公开(公告)号：US08637580B2

公开(公告)日：2014-01-28

申请号：US13808240

申请日：2011-05-17

Applicant: Poul Erik Højlund Nielsen ,  Burcin Temel ,  Pablo Beato

Inventor： Poul Erik Højlund Nielsen ,  Burcin Temel ,  Pablo Beato

IPC: C07C27/00

CPC classification number: C07C29/1516 ,  C07C29/1512 ,  C07C29/32 ,  C07C31/08 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125

Abstract: Process for the preparation of ethanol and/or higher alcohols comprising the steps of: (a) providing an alcohol synthesis gas comprising carbon monoxide and hydrogen in a molar ratio of higher than 0.5; (c) adding an amount of methanol and/or higher alcohols to the synthesis gas to obtain a synthesis gas mixture. (d) converting the synthesis gas mixture from step (c) in presence of one or more catalysts catalysing the conversion of the synthesis gas mixture into a ethanol and/or higher alcohols containing product; and (e) withdrawing the product from step (d), wherein the synthesis gas is purified by removing iron and nickel carbonyl compounds prior or after the addition methanol and/or higher alcohols to the synthesis gas and optionally (I) cooling the withdrawn product in step (e); and (g) contacting the cooled product with a hydrogenation catalyst.

Abstract translation: 制备乙醇和/或高级醇的方法包括以下步骤：（a）提供摩尔比高于0.5的一氧化碳和氢气的醇合成气; （c）向合成气中加入一定量的甲醇和/或高级醇以得到合成气体混合物。 （d）在催化合成气混合物转化为乙醇和/或高级醇的产物的一种或多种催化剂的存在下，转化来自步骤（c）的合成气混合物; 和（e）从步骤（d）中取出产物，其中通过在向合成气中加入甲醇和/或高级醇之前或之后除去铁和镍羰基化合物来纯化合成气，并且任选地（I）冷却所提取的产物 在步骤（e）中; 和（g）使冷却的产物与氢化催化剂接触。

公开(公告)号：US20130225879A1

公开(公告)日：2013-08-29

申请号：US13883059

申请日：2010-11-08

Applicant: Burcin Temel ,  Poul Erik Højlund Nielsen ,  Pablo Beato

Inventor： Burcin Temel ,  Poul Erik Højlund Nielsen ,  Pablo Beato

IPC: C07C29/32

CPC classification number: C07C29/32 ,  C07C31/08 ,  C07C31/10 ,  C07C31/12

Abstract: Process for the preparation of a product alcohol mixture comprising the steps of: (a) providing a synthesis gas comprising carbon monoxide and hydrogen (b) providing an amount of methanol and a second source alcohol Rn—CH2—CH2—OH comprising n+2 carbon atoms (Rn═CnH2n+1, n≧O) to the synthesis gas to obtain a selective alcohol synthesis mixture (c) converting the selective synthesis mixture in presence of one or more catalysts catalysing the conversion of the synthesis gas mixture into a product alcohol mixture in which the initially dominating alcohol is a preferred Cn+3 alcohol having the structure Rn—CH(CH3)—CH2—OH (d) withdrawing the product alcohol mixture of step (c).

Abstract translation: 制备产物醇混合物的方法，包括以下步骤：（a）提供包含一氧化碳和氢气的合成气（b）提供一定量的甲醇和包含n + 2的第二源醇Rn-CH2-CH2-OH 碳原子（Rn = CnH2n + 1，n> = 0），以获得选择性醇合成混合物（c）在一种或多种催化剂将催化合成气混合物转化为 产物醇混合物，其中最初占优势的醇是具有结构Rn-CH（CH3）-CH2-OH（d）的优选C n + 3醇（d）取出步骤（c）的产物醇混合物。

公开(公告)号：US20130082211A1

公开(公告)日：2013-04-04

申请号：US13701488

申请日：2011-05-13

Applicant: Kim Aasberg-Petersen ,  Poul Erik Højlund Nielsen ,  Peter Seier Christensen ,  Charlotte Stub Nielsen ,  Burcin Temel

Inventor： Kim Aasberg-Petersen ,  Poul Erik Højlund Nielsen ,  Peter Seier Christensen ,  Charlotte Stub Nielsen ,  Burcin Temel

IPC: C01B3/48

CPC classification number: C01B3/48 ,  C01B3/16 ,  C01B3/36 ,  C01B3/382 ,  C01B3/386 ,  C01B2203/0244 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/062 ,  C01B2203/1264 ,  C10G2/32 ,  C10G2300/1022 ,  C10G2300/807 ,  C10G2400/02

