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    Additive to maximize GLP and propene suitable for use in low-severity operations of a fluid catalytic cracking unit and its preparatory process
    4.
    发明授权
    Additive to maximize GLP and propene suitable for use in low-severity operations of a fluid catalytic cracking unit and its preparatory process 有权
    最大化GLP和丙烯的添加剂，适用于流化催化裂化装置的低强度操作及其制备过程

    公开(公告)号：US07691768B2

    公开(公告)日：2010-04-06

    申请号：US11714117

    申请日：2007-03-06

    申请人： Lam Yiu Lau ,  Raquel Bastiani ,  Claudia Maria de Lacerda Alvarenga Baptista

    发明人： Lam Yiu Lau ,  Raquel Bastiani ,  Claudia Maria de Lacerda Alvarenga Baptista

    IPC分类号： B01J29/06

    CPC分类号： B01J29/405 ,  B01J37/0045 ,  B01J37/06 ,  B01J37/08 ,  B01J2229/20 ,  B01J2229/40 ,  B01J2229/42 ,  C10G11/05 ,  C10G11/18

    摘要： A process for the preparation and modification of additives, with a zeolite base and a high silica alumina ratio (SAR) like the ZSM-5, to increase the yield of propene and LPG in low severity FCC operations, that seeks to maximize the production of medium-distillates with low aromaticity and to minimize molecular cracking in the LCO range. The additives involved guarantee an increase in light olefin yields without altering the yield or the quality of the LCO produced. The innovative process includes surprising actions from rare earths (RE) on the active sites of zeolite, that at once partially block their pores and, in this way, make molecular cracking in the medium-distillate range difficult, which preferably occur at low reaction temperatures and keeps the remaining sites quite active. These sites are sufficiently active to crack smaller molecules in the gasoline range, guaranteeing an overall increase in light olefins and allowing the additive involved to be used industrially in operations to maximize medium-distillates in an FCC unit. This new additive may be obtained by modifying any commercial ZSM-5 zeolite additive.

    摘要翻译： 一种用于制备和改性添加剂的方法，具有沸石基质和高ZSM-5的高二氧化硅氧化铝比（SAR），以提高低浓度FCC操作中丙烯和LPG的产率，从而最大限度地提高生产 具有低芳香度的中等馏出物，并使LCO范围内的分子裂解最小化。 所涉及的添加剂保证轻烯烃产量的增加，而不改变生产的LCO的产率或质量。 创新的方法包括来自稀土（RE）对沸石活性位点的惊人的作用，其一度部分阻断其孔，并且以这种方式使中等馏出物范围内的分子裂解困难，优选在低反应温度下发生 并保持其余的网站相当活跃。 这些位点具有足够的活性以在汽油范围内裂解较小的分子，保证轻质烯烃的总体增加，并允许所涉及的添加剂在工业上用于FCC装置中的中等馏出物的最大化。 这种新添加剂可以通过改变任何商业的ZSM-5沸石添加剂来获得。

    Additive to maximize GLP and propene suitable for use in low-severity operations of a fluid catalytic cracking unit and its preparatory process
    5.
    发明申请
    Additive to maximize GLP and propene suitable for use in low-severity operations of a fluid catalytic cracking unit and its preparatory process 有权
    最大化GLP和丙烯的添加剂，适用于流化催化裂化装置的低强度操作及其制备过程

    公开(公告)号：US20080015105A1

    公开(公告)日：2008-01-17

    申请号：US11714117

    申请日：2007-03-06

    申请人： Lam Yiu Lau ,  Raquel Bastiani ,  Claudia Maria de Lacerda Alvarenga Baptista

    发明人： Lam Yiu Lau ,  Raquel Bastiani ,  Claudia Maria de Lacerda Alvarenga Baptista

    IPC分类号： B01J29/04

    CPC分类号： B01J29/405 ,  B01J37/0045 ,  B01J37/06 ,  B01J37/08 ,  B01J2229/20 ,  B01J2229/40 ,  B01J2229/42 ,  C10G11/05 ,  C10G11/18

    摘要： A process for the preparation and modification of additives, with a zeolite base and a high silica alumina ratio (SAR) like the ZSM-5, to increase the yield of propene and LPG in low severity FCC operations, that seeks to maximize the production of medium-distillates with low aromaticity and to minimize molecular cracking in the LCO range. The additives involved guarantee an increase in light olefin yields without altering the yield or the quality of the LCO produced. The innovative process includes surprising actions from rare earths (RE) on the active sites of zeolite, that at once partially block their pores and, in this way, make molecular cracking in the medium-distillate range difficult, which preferably occur at low reaction temperatures and keeps the remaining sites quite active. These sites are sufficiently active to crack smaller molecules in the gasoline range, guaranteeing an overall increase in light olefins and allowing the additive involved to be used industrially in operations to maximize medium-distillates in an FCC unit. This new additive may be obtained by modifying any commercial ZSM-5 zeolite additive.

