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659 条记录 (耗时 0.021 秒)

    Aqueous stable suspension of water insoluble silicate capable of binding calcium ions and its use for the production of washing and cleansing agents
    81.
    发明授权
    Aqueous stable suspension of water insoluble silicate capable of binding calcium ions and its use for the production of washing and cleansing agents 失效
    能够结合钙离子的水不溶性硅酸盐的水性稳定悬浮液及其用于生产洗涤和清洁剂的用途

    公开(公告)号：US4486331A

    公开(公告)日：1984-12-04

    申请号：US475394

    申请日：1983-03-15

    申请人： Manfred Diehl ,  Roland Bergmann ,  Gunter Stadtmuller

    发明人： Manfred Diehl ,  Roland Bergmann ,  Gunter Stadtmuller

    IPC分类号： B01F17/42 ,  B01J39/14 ,  C01B39/06 ,  C01B39/14 ,  C11D1/72 ,  C11D3/12 ,  C11D1/66

    CPC分类号： C11D3/1286

    摘要： There are provided aqueous pumpable stable suspensions of a water insoluble silicate capable of binding calcium ions which contain based on the total weight of the aqueous suspension(A) as the silicate capable of binding calcium 0.5 to 80 weight percent of a finely divided, bound water containing, synthetically produced, water insoluble compound of the general formula(Cat.sub.2/n O).sub.x.Me.sub.2 O.sub.3.(SiO.sub.2).sub.y (I),in which Cat is a cation exchangeable with calcium and which has the valence n, x is a number from 0.7 to 1.5, Me is boron or aluminum and y is a number between 0.8 and 6 and(B) as a dispersingly active component 0.5 to 6 weight percent of a mixture of at least two different alkylphenolethoxylates of the formula ##STR1## where R is an alkyl group of 1 to 15 carbon atoms. The component A especially can be a zeolite A while component B can consist of two alkylphenolethoxylates of formula (II) in which m is 2 to 7 and m is 8 to 15. The suspension can be employed for the production of powdery washing agents and detergents.

    摘要翻译： 提供了能够结合钙离子的水不溶性硅酸盐的水性可泵送稳定的悬浮液，其含有基于水性悬浮液（A）的总重量，其为能够结合钙0.5至80重量％的细碎结合水的硅酸盐 含有合成产生的水不溶性的通式（Cat2 / nO）x.Me2O3。（SiO2）y（Ⅰ）的化合物，其中Cat是可与钙交换的阳离子，其中n为正数，x为数 0.7至1.5，Me是硼或铝，y是0.8和6之间的数，和（B）作为分散活性组分0.5至6重量％的至少两种不同的式（II）的烷基苯酚乙氧基化物的混合物， 其中R是1至15个碳原子的烷基。 组分A特别可以是沸石A，而组分B可以由两种式（II）的烷基苯酚乙氧基化物组成，其中m为2至7，m为8至15.该悬浮液可用于生产粉状洗涤剂和洗涤剂 。

    Low-foaming, pH sensitive, alkylamine polyether surface active agents and methods for using
    82.
    发明授权
    Low-foaming, pH sensitive, alkylamine polyether surface active agents and methods for using 失效
    低发泡，pH敏感，烷基胺聚醚表面活性剂和使用方法

    公开(公告)号：US4483741A

    公开(公告)日：1984-11-20

    申请号：US406885

    申请日：1982-08-10

    申请人： James E. Maloney ,  James A. McDonell

    发明人： James E. Maloney ,  James A. McDonell

    IPC分类号： C08G65/00 ,  B01F17/00 ,  B01F17/42 ,  B01F17/46 ,  B03D1/01 ,  C07C67/00 ,  C07C213/00 ,  C07C217/08 ,  C07C217/50 ,  C08G65/26 ,  C08G65/32 ,  D21C5/02 ,  D21H17/07 ,  D21H17/53

