公开(公告)号：US07638590B2

公开(公告)日：2009-12-29

申请号：US11172662

申请日：2005-06-24

Applicant: Tatsuki Fukui ,  Tetsuya Yano ,  Chieko Mihara ,  Shinya Kozaki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Ako Kusakari

Inventor： Tatsuki Fukui ,  Tetsuya Yano ,  Chieko Mihara ,  Shinya Kozaki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Ako Kusakari

IPC: G03G9/097

CPC classification number: C08G63/912 ,  C08G63/6852 ,  C08G63/6882 ,  G03G9/08755 ,  G03G9/08791

Abstract: The invention provides a novel polyester adapted for use in a charge control agent for a toner for an electrophotographic process, having a charge stability, a high charge amount, an improved dispersibility and a biodegradability, and a producing method and an application technology therefore. According to the invention, there is provided polyhydroxyalkanoate comprising at least one unit represented by the following chemical formula in a molecule: —(O—CH(—(CH2)m—CH2-p-C6H4—CONH-A1SO2R1)CH2CO)— (wherein R1 represents OH, a halogen atom, ONa, OK or OR1a; A1 and R1a each represents a substituted or unsubstituted aliphatic hydrocarbon structure, a substituted or unsubstituted aromatic cyclic structure or a substituted or unsubstituted heterocyclic structure; m represents an integer selected from a range of 0 to 7; and R1, A1, R1a and m have the aforementioned meanings independently for each unit when plural units are present), a charge control agent containing such polyhydroxyalkanoate, a toner utilizing such charge control agent, and an image forming method and an image forming apparatus utilizing such toner.

Abstract translation: 本发明提供了适用于用于电子照相方法的调色剂的电荷控制剂的新型聚酯，其具有电荷稳定性，高电荷量，改进的分散性和生物降解性，以及其制备方法和应用技术。 根据本发明，提供了在分子中包含至少一个由以下化学式表示的单元的聚羟基链烷酸酯： - （O-CH（ - （CH 2）m -CH 2-p-C 6 H 4 -CONH-AlSO 2 R 1）CH 2 CO） - （ 其中R1表示OH，卤素原子，ONa，OK或OR1a; A1和R1a各自表示取代或未取代的脂族烃结构，取代或未取代的芳族环状结构或取代或未取代的杂环结构; m表示选自 范围为0至7; R1，A1，R1a和m在存在多个单元时对于每个单元具有上述含义），含有这种聚羟基链烷酸酯的电荷控制剂，使用该电荷控制剂的调色剂和图像形成方法 以及利用这种调色剂的图像形成装置。

公开(公告)号：US07470768B2

公开(公告)日：2008-12-30

申请号：US10581698

申请日：2005-06-09

Applicant: Takashi Kenmoku ,  Tatsuki Fukui ,  Chieko Mihara ,  Ako Kusakari ,  Tetsuya Yano

Inventor： Takashi Kenmoku ,  Tatsuki Fukui ,  Chieko Mihara ,  Ako Kusakari ,  Tetsuya Yano

IPC: C08F6/00 ,  C08C1/14

CPC classification number: C08G63/912 ,  C08G63/6852 ,  C08G63/6882

Abstract: To provide a novel polyhydroxyalkanoate having a reactive functional group in a molecule and a method of producing the same; and a novel polyhydroxyalkanoate having a new function obtained by chemically modifying the polyhydroxyalkanoate having a reactive functional group and a method of producing the same. By utilizing a vinyl group of a polyhydroxyalkanoate containing a unit having the vinyl group at a side chain thereof, a polyhydroxyalkanoate containing units having a carboxyl group, an amide group, and a sulfonic group in a molecule is induced.

Abstract translation: 提供分子中具有反应性官能团的新型聚羟基链烷酸酯及其制造方法， 和具有通过化学改性具有反应性官能团的聚羟基链烷酸酯获得的新功能的新型聚羟基链烷酸酯及其制备方法。 通过使用含有在其侧链具有乙烯基的单元的聚羟基链烷酸酯的乙烯基，分子中含有含有羧基，酰胺基和磺酸基的单元的聚羟基链烷酸酯。

公开(公告)号：US07465779B2

公开(公告)日：2008-12-16

申请号：US10567762

申请日：2005-06-09

Applicant: Takashi Kenmoku ,  Tatsuki Fukui ,  Chieko Mihara ,  Ako Kusakari ,  Tetsuya Yano

Inventor： Takashi Kenmoku ,  Tatsuki Fukui ,  Chieko Mihara ,  Ako Kusakari ,  Tetsuya Yano

IPC: C08G63/02

CPC classification number: C08G63/6852 ,  C08G63/6882 ,  C08G63/912

Abstract: A novel polyhydroxyalkanoate having a reactive functional group in a molecule, and a production method thereof, etc. are provided. By utilizing the vinyl group of polyhydroxyalkanoate which contains a unit having a vinyl group on a side chain, a polyhydroxyalkanoate which contains a carboxyl group and a unit having an amide group and a sulfonic acid group in a molecule is derived.

