyte electrode assembly of the fuel cell is increased by the heat which is generated by the reaction.
摘要翻译： 在磷酸燃料电池产生电能之前，向阴极供给氢气（燃料气体）和空气（含氧气体）以引起氢和氧之间的反应。 此时，使氢和氧彼此反应，其中在通过用于降低磷酸浓度的反应产生的水（液态水）的时候的磷酸浓度和 从磷酸蒸发的水的平衡量等于或大于能够将燃料电池保持在期望的性能水平的参考磷酸浓度。 燃料电池的电解质电极组件的温度由反应产生的热量增加。
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公开(公告)号：US07030206B2
公开(公告)日：2006-04-18
申请号：US10804228
申请日：2004-03-19
CPC分类号： H01M10/052 , H01M4/926 , H01M8/0289 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M10/0565
摘要： To provide a sulfonic acid group-containing polymer having improved hot water resistance and radical resistance (durability), a solid polymer electrolyte including the polymer, and a proton-conducting membrane including the electrolyte, the polymer electrolyte includes a sulfonated product of a polymer shown by the following general formula (I): wherein X, Y, and Z are bonded randomly, alternately, or in blocks, y represents an integer of two or more, and each of x and z represents an integer of zero or more, where x+z>2.
摘要翻译： 为了提供具有改善的耐热水性和耐自由基性（耐久性）的含磺酸基聚合物，包含该聚合物的固体聚合物电解质和包含电解质的质子传导膜，聚合物电解质包括所示聚合物的磺化产物 通过以下通式（I）表示：其中X，Y和Z随机，交替或以块形式键合，y表示2以上的整数，x和z分别表示0以上的整数， x + z> 2。
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公开(公告)号：US07001929B2
公开(公告)日：2006-02-21
申请号：US10641212
申请日：2003-08-15
申请人： Kohei Goto , Mayumi Kakuta , Fusazumi Masaka , Kiyonori Kita , Naoki Mitsuta , Masaru Iguchi , Hiroshi Soma , Nagayuki Kanaoka
发明人： Kohei Goto , Mayumi Kakuta , Fusazumi Masaka , Kiyonori Kita , Naoki Mitsuta , Masaru Iguchi , Hiroshi Soma , Nagayuki Kanaoka
IPC分类号： C08J5/20
CPC分类号： H01M10/0565 , H01M8/0289 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1051 , H01M8/1081 , Y02P70/56
摘要： The invention provides a proton conductive membrane excellent in heat resistance, which has sulfonic acid as ion exchange groups. The proton conductive membrane comprises a nitrogen-containing compound that can be mixed with water in arbitrary proportions and has a boiling point of not lower than 100. degree. C. and a proton conductive resin which has sulfonic acid ion-exchange groups, wherein the nitrogen-containing compound is contained in an amount of 0.5 to 10 parts by weight based on 100 parts by weight of the proton conductive resin.
摘要翻译： 本发明提供了耐热性优异的质子传导膜，其具有作为离子交换基团的磺酸。 质子传导膜包含可与任意比例的水混合并且沸点不低于100.度的含氮化合物。 以及具有磺酸离子交换基团的质子传导性树脂，其中，相对于100重量份的质子传导性树脂，含氮化合物的含量为0.5〜10重量份。
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公开(公告)号：US20050202299A1
公开(公告)日：2005-09-15
申请号：US11074664
申请日：2005-03-09
CPC分类号： C08J5/2256 , C08J2365/02 , C08J2371/12 , H01B1/122 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039
摘要： A solid polymer electrolyte includes a polymer having a sulfonic group and shows high proton conductivity in a wide range of temperatures and humidities and is excellent in hot water resistance and chemical stability. A proton conductive membrane is composed of the electrolyte. The polymer electrolyte includes a polymer having a structural unit represented by the following formula (1a) or (1b): wherein A is a divalent electron-withdrawing group, B is a divalent electron-donating group or a direct bond, Ar is an aromatic group, Z is an oxygen or a sulfur atom, X is a hydrogen or a fluorine atom, j is an integer of 1 or greater, k is an integer of from 1 to 4, l is an integer of from 0 to 10, m is an integer of from 1 to 10, and n is an integer of from 1 to 8.
摘要翻译： 固体聚合物电解质包括具有磺酸基的聚合物，并且在宽的温度和湿度范围内显示出高质子传导性，并且耐热水性和化学稳定性优异。 质子传导膜由电解质组成。 聚合物电解质包括具有由下式（1a）或（1b）表示的结构单元的聚合物：其中A是二价吸电子基团，B是二价给电子基团或直接键合，Ar是芳族 基团，Z为氧或硫原子，X为氢或氟原子，j为1以上的整数，k为1〜4的整数，l为0〜10的整数，m 为1〜10的整数，n为1〜8的整数。
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9.发明授权公开(公告)号：US06770393B2
公开(公告)日：2004-08-03
申请号：US10193047
申请日：2002-07-11
申请人： Hiroshi Akita , Masao Ichikawa , Masaru Iguchi , Hiroyuki Oyanagi
发明人： Hiroshi Akita , Masao Ichikawa , Masaru Iguchi , Hiroyuki Oyanagi
IPC分类号： H01B112
CPC分类号： H01M8/103 , C08G73/0266 , H01B1/128 , H01M8/1009 , H01M8/1048 , H01M8/1081 , Y02P70/56
摘要： A proton conducting polymer obtained by blending an organic phosphoric acid compound solution with a meta type polyaniline solution; a solid polymer electrolyte for a fuel cell comprising the proton conducting polymer, which is excellent in proton conductivity, methanol barrier property and dopant stability in an aqueous solution of methanol; and an electrode comprising the proton conducting and fine catalyst particles carried on porous particles.
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公开(公告)号：US06703152B2
公开(公告)日：2004-03-09
申请号：US09896412
申请日：2001-06-28
申请人： Teruaki Komiya , Masaru Iguchi , Masahiro Ise
发明人： Teruaki Komiya , Masaru Iguchi , Masahiro Ise
IPC分类号： H01M804
CPC分类号： H01M8/04 , H01M8/04007 , H01M8/04089
摘要： The operating condition is set so that a phosphoric acid concentration, at which an amount of reaction product water to lower a concentration of phosphoric acid and an amount of water evaporated from phosphoric acid are equilibrated, can be not less than a reference phosphoric acid concentration to maintain desired performance, when a phosphoric acid fuel cell is operated under a condition where the reaction product water exists as liquid water. Specifically, an equilibrium phosphoric acid concentration-setting system is used to control, if necessary, gas flow rate control systems, gas temperature control systems, and pressure control systems so as to effectively prevent the performance of the phosphoric acid fuel cell and its power generation from being worsened. Accordingly, it is possible to suitably operate the phosphoric acid fuel cell at a low temperature without additional equipments.
摘要翻译： 操作条件设定为使磷酸浓度降低至磷酸浓度降低的反应产物水量和从磷酸蒸发的水量的磷酸浓度可以不小于参考磷酸浓度 当磷酸燃料电池在作为液体水存在反应产物水的条件下操作时，保持期望的性能。 具体而言，如果需要，使用平衡磷酸浓度设定系统来控制气体流量控制系统，气体温度控制系统和压力控制系统，以有效地防止磷酸燃料电池的性能及其发电 从恶化。 因此，可以在没有附加设备的情况下在低温下适当地操作磷酸燃料电池。
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