    CPC分类号： B03D1/01 ,  B01F17/0042 ,  B03D1/0043 ,  C08G65/2624 ,  D21C5/022 ,  D21H17/53 ,  Y02W30/648

    摘要： Alkylamine polyether surface active agent compositions and methods for using are described. The instant compositions are low foaming, and pH sensitive and are generally of the structure: ##STR1## in which (a) R.sub.1 may be hydrogen or alkyl;if R.sub.1 is hydrogen then R.sub.2, R.sub.3 and R.sub.4 must be alkyl having a total number of carbon atoms falling in the range of 7 to 23;if R.sub.1 is alkyl, then R.sub.2, R.sub.3 and R.sub.4 may be alkyl or hydrogen, the total number of carbon atoms in R.sub.1 +R.sub.2 +R.sub.3 +R.sub.4 falling in the range of 7 to 36 (preferably about 10 to 20);(b) The --(C.sub.2 H.sub.4 O).sub.m -- segment must be a poly(oxyethylene) homogeneous chain or "block" polymer (i.e., a homopolymer), m having an average value in the range of 1 to 15, preferably 5 to 13; and(c) Y is selected from the group consisting of:(1) homogeneous poly(oxypropylene) chain (PO) "block" polymer or residue (i.e., a homopolymer), of the structure --(C.sub.3 H.sub.6 O).sub.n H, n having a value in the range of 1 to 50, preferably 6 to 30;(2) hydrophobic end cap (e.g., --CH.sub.2 --.phi.); and(3) hydrophobic end capped polyoxypropylene residue.A particularly preferred class of surfactants of the instant invention constitutes 1,1,1-trialkylmethylamine ethyleneoxy(EO)-propyleneoxy(PO) polyethers having from 1 to 15 moles of ethyleneoxide residue and from 1 to 50 moles of propyleneoxide per mole of alkylmethylamine.The methods of the instant invention generally relate to the production of paper from secondary fiber. Unexpectedly, the compositions of the instant invention are found to be applicable in the common methods employed very pH sensitive, size-safe and to produce paper products from secondary fiber.

    摘要翻译： 描述了烷基胺聚醚表面活性剂组合物和使用方法。 本发明的组合物是低发泡和pH敏感的并且通常具有以下结构：其中（a）R 1可以是氢或烷基; 如果R1是氢，则R2，R3和R4必须是总碳原子数落在7-23的范围内的烷基; 如果R 1是烷基，则R 2，R 3和R 4可以是烷基或氢，R 1 + R 2 + R 3 + R 4中的碳原子总数落在7〜36（优选约10〜20）的范围内。 （b） - （C 2 H 4 O）m-链段必须是聚（氧乙烯）均匀链或“嵌段”聚合物（即均聚物），m的平均值在1至15，优选5至13的范围内; 和（c）Y选自：（1）均匀的聚（氧丙烯）链（PO）“嵌段”聚合物或残基（即均聚物），结构 - （C 3 H 6 O）n H，n具有 值在1至50，优选6至30的范围内; （2）疏水端帽（例如-CH 2 - phi）; 和（3）疏水封端的聚氧丙烯残基。 本发明特别优选的一类表面活性剂构成了每摩尔烷基甲基胺具有1至15摩尔环氧乙烷残基和1至50摩尔环氧丙烷的1,1,1-三烷基甲胺亚乙氧基（EO） - 亚丙基氧基（PO）聚醚。 本发明的方法通常涉及从次级纤维生产纸张。 意外地发现，本发明的组合物被发现适用于非常pH敏感，尺寸安全并且从次级纤维生产纸产品的常用方法。

    Composition and process for recovering and upgrading petroleum products
    83.
    发明授权
    Composition and process for recovering and upgrading petroleum products 失效
    回收和升级石油产品的组成和过程

    公开(公告)号：US4474622A

    公开(公告)日：1984-10-02

    申请号：US414344

    申请日：1982-08-16

    申请人： Marc-Andre Forster

    发明人： Marc-Andre Forster

    IPC分类号： C11D7/50 ,  B01D17/04 ,  B01F17/00 ,  B01F17/42 ,  B63B57/02 ,  C09K8/524 ,  C09K8/584 ,  C10G1/04 ,  C10G29/20 ,  C11D3/43 ,  E21B43/40 ,  B08B9/08 ,  C11D3/26 ,  C11D3/30 ,  C11D3/34

