摘要:
The present invention relates to powder coating compositions wherein the binder contains copolymers which are solid below 30.degree. C., prepared from olefinically unsaturated compounds and have a weight-average molecular weight (M.sub.w) of 1500 to 75,000, a content of free hydroxyl groups of 0.2 to 6.0% by weight and a content of intramolecular carboxylic acid anhydride groups (calculated as C.sub.4 H.sub.2 O.sub.3) of 1 to 30% by weight.
摘要翻译:本发明涉及粉末涂料组合物,其中粘合剂含有固体低于30℃的共聚物,由烯属不饱和化合物制备,重均分子量(Mw)为1500至75,000,游离羟基含量为 0.2〜6.0重量%,分子量内羧酸酐基(C 4 H 2 O 3计算)含量为1〜30重量%。
摘要:
The present invention relates to coating compositions in pulverulent form which are solid below 30.degree. C. and liquid above 150.degree. C. and containA) 10 to 99 parts by weight of a copolymer component containing at least one copolymer which is prepared from olefinically unsaturated compounds, has a weight average molecular weight of 1500 to 75,000 and contains in chemically bound form(i) 1 to 30% by weight of cyclic carboxylic acid anhydride groups (calculated as C.sub.4 H.sub.2 O.sub.3) and(ii) 0.3 to 10% by weight of epoxide groups (calculated as C.sub.2 H.sub.3 O), andB) 1 to 90 parts by weight of a polyol component containing at least one organic polyol having at least two hydroxyl groups per molecule,provided that for every anhydride group of component A) there are 0.1 to 10 hydroxyl groups of component B).
摘要:
The present invention relates to powder coating compositions which are solid below 3O.degree. C. and contain a mixture ofA) a copolymer component which is solid below 3O.degree. C. and contains at least one copolymer containing both cyclic carboxylic anhydride groups and hydroxyl groups,B) a polyepoxide component which contains at least one polyepoxide containing at least two epoxide groups per molecule.
摘要:
The present invention relates to powder coating compositions which can be cured in the presence of heat and/or high energy radiation and contain polyurethanes which melt at temperatures of 50.degree. to 180.degree. C., have 3 to 10% by weight of olefinic double bonds in the form of (meth)acryloyl groups (calculated as .dbd.C.dbd.C.dbd., molecular weight=24) and are based on the reaction product ofA) 40 to 80 parts by weight of one or more organic polyisocyanates withB) 15 to 50 parts of weight of one or more monohydric alcohols containing (meth)acryloyl groups andC) 2 to 20 parts by weight one or more compounds which are free from (meth)acryloyl groups and contain isocyanate reactive groups.
摘要翻译:本发明涉及粉末涂料组合物,其可以在热和/或高能量辐射的存在下固化,并且包含在50-180℃的温度下熔化的聚氨酯,具有3至10重量%的烯属双键 以(甲基)丙烯酰基的形式(以C = C =分子量= 24计算),并且基于A)的反应产物:40至80重量份的一种或多种有机多异氰酸酯与B)15至 50重量份的一种或多种含(甲基)丙烯酰基的一元醇和C)2至20重量份的一种或多种不含(甲基)丙烯酰基并含有异氰酸酯反应性基团的化合物。
摘要:
The present invention relates to compositions which are storage stable at room temperature and containA) at least one compound having at least two cyclic isourea groups per molecule andB) at least one compound having at least two carboxyl groups per molecule,in an amount sufficient to provide a molar ratio of isourea groups to carboxyl groups of 0.5:1 to 1.5:1.
摘要:
Polyesters useful as a binder or a component of a binder for powder lacquers and which contain hydroxyls, carboxyls or both and which have an acid value of up to 50, a hydroxyl value of up to 200 and a sum of hydroxyl value and acid value of from 20 to 200 is produced by reacting:(a) an acid component selected from the group consisting of (a1) at least one poly-functional organic carboxylic acid, (a2) at least one ester-forming derivative of a poly-functional organic carboxylic acid, (a3) at least one organic hydroxycarboxylic acid, (a4) at least one lactone of an organic hydroxycarboxylic acid, and mixtures thereof, with the proviso that at least 50 mol-% of component (a) consists of aromatic species of components (a1), (a2), (a3), (a4), or mixtures thereof,with(b) a polyol component which is at least one polyhydric alcohol having a molecular weight in the range from 62 to 250,while maintaining an equivalent ratio of carboxyl groups to hydroxyl groups of form 0.65:1 to 1.5:1, with the proviso that component (b) is used in a quantity of at least 30% by weight, based on the weight of component (a), and the reaction is carried out in the presence of(c) at least 5% by weight, based on the weight of components (a) and (b), of a solvent containing amide groups, lactam groups, or both and said solvent is free from any nitrogenhydrogen bonds.
摘要:
The present invention is directed to isocyanato isocyanurates prepared from diisocyanates which contain a sterically unhindered isocyanate group bound to a primary aliphatic carbon atom and a sterically hindered isocyanate group which is bound to a tertiary carbon atom forming part of a cycloaliphatic ring system, said diisocyanate having an NCO content of about 20 to 50% by weight. The present invention is further directed to a process for preparing these isocyanato isocyanurates by catalytic trimerization and the use of the isocyanato isocyanurates in a process for the production of polyisocyanate polyaddition products, preferably two-component polyurethane stoving lacquers.
摘要:
Cyclic amidines which are modified by the incorporation of additional polar groups, may be used as catalysts for hardening heat-curable resin compositions comprising polyepoxides and optionally carboxyl group-containing polymers. Such amidine catalysts yield a high reactivity, an excellent storage stability and result in elastic coatings which show a high gloss and a good resistance to solvents.
摘要:
Alkyd resin lacquers which contain cellulose nitric acid esters can be prevented from "lifting" and yellowing by the addition of bis-[hydroxyphenyl]-alkanes which are substituted in the nucleus.
摘要:
The invention relates to a pulverulent coating material prepared from a polyester which contains free carboxyl groups of succinic acid and cross-linking agents which react with carboxyl groups at elevated temperatures.