公开(公告)号：US06929679B2

公开(公告)日：2005-08-16

申请号：US10061147

申请日：2002-02-01

Applicant: Ulrich Müller ,  Klaus Harth ,  Markus Hölzle ,  Michael Hesse ,  Lisa Lobree ,  Wolfgang Harder ,  Omar M. Yaghi ,  Mohamed Eddaoudi

Inventor： Ulrich Müller ,  Klaus Harth ,  Markus Hölzle ,  Michael Hesse ,  Lisa Lobree ,  Wolfgang Harder ,  Omar M. Yaghi ,  Mohamed Eddaoudi

IPC: B01D53/02 ,  B01D53/04 ,  B01J20/22 ,  B01J20/26 ,  B01J20/28 ,  B01J20/30 ,  B01J20/32 ,  C01B3/00 ,  F17C11/00 ,  H01M8/04 ,  H01M8/06

CPC classification number: H01M8/065 ,  B01D53/02 ,  B01J20/226 ,  C01B3/001 ,  F17C11/00 ,  F17C11/005 ,  F17C11/007 ,  Y02C10/08 ,  Y02E60/321 ,  Y02E60/327 ,  Y02E60/328 ,  Y10S502/526

Abstract: The present invention relates to the technical field of storing gas including methane and hydrogen, in particular to the fuel cell technology. In particulars it relates to a method of using a metallo-organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound.

Abstract translation: 本发明涉及包括甲烷和氢气在内的气体储存技术领域，特别涉及燃料电池技术领域。 具体地说，本发明涉及使用包含孔和至少一种金属离子和至少一种至少二齿有机化合物的金属 - 有机骨架材料的方法。

公开(公告)号：US20050154222A1

公开(公告)日：2005-07-14

申请号：US10755231

申请日：2004-01-13

Applicant: Ulrich Muller ,  Gerald Lippert ,  Olga Schubert ,  Michael Hesse ,  Reinhard Hess ,  Michael Stosser ,  Omar Yaghi

Inventor： Ulrich Muller ,  Gerald Lippert ,  Olga Schubert ,  Michael Hesse ,  Reinhard Hess ,  Michael Stosser ,  Omar Yaghi

IPC: B01J20/22 ,  C07F3/00 ,  C07F3/06 ,  C07F15/00 ,  C07F15/02

CPC classification number: C07F3/003 ,  B01J20/226

Abstract: A process for preparing an organometallic framework material comprising reacting at least one metal salt with at least one at least bidentate compound capable of coordination to the metal ion of said metal salt, in the presence of an aqueous solvent system and at least one base wherein at least one bidentate compound comprises at least carboxy group and at least one further group which is not a carboxy group and which is capable of forming a hydrogen bridge linkage.

Abstract translation: 一种制备有机金属骨架材料的方法，包括使至少一种金属盐与至少一种能够与所述金属盐的金属离子配位的至少二齿化合物在水性溶剂体系和至少一种碱的存在下反应，其中在 至少一个二齿化合物至少包含羧基和至少一个不是羧基并且能够形成氢桥键的另外的基团。

公开(公告)号：US20050085381A1

公开(公告)日：2005-04-21

申请号：US10984225

申请日：2004-11-09

Applicant: Matthias Irgang ,  Michael Hesse ,  Werner Schnurr

Inventor： Matthias Irgang ,  Michael Hesse ,  Werner Schnurr

IPC: B01J21/06 ,  C01G25/02 ,  B01J23/00 ,  B01J21/04

CPC classification number: B01J21/066 ,  C01G25/02 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/90

Abstract: Catalysts or carriers which consist essentially of monoclinic zirconium dioxide are prepared by pecipitation of zirconium salts with ammonia, by adding a zirconyl nitrate or zirconyl chloride solution to an aqueous ammonia solution at a decreasing pH from 14 to 6 and drying, calcining and pelletizing the product.