    CPC分类号： B63B57/02 ,  B01D17/047 ,  B01F17/0042 ,  C09K8/524 ,  C09K8/584 ,  C10G1/04 ,  C11D3/43 ,  E21B43/40 ,  Y10S507/929

    摘要： A composition for recovering and upgrading sludge that accumulates in vessels for storing and transporting petroleum products comprises a solvent made up of at least one aliphatic hydrocarbon and at least one aromatic monohalogenated hydrocarbon of the benzene or naphthalene type, together with a demulsifying and dispersing agent that is an aliphatic straight-chain oxyethylated amineated derivative or a quaternary ammonium compound having at least one alkyl and at least one aryl residue in the form of thiocyano derivative.The composition is dissolved in a hydrocarbon in a proportion of from 2 to 10% by weight, the resulting solution is projected on to the residues at a pressure of from 2 to 15 bars, and the resulting suspension is recycled, recovered, and treated like crude oil.The invention is applied to the recovery and upgrading of sludges which accumulate in storage vessels and petroleum product transport vessels, whether they are on the ground or on land or sea transport vessels.

    摘要翻译： PCT No.PCT / FR81 / 00168 Sec。 371日期1982年8月16日 102（e）日期1982年8月16日PCT提交1981年12月23日PCT公布。 出版物WO82 / 02177 日期：1982年7月8日。用于回收和提炼积聚在用于储存和运输石油产品的容器中的污泥的组合物包括由至少一种脂族烃和至少一种苯或萘型芳族单卤代烃组成的溶剂 具有破乳分散剂，其是脂族直链氧乙基化胺化衍生物或具有至少一个烷基和至少一个硫氰酸衍生物形式的芳基的季铵化合物。 将组合物以2至10重量％的比例溶解在烃中，将所得溶液以2至15巴的压力投影到残留物上，并将所得悬浮液再循环，回收和处理，如 原油。 本发明适用于堆放在储存容器和石油产品运输船舶中的淤泥的回收和升级，无论是在地面上还是陆上或海上运输船上。

    Process for preparing nonionic surfactants-oxyalkylation with promoted barium catalysts
    85.
    发明授权
    Process for preparing nonionic surfactants-oxyalkylation with promoted barium catalysts 失效
    用促进的钡催化剂制备非离子表面活性剂 - 烷氧基化的方法

    公开(公告)号：US4453023A

    公开(公告)日：1984-06-05

    申请号：US454573

    申请日：1982-12-30

    申请人： James H. McCain ,  Louis F. Theiling, Jr.

    发明人： James H. McCain ,  Louis F. Theiling, Jr.

    IPC分类号： C07C41/02 ,  B01F17/42 ,  B01J27/00 ,  B01J27/16 ,  B01J31/00 ,  B01J31/02 ,  B01J31/26 ,  C07B61/00 ,  C07C41/00 ,  C07C41/03 ,  C07C43/11 ,  C07C67/00 ,  C08G65/26 ,  B01J23/02

    CPC分类号： C08G65/2651 ,  C07C41/03

    摘要： The process for preparing nonionic surfactants wherein a narrower molecular weight distribution is obtained by the use of a barium catalyst which comprises reacting a reactive hydrogen compound selected from the group consisting of monohydric alcohols having from about 8 to about 20 carbon atoms and a difunctional polypropylene oxide polymer having an average molecular weight in the range of 1000 to 5000 with an alkylene oxide having 2 to 4 carbon atoms at a temperature at which the reaction proceeds in the presence of at least a catalytic amount of a barium salt selected from the group consisting of barium hydroxide, barium alkoxides, barium phenoxides, hydrates thereof or mixtures thereof and a catalytic amount of an oxyalkylation catalyst promoter.

