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1.发明授权Additive to maximize GLP and propene suitable for use in low-severity operations of a fluid catalytic cracking unit and its preparatory process 有权最大化GLP和丙烯的添加剂，适用于流化催化裂化装置的低强度操作及其制备过程公开(公告)号：US07691768B2
公开(公告)日：2010-04-06
申请号：US11714117
申请日：2007-03-06
IPC分类号： B01J29/06
CPC分类号： B01J29/405 , B01J37/0045 , B01J37/06 , B01J37/08 , B01J2229/20 , B01J2229/40 , B01J2229/42 , C10G11/05 , C10G11/18
摘要： A process for the preparation and modification of additives, with a zeolite base and a high silica alumina ratio (SAR) like the ZSM-5, to increase the yield of propene and LPG in low severity FCC operations, that seeks to maximize the production of medium-distillates with low aromaticity and to minimize molecular cracking in the LCO range. The additives involved guarantee an increase in light olefin yields without altering the yield or the quality of the LCO produced. The innovative process includes surprising actions from rare earths (RE) on the active sites of zeolite, that at once partially block their pores and, in this way, make molecular cracking in the medium-distillate range difficult, which preferably occur at low reaction temperatures and keeps the remaining sites quite active. These sites are sufficiently active to crack smaller molecules in the gasoline range, guaranteeing an overall increase in light olefins and allowing the additive involved to be used industrially in operations to maximize medium-distillates in an FCC unit. This new additive may be obtained by modifying any commercial ZSM-5 zeolite additive.
摘要翻译： 一种用于制备和改性添加剂的方法，具有沸石基质和高ZSM-5的高二氧化硅氧化铝比（SAR），以提高低浓度FCC操作中丙烯和LPG的产率，从而最大限度地提高生产 具有低芳香度的中等馏出物，并使LCO范围内的分子裂解最小化。 所涉及的添加剂保证轻烯烃产量的增加，而不改变生产的LCO的产率或质量。 创新的方法包括来自稀土（RE）对沸石活性位点的惊人的作用，其一度部分阻断其孔，并且以这种方式使中等馏出物范围内的分子裂解困难，优选在低反应温度下发生 并保持其余的网站相当活跃。 这些位点具有足够的活性以在汽油范围内裂解较小的分子，保证轻质烯烃的总体增加，并允许所涉及的添加剂在工业上用于FCC装置中的中等馏出物的最大化。 这种新添加剂可以通过改变任何商业的ZSM-5沸石添加剂来获得。
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2.发明申请Additive to maximize GLP and propene suitable for use in low-severity operations of a fluid catalytic cracking unit and its preparatory process 有权最大化GLP和丙烯的添加剂，适用于流化催化裂化装置的低强度操作及其制备过程公开(公告)号：US20080015105A1
公开(公告)日：2008-01-17
申请号：US11714117
申请日：2007-03-06
IPC分类号： B01J29/04
CPC分类号： B01J29/405 , B01J37/0045 , B01J37/06 , B01J37/08 , B01J2229/20 , B01J2229/40 , B01J2229/42 , C10G11/05 , C10G11/18
摘要： A process for the preparation and modification of additives, with a zeolite base and a high silica alumina ratio (SAR) like the ZSM-5, to increase the yield of propene and LPG in low severity FCC operations, that seeks to maximize the production of medium-distillates with low aromaticity and to minimize molecular cracking in the LCO range. The additives involved guarantee an increase in light olefin yields without altering the yield or the quality of the LCO produced. The innovative process includes surprising actions from rare earths (RE) on the active sites of zeolite, that at once partially block their pores and, in this way, make molecular cracking in the medium-distillate range difficult, which preferably occur at low reaction temperatures and keeps the remaining sites quite active. These sites are sufficiently active to crack smaller molecules in the gasoline range, guaranteeing an overall increase in light olefins and allowing the additive involved to be used industrially in operations to maximize medium-distillates in an FCC unit. This new additive may be obtained by modifying any commercial ZSM-5 zeolite additive.
