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1.发明授权
公开(公告)号：US5688609A
公开(公告)日：1997-11-18
申请号：US535750
申请日：1995-09-28
IPC分类号： H01M8/0612 , H01M8/1231 , H01M8/124 , H01M8/10
CPC分类号： H01M8/0625 , H01M8/1231 , H01M2008/1293 , H01M2300/0074
摘要： A process for producing electrical energy in an internal reforming, high-temperature fuel cell. Steam reforming of a carbonaceous feed gas takes place in the presence of a steam-reforming catalyst in heat-conducting relationship with electrochemical reactions in the fuel cell. The steam reformed feed gas is electrochemically reacted in an anode compartment of the fuel cell. The process is improved by controlled addition of a gaseous, sulfur-containing compound to the carbonaceous feed gas in an amount sufficient to obtain a sulfur coverage on the steam reforming catalyst of between 0.1 to 0.9.
摘要翻译： 一种在内部重整高温燃料电池中产生电能的方法。 含碳进料气体的蒸汽重整在与燃料电池中的电化学反应导热的蒸汽重整催化剂存在下进行。 蒸汽重整的进料气体在燃料电池的阳极室中电化学反应。 该方法通过将适量的气态含硫化合物以足以获得0.1至0.9的蒸汽重整催化剂上的硫覆盖的量向含碳进料气体中加入来提高。
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公开(公告)号：US07717971B2
公开(公告)日：2010-05-18
申请号：US11759096
申请日：2007-06-06
申请人： Kim Aasberg-Petersen , Ib Dybkjær , Peter Seier Christensen , Thomas Rostrup-Nielsen , Niels Erikstrup , Jens-Henrik Bak Hansen
发明人： Kim Aasberg-Petersen , Ib Dybkjær , Peter Seier Christensen , Thomas Rostrup-Nielsen , Niels Erikstrup , Jens-Henrik Bak Hansen
IPC分类号： B01J8/00
CPC分类号： C01B3/382 , C01B2203/0233 , C01B2203/0244 , C01B2203/0844 , C01B2203/1035 , C01B2203/143 , C01B2203/148 , C01B2203/82
摘要： Process and system for the production of synthesis gas from a hydrocarbon feed stock comprising the steps of endothermic and/or adiabatic catalytic steam reforming and autothermal steam reforming in series, wherein the steam reforming is carried out in one or more endothermic stages in series or in one or more adiabatic steam reforming stages in series with intermediate heating of feed stock gas leaving the adiabatic reforming stages and wherein carbon monoxide containing gas characterised by having a molar ratio of hydrogen to carbon of less than 4.5 is added prior to at least one of the endothermic or adiabatic steam reforming stages and/or prior to the autothermal steam reforming step.
摘要翻译： 用于从烃原料生产合成气的方法和系统，包括以下步骤：串联的吸热和/或绝热催化蒸汽重整和自热蒸汽重整，其中蒸汽重整在一个或多个吸热阶段串联或在 与离开绝热重整阶段的原料气体的中间加热串联的一个或多个绝热蒸汽重整级，并且其中以至少一个氢气与碳之间的氢与碳的摩尔比为小于4.5的一氧化碳的气体加入 吸热或绝热蒸汽重整阶段和/或在自热蒸汽重整步骤之前。
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公开(公告)号：US07087192B2
公开(公告)日：2006-08-08
申请号：US10667392
申请日：2003-09-23
申请人： Thomas Rostrup-Nielsen , Niels Erikstrup , Peter Seier Christensen , Kim Aasberg-Petersen , Jens-Henrik Bak Hansen , Ib Dybkjaer
发明人： Thomas Rostrup-Nielsen , Niels Erikstrup , Peter Seier Christensen , Kim Aasberg-Petersen , Jens-Henrik Bak Hansen , Ib Dybkjaer
IPC分类号： C01B3/38
CPC分类号： C01B3/384 , C01B3/382 , C01B2203/0233 , C01B2203/0816 , C01B2203/1011 , C01B2203/1023 , C01B2203/1035 , C01B2203/142 , Y02P20/129
摘要： Process and apparatus for the preparation of synthesis gas by catalytic steam and/or CO2 reforming of a hydrocarbon feedstock comprising the following steps: (a) heating the reaction mixture of hydrocarbon feedstock and steam and/or CO2 in the flue gas containing waste heat section from the fired tubular reformer (b) adiabatic reforming of the reaction mixture outside the waste heat section by contact with a solid reforming catalyst (c) repeating steps (a) and (b) until the desired reaction mixture composition and temperature is reached (d) feeding the reaction mixture to the fired tubular reformer and further reforming the mixture to the desired composition and temperature, wherein the adiabatic reforming of the reaction mixture is conducted in the process gas piping system in the flue gas-containing waste heat section, the piping system having adiabatic zones outside the heating section and containing solid reforming catalysts comprising one or more catalyzed structured elements.