    摘要翻译： 制备非离子表面活性剂的方法，其中通过使用钡催化剂获得较窄的分子量分布，该钡催化剂包括使选自具有约8至约20个碳原子的一元醇的反应性氢化合物与二官能聚环氧丙烷 在至少催化量的选自以下的钡盐的存在下，在反应进行的温度下，平均分子量为1000-5000的聚合物与具有2至4个碳原子的烯化氧反应， 氢氧化钡，烷氧化钡，苯氧化钡，其水合物或其混合物和催化量的烷氧基化催化剂促进剂。

    Mixed formals of polyglycol ethers
    89.
    发明授权
    Mixed formals of polyglycol ethers 失效

    公开(公告)号：US4418217A

    公开(公告)日：1983-11-29

    申请号：US257632

    申请日：1981-04-27

    申请人： Karl Schmid ,  Margarete Grunert ,  Jochen Heidrich ,  Holger Tesmann

    发明人： Karl Schmid ,  Margarete Grunert ,  Jochen Heidrich ,  Holger Tesmann

    IPC分类号： C07C43/164 ,  B01F17/42 ,  B01J27/00 ,  B01J27/02 ,  B01J27/16 ,  B01J29/00 ,  B01J29/04 ,  B01J31/00 ,  B01J31/02 ,  B01J31/08 ,  C07C41/00 ,  C07C41/48 ,  C07C43/11 ,  C07C43/30 ,  C07C43/315 ,  C07C67/00 ,  C08G4/00 ,  C08G65/00 ,  C08G65/32 ,  C08G65/331 ,  C08G65/34 ,  C11D1/72 ,  C07C41/14

    CPC分类号： C08G65/331 ,  C07C43/30 ,  C08G4/00 ,  C08G65/34 ,  C11D1/721 ,  Y10S516/01

    摘要： A process for the production of a mixed formal of polyglycol ethers having formulae selected from the group consisting of ##STR1## wherein R.sup.1 is a straight or branched chain alkyl having from 1 to 18 carbon atoms, and R.sup.2 is selected from the group consisting of hydrogen and straight or branched chain alkyl having from 1 to 17 carbon atoms, where the sum of the carbon atoms in R.sup.1 plus R.sup.2 is from 6 to 18, R.sup.3 is a member selected from the group consisting of monoalkylphenyl having from 14 to 26 carbon atoms, dialkylphenyl having from 14 to 26 carbon atoms, trialkylphenyl having from 14 to 26 carbon atoms, a straight or branched chain alkyl having from 8 to 22 carbon atoms, a straight or branched chain alkenyl having from 8 to 22 carbon atoms, and a radical having the formula ##STR2## wherein R.sup.1 and R.sup.2 have the above assigned values, and R.sup.5 is selected from the group consisting of a straight or branched chain alkyl having from 1 to 5 carbon atoms, phenyl and alkylphenyl having from 7 to 9 carbon atoms, R.sup.4 is a straight or branched chain alkyl having from 1 to 5 carbon atoms, A and B are selected from the group consisting of ethylene and isopropylene, m and n are integers from 0 to 50, p is an integer from 2 to 50, and q is an integer from 0 to 3, where the sum of m plus n is from 2 to 50, consisting essentially of the steps of(1) reacting a polyglycol ether having the formulae selected from the group consisting of ##STR3## wherein R.sup.1, R.sup.2, R.sup.3, A, m, n and p have the above-assigned meanings, with a diformal having the formulaR.sup.4 --O--(B--O).sub.q --CH.sub.2 --(O--B).sub.q --O--R.sup.4wherein R.sup.4, B and q have the above-assigned meanings, at a temperature of from 60.degree. to 150.degree. C. in the presence of a strong acid, while employing from 2 to 10 mols of said diformal per mol of hydroxyl groups in said polyglycol ether.(2) distilling off the alcohol formed having the formulaR.sup.4 --O--(B--O).sub.q --H(3) neutralizing,(4) distilling of unreacted diformal, and(5) recovering said mixed formal of polyglycol ethers; as well as novel mixed formals of polyglycol ethers produced by the process.