Abstract translation: 提供了分子中具有反应性官能团的新型聚羟基链烷酸酯及其制造方法等。 通过在侧链上使用含有乙烯基单元的聚羟基链烷酸酯的乙烯基，得到分子中含有羧基的聚羟基链烷酸酯和具有酰胺基和磺酸基的单元。

公开(公告)号：US07459517B2

公开(公告)日：2008-12-02

申请号：US10531226

申请日：2003-10-23

Applicant: Tatsuki Fukui ,  Tetsuya Yano ,  Chieko Mihara ,  Shinya Kozaki ,  Tsutomu Honma ,  Takashi Kenmoku

Inventor： Tatsuki Fukui ,  Tetsuya Yano ,  Chieko Mihara ,  Shinya Kozaki ,  Tsutomu Honma ,  Takashi Kenmoku

IPC: C08G63/02 ,  C08G63/91 ,  C12P7/62 ,  C08G9/08

CPC classification number: G03G9/08755 ,  C08G63/06 ,  C08G63/6852 ,  C08G63/6882 ,  C08G63/912 ,  C08L67/04 ,  C08L101/00 ,  C12P7/625 ,  C08L2666/02

Abstract: A novel polyhydroxyalkanoate having a monomer unit represented by the formula (1), the unit having a carboxyl group substituting a ring structure at the end of side chain, obtainable by oxydizing vinyl or methyl group substituting a ring structure at the end of the side chain. The polyhydroxyalkanoate has high thermal stability, charge stablity, a high charge amount, improved dispersibility and biodegradability together, and therefore, suitable for resin moldings, and binders and charge controlling agents for toners used in the electrophotographic process.

Abstract translation: 一种具有由式（1）表示的单体单元的新型聚羟基链烷酸酯，该单元具有在侧链末端取代环结构的羧基，可通过在侧链末端以环状结构取代乙烯基或甲基取代 。 聚羟基链烷酸酯具有高的热稳定性，电荷稳定性，高电荷量，一起提高的分散性和生物降解性，因此适用于电子照相方法中用于调色剂的树脂模制品和粘合剂和电荷控制剂。

公开(公告)号：US07452960B2

公开(公告)日：2008-11-18

申请号：US10532136

申请日：2003-10-24

Applicant: Tetsuya Yano ,  Chieko Mihara ,  Shinya Kozaki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

Inventor： Tetsuya Yano ,  Chieko Mihara ,  Shinya Kozaki ,  Tsutomu Honma ,  Takashi Kenmoku ,  Tatsuki Fukui

IPC: G03G9/00 ,  C12P11/00

CPC classification number: G03G9/08791 ,  C08G63/6882 ,  C08G63/912 ,  C08L23/10 ,  C08L25/06 ,  C08L67/02 ,  C08L67/04 ,  C08L75/00 ,  C08L77/00 ,  C12P7/625 ,  G03G9/08755 ,  G03G9/08757 ,  Y10T428/24083 ,  Y10T428/24099 ,  Y10T428/2424 ,  Y10T428/24322 ,  C08L2666/04 ,  C08L2666/02

Abstract: A polyhydroxyalkanoate copolymer comprises one kind of unit of —[OCH((CH2)x—SOC6H5R)CH2CO]— (n=1-7)  (1) (wherein R is any one of H, halogen, CN, NO2, COOR′, SO2R″ (R′ is any one of H, Na, K, CH3 and C2H5; R″ is any one of OH, ONa, OK, halogen, OCH3 and OC2H5), CH3, C2H5, C3H7, (CH3)2—CH and (CH3)3—C) and —[OCH((CH2)x—SO2C6H5R)CH2CO]— (n=1-7)  (2) (wherein R is any one of H, halogen, CN, NO2, COO R′, SO2R″ (R′ is any one of H, Na, K, CH3 and C2H5; R″ is any one of OH, ONa, OK, halogen, OCH3 and OC2H5), CH3, C2H5, C3H7, (CH3)2—CH and (CH3)3—C) and at least one unit of chemical formulae (3) to (6): —[OCH((CH2)m—Rz)CH2CO]— (n=1-8)   (3) (wherein Rz comprises a residue having either a phenyl structure or a thienyl structure), —[OCH((CH2)k—C6H11Ra)CH2CO]— (n=1-8)  (4) (wherein Ra is any one of H, CN, NO2, halogen, CH3, C2H5, C3H7, CF3, C2F5 and C3F7) —[OCH((CH2)n—CH═CH2)CH2CO]— (n=1-8), and  (5) —[OCH((CH2)n—COORb)CH2CO]— (n=1-8)  (6) (wherein Rb is any one of H, Na and K).