摘要翻译： 一种用于制备和改性添加剂的方法，具有沸石基质和高ZSM-5的高二氧化硅氧化铝比（SAR），以提高低浓度FCC操作中丙烯和LPG的产率，从而最大限度地提高生产 具有低芳香度的中等馏出物，并使LCO范围内的分子裂解最小化。 所涉及的添加剂保证轻烯烃产量的增加，而不改变生产的LCO的产率或质量。 创新的方法包括来自稀土（RE）对沸石活性位点的惊人的作用，其一度部分阻断其孔，并且以这种方式使中等馏出物范围内的分子裂解困难，优选在低反应温度下发生 并保持其余的网站相当活跃。 这些位点具有足够的活性以在汽油范围内裂解较小的分子，保证轻质烯烃的总体增加，并允许所涉及的添加剂在工业上用于FCC装置中的中等馏出物的最大化。 这种新添加剂可以通过改变任何商业的ZSM-5沸石添加剂来获得。
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3.发明申请CATALYTIC SYSTEM AND ADDITIVE FOR MAXIMISATION OF LIGHT OLEFINS IN FLUID CATALYTIC CRACKING UNITS IN OPERATIONS OF LOW SEVERITY 审中-公开催化体系和添加剂在液体催化裂化装置中在低严重运行中最大化烯烃公开(公告)号：US20090107885A1
公开(公告)日：2009-04-30
申请号：US12260181
申请日：2008-10-29
摘要： The present invention concerns the field of fluid catalytic cracking (FCC) processes. The invention provides a process increasing production of LPG and propene in FCC units operating under conditions of maximisation of middle distillates of low aromaticity, such that they may be incorporated into the diesel oil pool. The invention also relates to the preparation and employment of additives based on zeolites having small pores, such as ferrierite (FER), in catalytic systems for FCC units, wherein conditions of low severity are adopted with a view to increasing yields of LPG and light olefins whilst improving stability of petrol. The invention also provides an original catalytic system, being more efficient than catalytic systems known in the state of the art, to increase the yield of LPG and propene without prejudicing the yield and quality of LCO. Furthermore it provides a method of preparation of an additive for said process employing the zeolite ferrierite.
摘要翻译： 本发明涉及流化催化裂化（FCC）方法领域。 本发明提供一种加工生产液化石油气和丙烯的方法，其中FCC装置在低芳烃中间馏分最大化的条件下运行，使得它们可以并入柴油池中。 本发明还涉及在FCC单元的催化体系中制备和使用基于具有小孔的沸石的添加剂，例如镁碱沸石（FER），其中采用低严重性的条件以提高LPG和轻质烯烃的产率 同时提高汽油的稳定性。 本发明还提供了比现有技术中已知的催化体系更有效的原始催化体系，以增加LPG和丙烯的产率而不损害LCO的产率和质量。 此外，它提供了使用沸石镁碱沸石的所述方法的添加剂的制备方法。
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公开(公告)号：US09919985B2
公开(公告)日：2018-03-20
申请号：US14382477
申请日：2012-03-02
申请人： Raquel Bastiani , Lam Yiu Lau , Andrea de Rezende Pinho , Rosana Wasserman , Ivanilda Barboza do Espirito Santo
发明人： Raquel Bastiani , Lam Yiu Lau , Andrea de Rezende Pinho , Rosana Wasserman , Ivanilda Barboza do Espirito Santo
CPC分类号： C07C4/06 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/80 , C07C2529/85 , C10G11/05 , C10G11/18 , C10G2400/20
摘要： Additives for mixing into the base catalyst inventory of the fluid catalytic cracking (FCC) process units, so as to achieve a high selectivity of light olefins (ethylene and propylene), are described. Such additives comprise an FER zeolite and an MFI zeolite, the MFI zeolite preferably being zeolite ZSM-5. The mixture of the additive in a concentration greater than 2% w/w relative to the base catalyst of an FCC unit allows greater selectivity for light olefins, propylene and ethylene, while maintaining catalytic activity.
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