摘要翻译： 通过烃原料的催化蒸汽和/或CO 2重整制备合成气的方法和装置，包括以下步骤：（a）加热烃原料和蒸汽和/或CO的反应混合物 （b）通过与固体重整催化剂（c）接触使反应混合物在废热段外部进行绝热重整，重复步骤（a）， 和（b）直到达到所需的反应混合物组成和温度（d）将反应混合物进料到烧制的管状重整器中，并进一步将混合物重整成所需的组成和温度，其中反应混合物的绝热重整在 含烟道气废热段的处理气体管道系统，该管道系统在加热段外部具有绝热区，并含有固体重整催化剂，其包含一个或多个催化的st 被推翻的元素。
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公开(公告)号：US5705288A
公开(公告)日：1998-01-06
申请号：US619833
申请日：1996-03-19
CPC分类号： H01M8/0625 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要： Process for the generation of electrical energy in an internal reforming high temperature fuel cell, comprising steam and/or carbon dioxide reforming of a hydrocarbon feed gas in contact with a catalyst having activity in the steam reforming of the carbonaceous gas to fuel cell fuel gas and being arranged within the fuel cell in heat conducting relationship with electrochemical reactions proceeding in the cell; and electrochemically reacting the fuel gas in an anode compartment of the cell for the generation of electric energy, wherein the steam reforming activity of the catalyst has been reduced by including one or more salts of metals selected from Group IA, IB, IIA, IVA and VA of the Periodic Table in the catalyst.
摘要翻译： 在内部重整高温燃料电池中产生电能的方法，包括与在碳质气体与燃料电池燃料气体的蒸汽转化中具有活性的催化剂接触的烃进料气体的蒸汽和/或二氧化碳重整，以及 在与电池中进行的电化学反应的热传导关系中布置在燃料电池内; 并且使电池的阳极室中的燃料气体电化学反应以产生电能，其中催化剂的蒸汽重整活性已经通过包括一种或多种选自IA，IB，IIA，IVA族和 VA在催化剂中的周期表。
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公开(公告)号：US09162886B2
公开(公告)日：2015-10-20
申请号：US14129244
申请日：2012-06-20
CPC分类号： C10K3/02 , B01D53/72 , C01B3/24 , C01B3/34 , C01B3/36 , C01B3/38 , C01B3/382 , C01B3/386 , C01B2203/0227 , C01B2203/0233 , C01B2203/0244 , C01B2203/0255 , C01B2203/0261 , C01B2203/062 , C01B2203/1235 , C01B2203/1258 , C01B2203/1276 , C01B2203/142 , C01B2203/143 , C01B2203/148 , C07C1/0485 , C10G2/30 , C10G2/31 , C10G2/32 , C10G2300/4075
摘要： The invention relates to a process for the production of synthesis gas by the use of autothermal reforming in which tail gas from downstream Fischer-Tropsh synthesis is hydrogenated and then added to the autothermal reforming stage.
摘要翻译： 本发明涉及一种通过使用自热重整制备合成气的方法，其中将来自下游费 - 托罗普合成的尾气氢化，然后加入到自热重整阶段。
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公开(公告)号：US08106102B2
公开(公告)日：2012-01-31
申请号：US11922380
申请日：2006-06-14
IPC分类号： C07C27/00
CPC分类号： C01B3/384 , B01J23/755 , B01J37/0201 , C01B3/382 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/062 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C10G2/32 , C10G2/332 , C10G2300/4081 , C10K1/005 , C10K3/006 , Y02P20/52
摘要： A process (10) for the preparation and conversion of synthesis gas includes reforming a feed gas (34) comprising methane in a reforming stage (18) to produce synthesis gas (46) which includes hydrogen and carbon monoxide. Some of the hydrogen and carbon monoxide is converted to a Fischer-Tropsch product (48) in a Fischer-Tropsch hydrocarbon synthesis stage (24). A tail gas (52), including unreacted hydrogen and carbon monoxide, methane and carbon dioxide, is separated from the Fischer-Tropsch product (48). In a tail gas treatment stage (28,30), the tail gas (52) is treated by reforming the methane in the tail gas (52) with steam (66) and removing carbon dioxide to produce a hydrogen rich gas (56). The tail gas treatment stage (28,30) may be either a combined tail gas treatment stage (28,30) or a composite tail gas treatment stage. The carbon dioxide from the tail gas treatment stage (28,30) is fed to the reforming stage (18).