Abstract: Process for the preparation of synthesis gas from an essentially dry hydrocarbon feedstock (1) comprising olefins, hydrogen and carbon monoxide, the process comprising the steps: (a) selectively hydrogenating the olefins in the hydrocarbon feedstock at a temperature between 60 to 190° C. (2) to obtain a hydrogenated hydrocarbon feedstock comprising hydrogen, carbon monoxide and saturated hydrocarbons (3; (b) adding steam (4) to the hydrogenated hydrocarbon feedstock; (c) performing a water gas shift reaction in the presence of steam on the hydrogenated hydrocarbon feedstock (6) to obtain a shifted, hydrogenated hydrocarbon mixture; (d) converting the shifted, hydrogenated hydrocarbon mixture (8) to obtain a synthesis gas.

Abstract translation: 用于从包含烯烃，氢气和一氧化碳的基本上干的烃原料（1）制备合成气的方法，该方法包括以下步骤：（a）在60至190℃的温度下选择性氢化烃原料中的烯烃 （2）获得包含氢气，一氧化碳和饱和烃的氢化烃原料（3;（b）向氢化烃原料中加入蒸汽（4）;（c）在蒸汽存在下进行水煤气变换反应 氢化烃原料（6）以获得偏移的氢化烃混合物;（d）转化转移的氢化烃混合物（8）以获得合成气。

公开(公告)号：US07825287B2

公开(公告)日：2010-11-02

申请号：US12058300

申请日：2008-03-28

Applicant: John Ahn ,  Burcin Temel ,  Enrique Iglesia

Inventor： John Ahn ,  Burcin Temel ,  Enrique Iglesia

IPC: C07C1/00

CPC classification number: C07C1/20 ,  C07C9/16 ,  C07C11/107

Abstract: High octane C7 hydrocarbons, particularly 2,2,3-trimethylbutane (“triptane”) and 2,2,3-trimethyl-but-1-ene (“triptene”) (collectively “triptyls”) are produced by homologation of a feed comprising dimethyl ether and/or methanol and optionally including one or more aliphatic hydrocarbons in the presence of certain acidic zeolite catalysts. The process can be carried out at temperatures lower than those previously used for conversion of dimethyl ether and/or methanol to higher alkanes, including C7 alkanes, and results in selective production of triptane and/or triptene with relatively little isomerization to or production of other C7 alkanes.

Abstract translation: 高辛烷值的C7烃，特别是2,2,3-三甲基丁烷（“triptane”）和2,2,3-三甲基 - 丁-1-烯（“triptene”）（统称为“triptyl”）是通过进料 包括二甲醚和/或甲醇，并且在某些酸性沸石催化剂的存在下任选地包括一种或多种脂族烃。 该方法可以在比以前用于将二甲醚和/或甲醇转化为高级烷烃（包括C 7烷烃）的温度低的温度下进行，并且导致选择性生产具有相对较少的异构化或生产其它的三烷基和/或三丁烯 C7烷烃。

公开(公告)号：US20090247803A1

公开(公告)日：2009-10-01

申请号：US12058300

申请日：2008-03-28

Applicant: John Ahn ,  Burcin Temel ,  Enrique Iglesia

Inventor： John Ahn ,  Burcin Temel ,  Enrique Iglesia

IPC: C07C1/00

CPC classification number: C07C1/20 ,  C07C9/16 ,  C07C11/107

Abstract: High octane C7 hydrocarbons, particularly 2,2,3-trimethylbutane (“triptane”) and 2,2,3-trimethyl-but-1-ene (“triptene”) (collectively “triptyls”) are produced by homologation of a feed comprising dimethyl ether and/or methanol and optionally including one or more aliphatic hydrocarbons in the presence of certain acidic zeolite catalysts. The process can be carried out at temperatures lower than those previously used for conversion of dimethyl ether and/or methanol to higher alkanes, including C7 alkanes, and results in selective production of triptane and/or triptene with relatively little isomerization to or production of other C7 alkanes.