    摘要翻译： 一种用于制备和改性添加剂的方法，具有沸石基质和高ZSM-5的高二氧化硅氧化铝比（SAR），以提高低浓度FCC操作中丙烯和LPG的产率，从而最大限度地提高生产 具有低芳香度的中等馏出物，并使LCO范围内的分子裂解最小化。 所涉及的添加剂保证轻烯烃产量的增加，而不改变生产的LCO的产率或质量。 创新的方法包括来自稀土（RE）对沸石活性位点的惊人的作用，其一度部分阻断其孔，并且以这种方式使中等馏出物范围内的分子裂解困难，优选在低反应温度下发生 并保持其余的网站相当活跃。 这些位点具有足够的活性以在汽油范围内裂解较小的分子，保证轻质烯烃的总体增加，并允许所涉及的添加剂在工业上用于FCC装置中的中等馏出物的最大化。 这种新添加剂可以通过改变任何商业的ZSM-5沸石添加剂来获得。

    CATALYTIC SYSTEM AND ADDITIVE FOR MAXIMISATION OF LIGHT OLEFINS IN FLUID CATALYTIC CRACKING UNITS IN OPERATIONS OF LOW SEVERITY
    8.
    发明申请
    CATALYTIC SYSTEM AND ADDITIVE FOR MAXIMISATION OF LIGHT OLEFINS IN FLUID CATALYTIC CRACKING UNITS IN OPERATIONS OF LOW SEVERITY 审中-公开
    催化体系和添加剂在液体催化裂化装置中在低严重运行中最大化烯烃

    公开(公告)号：US20090107885A1

    公开(公告)日：2009-04-30

    申请号：US12260181

    申请日：2008-10-29

    申请人： Raquel Bastiani ,  Lam Yiu Lam ,  Claudia Maria de Lacerda Alvarenga Baptista

    发明人： Raquel Bastiani ,  Lam Yiu Lam ,  Claudia Maria de Lacerda Alvarenga Baptista

    IPC分类号： C10G11/00 ,  B01J8/18 ,  C01B39/02 ,  B01J29/06

    CPC分类号： C10G11/05 ,  B01J29/40 ,  B01J29/65 ,  B01J29/80 ,  C10G11/18

    摘要： The present invention concerns the field of fluid catalytic cracking (FCC) processes. The invention provides a process increasing production of LPG and propene in FCC units operating under conditions of maximisation of middle distillates of low aromaticity, such that they may be incorporated into the diesel oil pool. The invention also relates to the preparation and employment of additives based on zeolites having small pores, such as ferrierite (FER), in catalytic systems for FCC units, wherein conditions of low severity are adopted with a view to increasing yields of LPG and light olefins whilst improving stability of petrol. The invention also provides an original catalytic system, being more efficient than catalytic systems known in the state of the art, to increase the yield of LPG and propene without prejudicing the yield and quality of LCO. Furthermore it provides a method of preparation of an additive for said process employing the zeolite ferrierite.

    摘要翻译： 本发明涉及流化催化裂化（FCC）方法领域。 本发明提供一种加工生产液化石油气和丙烯的方法，其中FCC装置在低芳烃中间馏分最大化的条件下运行，使得它们可以并入柴油池中。 本发明还涉及在FCC单元的催化体系中制备和使用基于具有小孔的沸石的添加剂，例如镁碱沸石（FER），其中采用低严重性的条件以提高LPG和轻质烯烃的产率 同时提高汽油的稳定性。 本发明还提供了比现有技术中已知的催化体系更有效的原始催化体系，以增加LPG和丙烯的产率而不损害LCO的产率和质量。 此外，它提供了使用沸石镁碱沸石的所述方法的添加剂的制备方法。

    FCC process for the maximization of medium distillates
    10.
    发明申请
    FCC process for the maximization of medium distillates 审中-公开
    FCC工艺可以使中等馏出物达到最大化

    公开(公告)号：US20070095724A1

    公开(公告)日：2007-05-03

    申请号：US11545443

    申请日：2006-10-11

    申请人： Claudia Maria de Lacerda Alvarenga Baptista ,  William Richard Gilbert

    发明人： Claudia Maria de Lacerda Alvarenga Baptista ,  William Richard Gilbert

    IPC分类号： C10G11/00

    CPC分类号： C10G11/18

    摘要： A FCC process for the maximization of medium distillates from feedstocks of different sources, by the contact of the feedstock which circulates in a riser reactor together with a fine particulate catalyst from a regenerator (6), under FCC conditions of maximum LCO, at temperatures between about 480° C. and about 520° C., in the absence of added hydrogen, and with injection of coolant or quench to a riser ascendant R, and where the process consists of the injection of a coolant proportion between about 200 and about 50 kg/m3 of feedstock, preferably between about 100 and about 50 kg/m3 of feedstock, in a zone (3) of the riser ascendant R in a position located between about 25% and about 50% of the height of said riser R above the feedstock inlet mouths (2), the injection in this position resulting in the increase of the catalyst circulation and the temperature increase in the starting segment of the riser, yielding the production of medium distillates with low aromatic compounds content and bottoms conversion lower than when the coolant injection is employed in the base of the riser R as it is handled in the prior art processes.

    摘要翻译： FCC方法，通过在最高LCO的FCC条件下，通过在提升管反应器中循环的原料与来自再生器（6）的细颗粒催化剂的原料的接触在不同来源的原料中最大化中间馏分， 约480℃和约520℃，在没有加入氢气的情况下，并且注入冷却剂或骤冷至提升管上升R，并且其中该方法包括注入冷却剂比例为约200至约50 kg / m 3的原料，优选在约100至约50kg / m 3原料之间，在提升器上升R的区域（3）中位于 在原料入口（2）上方的所述提升管R的高度的约25％至约50％之间，在该位置的注入导致催化剂循环的增加和提升管的起始段中的温度升高，产生 中间馏分的生产 低芳族化合物含量和底部转化率比在现有技术方法处理时在提升管R的基底中使用冷却剂注入时低。