摘要翻译： 用于制备和转化合成气的方法（10）包括在重整阶段（18）中重整包含甲烷的进料气体（34）以产生包括氢气和一氧化碳的合成气体（46）。 在费 - 托烃合成阶段（24）中，一些氢和一氧化碳转化成费 - 托产物（48）。 包含未反应的氢气和一氧化碳的甲烷和二氧化碳的尾气（52）从费 - 托产物（48）中分离出来。 在尾气处理阶段（28,30）中，通过用蒸汽（66）重整尾气（52）中的甲烷并除去二氧化碳以产生富氢气体（56）来处理尾气（52）。 尾气处理阶段（28,30）可以是组合尾气处理阶段（28,30）或复合尾气处理阶段。 来自尾气处理阶段（28,30）的二氧化碳被供给到重整阶段（18）。
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公开(公告)号：US20060057058A1
公开(公告)日：2006-03-16
申请号：US10940762
申请日：2004-09-15
IPC分类号： C01B3/02
CPC分类号： C01B3/382 , C01B2203/0233 , C01B2203/066 , C01B2203/1241 , C01B2203/1264 , C01B2203/142
摘要： Process for selectively reforming ethanol to a hydrogen-rich product in the presence of at least one catalyst comprising a catalytically active material supported on a carrier, the process comprising the following steps in which the at least one catalyst is active: transferring a stream of ethanol and steam and a hydrogen-comprising stream, the molar ratio of ethanol to hydrogen being 0.2-1, to a dehydration/hydrogenation reactor for dehydrating ethanol to ethylene and for hydrogenating ethylene to produce an ethane-containing stream, adiabatically pre-reforming the ethane-comprising stream to a stream comprising methane, steam reforming the stream comprising methane to produce a mixture comprising hydrogen and carbon monoxide, converting the mixture comprising hydrogen and carbon monoxide from the steam reforming step under water gas shift conditions to produce a hydrogen-rich product stream.
摘要翻译： 在至少一种包含负载在载体上的催化活性物质的催化剂存在下，将乙醇选择性地重整成富氢产物的方法，所述方法包括以下步骤：其中所述至少一种催化剂是有活性的：将乙醇流 和蒸汽和含氢气流，乙醇与氢气的摩尔比为0.2-1，用于脱乙醇/氢化反应器，用于将乙醇脱水成乙烯和氢化乙烯以产生含乙烷的流，绝热地重整乙烷 包含甲烷的流，对包含甲烷的流进行蒸汽重整以产生包含氢气和一氧化碳的混合物，在水煤气变换条件下将来自蒸汽重整步骤的氢和一氧化碳的混合物转化，以产生富氢产物 流。
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公开(公告)号：US5705916A
公开(公告)日：1998-01-06
申请号：US587581
申请日：1996-01-17
申请人： Poul Rudbeck , Kim Aasberg-Petersen , Susanne L.oe butted.gsgaard J.o slashed.rgensen , Poul Erik H.o slashed.jlund Nielsen
发明人： Poul Rudbeck , Kim Aasberg-Petersen , Susanne L.oe butted.gsgaard J.o slashed.rgensen , Poul Erik H.o slashed.jlund Nielsen
IPC分类号： F01K23/16 , C01B3/38 , C01B3/50 , F01K23/10 , F02C3/20 , F02C3/28 , F02C6/00 , F02C6/02 , F02C6/18 , F02C9/40 , H01M8/06 , H02N3/00
CPC分类号： C01B3/505 , C01B3/384 , F01K23/10 , F02C3/20 , F02C6/003 , C01B2203/0233 , C01B2203/041 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/06 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/1058 , C01B2203/1241 , Y02P20/128
摘要： A process for generating electrical power in a gas turbine cycle including an air compression stage, first and second gas combustion stages, and a series of first and second gas expansion stages. Mechanical power is provided for the generation of electrical power in a rotating power generator. The first combustion stage is operated on hydrogen-depleted fuel gas at high pressure using air from the air compression stage. The hydrogen-depleted fuel gas is obtained by endothermic catalytic steam reforming of a hydrocarbon feed gas. Heat for the endothermic steam reforming is supplied by indirect heat exchange with heat from hot exhaust gas from the second expansion stage. The second combustion stage is operated at lower pressure than the first combustion stage on exhaust gas from the first expansion stage and the hydrogen-enriched gas separated form the hydrogen depleted gas. The hydrogen-enriched gas is separated from the hydrogen-depleted fuel gas during the catalytic steam reforming of the feed gas.