公开(公告)号：US20070059627A1

公开(公告)日：2007-03-15

申请号：US10557413

申请日：2005-05-11

Applicant: Tatsuki Fukui ,  Takashi Kenmoku ,  Ako Kusakari ,  Chieko Mihara ,  Tetsuya Yano ,  Norikazu Fujimoto

Inventor： Tatsuki Fukui ,  Takashi Kenmoku ,  Ako Kusakari ,  Chieko Mihara ,  Tetsuya Yano ,  Norikazu Fujimoto

IPC: G03G9/00

CPC classification number: C08F8/34 ,  C07C309/15 ,  C07C309/51 ,  C07C309/69 ,  C07C309/76 ,  C08F8/14 ,  C08F212/08 ,  C08F220/58 ,  C08F2220/585 ,  G03G9/08726 ,  G03G9/097 ,  C08F220/14

Abstract: A polymer is provided in which a sulfonic group or a derivative thereof is introduced. The polymer includes a unit represented by the following chemical formula (1): wherein R represents -A1-SO2R1; A1 is selected from an alkylene group, a heterocyclic ring, an aromatic ring; and —SO2R1 is a sulfonic group or of a derivative of a sulfonic acid.

Abstract translation: 提供其中引入了磺酸基或其衍生物的聚合物。 聚合物包括由以下化学式（1）表示的单元：其中R表示-A 1 -SO 2 R 2 R 1。 A 1选自亚烷基，杂环，芳环; 和-SO 2 R 1是磺酸基或磺酸衍生物。

公开(公告)号：US20060127786A1

公开(公告)日：2006-06-15

申请号：US11298540

申请日：2005-12-12

Applicant: Etsuko Sugawa ,  Chieko Mihara ,  Takashi Kenmoku ,  Tatsuki Fukui ,  Shinya Kozaki ,  Tsutomu Honma ,  Tetsuya Yano ,  Shigeki Yoshida

Inventor： Etsuko Sugawa ,  Chieko Mihara ,  Takashi Kenmoku ,  Tatsuki Fukui ,  Shinya Kozaki ,  Tsutomu Honma ,  Tetsuya Yano ,  Shigeki Yoshida

IPC: G03G9/097 ,  G03G9/087

CPC classification number: G03G9/08708 ,  G03G9/081 ,  G03G9/0821 ,  G03G9/0825 ,  G03G9/08704 ,  G03G9/08728 ,  G03G9/08733 ,  G03G9/08757 ,  G03G9/08791 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/09733

Abstract: To provide a toner for developing electrostatic images which is not easily cause the phenomenon of toner-spent, constituent materials are so selected that a charge control resin has hardness which is the same as the hardness of a binder resin or the charge control resin is harder than the binder resin, as measured with a scanning probe microscope in a viscoelasticity evaluation mode in respect to the binder resin and the charge control resin which are present in the particle interiors or particle surfaces of the toner.

Abstract translation: 为了提供用于显影静电图像的调色剂，其不容易引起调色剂消耗的现象，构成材料被选择成使得电荷控制树脂具有与粘合剂树脂的硬度相同的硬度或电荷控制树脂更硬 相对于存在于调色剂的颗粒内部或颗粒表面中的粘合剂树脂和电荷控制树脂，以粘弹性评价模式的扫描探针显微镜测量。

公开(公告)号：US20060030675A1

公开(公告)日：2006-02-09

申请号：US11246110

申请日：2005-10-11

Applicant: Hiroshi Maehara ,  Chieko Mihara ,  Yoshihiko Kikuchi

Inventor： Hiroshi Maehara ,  Chieko Mihara ,  Yoshihiko Kikuchi

IPC: C08C19/22 ,  C08F110/00

CPC classification number: C08J11/10 ,  C08F8/14 ,  C08F8/32 ,  C08F2810/40 ,  C08G81/021 ,  Y02W30/702 ,  C08F112/08

Abstract: A novel resin is provided which is renewable with less energy. A process for renewing the resin is also provided. The present invention includes a polymer having the repeating unit represented by Structural Formula (1) below, and a process for producing the polymer: [—P1—R—]n (1). In the formula, P1 indicates an addition polymer moiety having a continuous hydrocarbon chain as the skeleton containing no condensation system, and is a polymer or oligomer prepared by addition polymerization of one or more monomers having a double bond; R indicates a linking group constituted of a condensation system for linking the polymer moieties P; and n is a number of repeating units and is an integer of 2 or more.