Abstract translation: 高辛烷值的C7烃，特别是2,2,3-三甲基丁烷（“triptane”）和2,2,3-三甲基 - 丁-1-烯（“triptene”）（统称为“triptyl”）是通过进料 包括二甲醚和/或甲醇，并且在某些酸性沸石催化剂的存在下任选地包括一种或多种脂族烃。 该方法可以在比以前用于将二甲醚和/或甲醇转化为高级烷烃（包括C 7烷烃）的温度低的温度下进行，并且导致选择性生产具有相对较少的异构化或生产其它的三烷基和/或三丁烯 C7烷烃。

公开(公告)号：US08765019B2

公开(公告)日：2014-07-01

申请号：US13701488

申请日：2011-05-13

Applicant: Kim Aasberg-Petersen ,  Poul Erik Højlund Nielsen ,  Peter Seier Christensen ,  Charlotte Stub Nielsen ,  Burcin Temel

Inventor： Kim Aasberg-Petersen ,  Poul Erik Højlund Nielsen ,  Peter Seier Christensen ,  Charlotte Stub Nielsen ,  Burcin Temel

IPC: C01B3/48

CPC classification number: C01B3/48 ,  C01B3/16 ,  C01B3/36 ,  C01B3/382 ,  C01B3/386 ,  C01B2203/0244 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/062 ,  C01B2203/1264 ,  C10G2/32 ,  C10G2300/1022 ,  C10G2300/807 ,  C10G2400/02

Abstract: Process for the preparation of synthesis gas from an essentially dry hydrocarbon feedstock (1) comprising olefins, hydrogen and carbon monoxide, the process comprising the steps: (a) selectively hydrogenating the olefins in the hydrocarbon feedstock at a temperature between 60 to 190° C. (2) to obtain a hydrogenated hydrocarbon feedstock comprising hydrogen, carbon monoxide and saturated hydrocarbons (3; (b) adding steam (4) to the hydrogenated hydrocarbon feedstock; (c) performing a water gas shift reaction in the presence of steam on the hydrogenated hydrocarbon feedstock (6) to obtain a shifted, hydrogenated hydrocarbon mixture; (d) converting the shifted, hydrogenated hydrocarbon mixture (8) to obtain a synthesis gas.

Abstract translation: 用于从包含烯烃，氢气和一氧化碳的基本上干的烃原料（1）制备合成气的方法，该方法包括以下步骤：（a）在60至190℃的温度下选择性氢化烃原料中的烯烃 （2）获得包含氢气，一氧化碳和饱和烃的氢化烃原料（3;（b）向氢化烃原料中加入蒸汽（4）;（c）在蒸汽存在下进行水煤气变换反应 氢化烃原料（6）以获得偏移的氢化烃混合物;（d）转化转移的氢化烃混合物（8）以获得合成气。

公开(公告)号：US20130123377A1

公开(公告)日：2013-05-16

申请号：US13808240

申请日：2011-05-17

Applicant: Poul Erik Højlund Nielsen ,  Burcin Temel ,  Pablo Beato

Inventor： Poul Erik Højlund Nielsen ,  Burcin Temel ,  Pablo Beato

IPC: C07C29/151

CPC classification number: C07C29/1516 ,  C07C29/1512 ,  C07C29/32 ,  C07C31/08 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125

Abstract: Process for the preparation of ethanol and/or higher alcohols comprising the steps of: (a) providing an alcohol synthesis gas comprising carbon monoxide and hydrogen in a molar ratio of higher than 0.5; (c) adding an amount of methanol and/or higher alcohols to the synthesis gas to obtain a synthesis gas mixture. (d) converting the synthesis gas mixture from step (c) in presence of one or more catalysts catalysing the conversion of the synthesis gas mixture into a ethanol and/or higher alcohols containing product; and (e) withdrawing the product from step (d), wherein the synthesis gas is purified by removing iron and nickel carbonyl compounds prior or after the addition methanol and/or higher alcohols to the synthesis gas and optionally (I) cooling the withdrawn product in step (e); and (g) contacting the cooled product with a hydrogenation catalyst.

Abstract translation: 制备乙醇和/或高级醇的方法包括以下步骤：（a）提供摩尔比高于0.5的一氧化碳和氢气的醇合成气; （c）向合成气中加入一定量的甲醇和/或高级醇以得到合成气体混合物。 （d）在催化合成气混合物转化为乙醇和/或高级醇的产物的一种或多种催化剂的存在下，转化来自步骤（c）的合成气混合物; 和（e）从步骤（d）中取出产物，其中通过在向合成气中加入甲醇和/或高级醇之前或之后除去铁和镍羰基化合物来纯化合成气，并且任选地（I）冷却所提取的产物 在步骤（e）中; 和（g）使冷却的产物与氢化催化剂接触。