摘要翻译： 一种用于在包括空气压缩级，第一和第二气体燃烧级以及一系列第一和第二气体膨胀级的燃气轮机循环中产生电力的过程。 提供了用于在旋转发电机中产生电力的机械功率。 第一燃烧阶段使用来自空气压缩级的空气在高压下在贫氢燃料气体下运行。 通过烃进料气体的吸热催化蒸汽重整获得贫氢燃料气体。 用于吸热蒸汽重整的热量通过来自第二膨胀级的热废气的热量的间接热交换而提供。 第二燃烧阶段在比来自第一膨胀级的废气的第一燃烧阶段低的压力下工作，并且富氢气体从贫氢气体分离。 在进料气体的催化蒸汽重整期间，富氢气体与贫氢燃料气体分离。
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公开(公告)号：US20130082211A1
公开(公告)日：2013-04-04
申请号：US13701488
申请日：2011-05-13
申请人： Kim Aasberg-Petersen , Poul Erik Højlund Nielsen , Peter Seier Christensen , Charlotte Stub Nielsen , Burcin Temel
发明人： Kim Aasberg-Petersen , Poul Erik Højlund Nielsen , Peter Seier Christensen , Charlotte Stub Nielsen , Burcin Temel
IPC分类号： C01B3/48
CPC分类号： C01B3/48 , C01B3/16 , C01B3/36 , C01B3/382 , C01B3/386 , C01B2203/0244 , C01B2203/0255 , C01B2203/0261 , C01B2203/0283 , C01B2203/062 , C01B2203/1264 , C10G2/32 , C10G2300/1022 , C10G2300/807 , C10G2400/02
摘要： Process for the preparation of synthesis gas from an essentially dry hydrocarbon feedstock (1) comprising olefins, hydrogen and carbon monoxide, the process comprising the steps: (a) selectively hydrogenating the olefins in the hydrocarbon feedstock at a temperature between 60 to 190° C. (2) to obtain a hydrogenated hydrocarbon feedstock comprising hydrogen, carbon monoxide and saturated hydrocarbons (3; (b) adding steam (4) to the hydrogenated hydrocarbon feedstock; (c) performing a water gas shift reaction in the presence of steam on the hydrogenated hydrocarbon feedstock (6) to obtain a shifted, hydrogenated hydrocarbon mixture; (d) converting the shifted, hydrogenated hydrocarbon mixture (8) to obtain a synthesis gas.
摘要翻译： 用于从包含烯烃，氢气和一氧化碳的基本上干的烃原料（1）制备合成气的方法，该方法包括以下步骤：（a）在60至190℃的温度下选择性氢化烃原料中的烯烃 （2）获得包含氢气，一氧化碳和饱和烃的氢化烃原料（3;（b）向氢化烃原料中加入蒸汽（4）;（c）在蒸汽存在下进行水煤气变换反应 氢化烃原料（6）以获得偏移的氢化烃混合物;（d）转化转移的氢化烃混合物（8）以获得合成气。
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10.发明申请公开(公告)号：US20100311848A1
公开(公告)日：2010-12-09
申请号：US12739677
申请日：2008-10-23
CPC分类号： B01D53/04 , B01D53/8603 , B01D2253/104 , B01D2253/112 , B01D2255/1021 , B01D2255/1023 , B01D2255/104 , B01D2255/106 , B01D2257/30 , C01B3/56 , C01B3/58 , C01B2203/0425 , C01B2203/0435 , C01B2203/0465 , C01B2203/0475 , C01B2203/048 , C01B2203/0485
摘要： A process for a reduction in the amount of sulphur compounds, hydrogen cyanide, formic acid and formic acid derivatives in synthesis gas comprising these compounds, the process comprising contacting the synthesis gas with a sulphur absorbent comprising material and thereafter with a catalyst comprising one or more metals selected from the group consisting of silver, gold, copper, palladium, platinum and their mixtures and supported on a carrier comprising at least one of the oxides of scandium, yttrium, lanthanum, cerium, titanium, zirconium, aluminium, zinc, chromium and molybdenum.
摘要翻译： 包含这些化合物的合成气中的硫化合物，氰化氢，甲酸和甲酸衍生物的量的减少的方法，该方法包括使合成气与含硫吸收剂的材料接触，然后与含有一种或多种 选自银，金，铜，钯，铂及其混合物的金属，并负载在包含钪，钇，镧，铈，钛，锆，铝，锌，铬中的至少一种氧化物的载体上， 钼。
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