Catalyst system for polymerizing alpha-olefins and method of making same
    3.
    发明授权
    Catalyst system for polymerizing alpha-olefins and method of making same 失效
    用于聚合α-烯烃的催化剂体系及其制备方法

    公开(公告)号:US4190555A

    公开(公告)日:1980-02-26

    申请号:US762843

    申请日:1977-01-27

    CPC分类号: C08F10/00

    摘要: A method is disclosed for preparing a catalyst system for polymerizing .alpha.-olefins. This method comprises admixing with at least an organoaluminum compound an activated titanium component which is prepared by first reacting a titanium compound of the general formula, TiX.sub.n (OR).sub.4-n (in which X is a halogen atom, R is an alkyl group or a phenyl group, and n is 2 to 4), with a metal of Group II or III of the Periodic Table and a halide of a metal of Group II or III of the Periodic Table in the presence of an aromatic compound, then treating the resulting reaction product with an oxygen-containing organic compound, and further treating with a tetrahalide of titanium, vanadium or both at a temperature of from -80.degree. C. to 80.degree. C., and finally aging at a temperature above 30.degree. C. for from 30 minutes to 24 hours.

    摘要翻译: 公开了制备用于聚合α-烯烃的催化剂体系的方法。 该方法包括与至少有机铝化合物混合活化的钛组分,其通过首先使通式TiXn(OR)4-n(其中X是卤素原子,R是烷基或 苯基,n为2至4)与元素周期表中II或III族的金属和元素周期表第II或III族金属的卤化物在芳族化合物的存在下, 得到与含氧有机化合物的反应产物,并在-80℃至80℃的温度下用钛,钒或二者的四卤化物进一步处理,最后在30℃以上升温。 从30分钟到24小时。