Abstract translation: 提供了一种新型树脂，可以以更少的能量再生。 还提供了更新树脂的方法。 本发明包括具有下述结构式（1）表示的重复单元的聚合物和聚合物的制备方法：[-P R - ] n < （1）。 在该式中，P 1'表示具有连续烃链作为不含缩合体系的骨架的加成聚合物部分，是通过一种或多种具有双键的单体的加成聚合制备的聚合物或低聚物 ; R表示由用于连接聚合物部分P的缩合体系构成的连接基团; n为重复单元数，为2以上的整数。

公开(公告)号：US5962305A

公开(公告)日：1999-10-05

申请号：US904018

申请日：1997-07-31

Applicant: Chieko Mihara ,  Tetsuya Yano ,  Shinya Kozaki ,  Takeshi Imamura

Inventor： Chieko Mihara ,  Tetsuya Yano ,  Shinya Kozaki ,  Takeshi Imamura

IPC: A62D3/00 ,  A62D3/02 ,  B01D53/84 ,  B09C1/10 ,  C02F3/34 ,  C12N1/20 ,  C12R1/01 ,  C12S5/00 ,  C12S9/00 ,  B09B3/00

CPC classification number: C12R1/15 ,  A62D3/02 ,  B01D53/84 ,  B09C1/10 ,  C02F3/34 ,  A62D2101/22 ,  A62D2101/28

Abstract: A novel microbial strain JMC1 (FERM BP-5960) that it is a mutant strain derived from JM1 (FERM BP-5352) constitutively expressing oxygenase, and a method for biodegrading aromatic compounds and chlorinated organic compounds by using strain JMC1 as well as a method for environmental remediation which comprises a step of biodegrading contaminant in the environment by using strain JMC1. Aromatic compounds and/or chlorinated aliphatic hydrocarbon compounds contained in the environment can be removed at a low temperature by using the novel strain JMC1 without using any inducer substances.

Abstract translation: 作为构成型表达加氧酶的JM1（FERM BP-5352）的突变菌株的新型微生物菌株JMC1（FERM BP-5960），使用菌株JMC1生物降解芳香族化合物和氯化有机化合物的方法以及方法 用于环境修复，其包括通过使用菌株JMC1在环境中生物降解污染物的步骤。 环境中含有的芳族化合物和/或氯化脂族烃化合物可以在低温下通过使用新型菌株JMC1而不使用任何诱导物质来除去。

公开(公告)号：US5492792A

公开(公告)日：1996-02-20

申请号：US58761

申请日：1993-05-10

Applicant: Miki Tamura ,  Tsuyoshi Santoh ,  Chieko Mihara

Inventor： Miki Tamura ,  Tsuyoshi Santoh ,  Chieko Mihara

IPC: G11B7/247 ,  G11B7/2472 ,  G11B7/24 ,  G11B7/26

CPC classification number: G11B7/247 ,  G11B7/2472 ,  Y10S430/146

Abstract: An optical recording medium of the present invention has a recording layer containing an organic coloring matter expressed by the following formula (I) or (II): ##STR1## wherein R.sub.0 through R.sub.5 each indicate a hydrogen atom or an monovalent organic residue, at least one of R.sub.0 through R.sub.3 being a fluorine-containing monovalent organic residue; m indicates 0, 1 or 2; and X.sup..crclbar. indicates an anion residue. ##STR2## wherein X.sup..crclbar. indicates an anion residue; m indicates 0, 1 or 2; and R.sub.0' and R.sub.3' are atoms forming combinations of R.sub.0' and R.sub.1', and R.sub.2', and R.sub.3' at least one of which forms, with a nitrogen atom, a fluorine-containing substituted or unsubstituted pyrrolidine ring, a fluorine-containing substituted or unsubstituted piperidine ring, a fluorine-containing substituted or unsubstituted morpholine ring, a fluorine-containing substituted or unsubstituted tetrahydropyridine ring, a fluorine-containing substituted or unsubstituted cyclohexylamine ring expressed by the formula ##STR3## and the other substituents each being a hydrogen atom or a monovalent organic residue; and R.sub.4, and R.sub.5, each indicate a hydrogen atom or a monovalent organic residue.

Abstract translation: 本发明的光记录介质具有含有下式（I）或（II）表示的有机色素的记录层：其中R 0〜R 5分别表示氢原子或一价有机残基 ，R 0〜R 3中的至少一个为含氟一价有机残基; m表示0,1或2; X（ - ）表示阴离子残基。 （II）其中X（ - ）表示阴离子残基; m表示0,1或2; R 0'和R 3'是形成R 0'和R''的组合的原子，R 2'和R 3'至少一个与氮原子一起形成含氟取代或未取代的吡咯烷环，含氟 取代或未取代的哌啶环，含氟取代或未取代的吗啉环，含氟取代或未取代的四氢吡啶环，由式为氢原子或一价有机残基的含氟取代或未取代的环己胺环; R 4和R 5各自表示氢原子或一价有机残基。