Abstract translation: 基本上由单斜晶系二氧化锆组成的催化剂或载体是通过在氨水溶液中加入硝酸氧锆或氧氯化锆溶液，在14至6的降低pH下进行锆的盐化，然后干燥，煅烧和造粒产物 。

公开(公告)号：US20050004404A1

公开(公告)日：2005-01-06

申请号：US10611863

申请日：2003-07-03

Applicant: Ulrich Muller ,  Olga Metelkina ,  Michael Hesse ,  Michael Stoesser ,  Peter Haas ,  Omar Yaghi

Inventor： Ulrich Muller ,  Olga Metelkina ,  Michael Hesse ,  Michael Stoesser ,  Peter Haas ,  Omar Yaghi

IPC: C07C41/03 ,  C07C43/11 ,  C08G18/28 ,  C08G65/26 ,  C08G65/28

CPC classification number: C08G65/2606 ,  C07C41/03 ,  C08G18/283 ,  C08G65/2645 ,  C08G65/266 ,  C08G2101/00 ,  C07C43/11

Abstract: The present invention relates to a process for the alkoxylation of a monool with at least one alkoxylating agent to an alkoxylated alcohol wherein a catalyst is employed which comprises a metallo-organic framework material of metal ions and at least bidentate coordinately bound organic ligands.

Abstract translation: 本发明涉及使用至少一种烷氧基化剂将烷氧基化为烷氧基化醇的方法，其中使用包含金属离子的金属有机骨架材料和至少二齿配位结合的有机配体的催化剂。

公开(公告)号：US06455711B1

公开(公告)日：2002-09-24

申请号：US09486643

申请日：2000-02-29

Applicant: Karsten Eller ,  Michael Hesse ,  Rainer Becker ,  Arthur Höhn ,  Heinz Rütter

Inventor： Karsten Eller ,  Michael Hesse ,  Rainer Becker ,  Arthur Höhn ,  Heinz Rütter

IPC: C07D30702

CPC classification number: C08G65/2693 ,  B01J21/16 ,  C08G65/20 ,  C08G65/2657

Abstract: A process for preparing polytetrahydrofuran, polytetrahydrofuran copolymers or diesters or monoesters of these polymers comprises polymerizing tetrahydrofuran in the presence of at least one telogen and/or comonomer over a heterogeneous catalyst comprising hectorite.

Abstract translation: 制备聚四氢呋喃，聚四氢呋喃共聚物或这些聚合物的二酯或单酯的方法包括在包含锂蒙脱石的多相催化剂的存在下，在至少一种前体和/或共聚单体的存在下聚合四氢呋喃。

公开(公告)号：US6162928A

公开(公告)日：2000-12-19

申请号：US553254

申请日：2000-04-20

Applicant: Joachim Wulff-Doring ,  Joachim Simon ,  Michael Hesse ,  Peter Wahl

Inventor： Joachim Wulff-Doring ,  Joachim Simon ,  Michael Hesse ,  Peter Wahl

IPC: B01J23/44 ,  B01J23/63 ,  C07B61/00 ,  C07D207/32 ,  C07D207/323

CPC classification number: C07D207/323 ,  B01J23/44 ,  B01J23/63

Abstract: A process for preparing pyrroles of the formula I: ##STR1## where R.sub.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and are hydrogen atoms, alkyl groups having from 1 to 12 carbon atoms or cycloalkyl groups having from 3 to 12 carbon atoms, by dehydrogenation of pyrrolidines of the formula II: ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are as defined above, in the presence of a supported noble metal catalyst is described. In this process, the dehydrogenation is carried out at from 150 to 300.degree. C. and pressures of from 0.01 to 50 bar and the noble metal catalyst comprises from 30 to 100% by weight of:a) palladium on an oxide of a rare earth or an oxide of an element of the 4.sup.th group (transition group IV) of the Periodic Table, orb) a platinum/palladium mixture on aluminum oxide, an oxide of a rare earth or an oxide of an element of the 4.sup.th groupand from 0 to 70% by weight of alkali metal oxide or alkaline earth metal oxide.

Abstract translation: 制备式I的吡咯的方法：其中R 1，R 2，R 3和R 4相同或不同，为氢原子，具有1至12个碳原子的烷基或具有3至12个碳原子的环烷基，通过脱氢 描述了在负载的贵金属催化剂的存在下，式II的吡咯烷（其中R 1，R 2，R 3和R 4如上定义）。 在该方法中，脱氢在150-300℃，压力为0.01至50巴，贵金属催化剂包含30-100重量％的：a）在稀土氧化物上的钯 或元素周期表第4族元素（过渡组IV）的氧化物，或b）在氧化铝上的铂/钯混合物，稀土的氧化物或第4族元素的氧化物， 0〜70重量％的碱金属氧化物或碱土金属氧化物。

公开(公告)号：US6063939A

公开(公告)日：2000-05-16

申请号：US226144

申请日：1999-01-07

Applicant: Carsten Groning ,  Michael Hesse ,  Daniel Heineke ,  Heinz-Josef Kneuper ,  Gerhard Fritz

Inventor： Carsten Groning ,  Michael Hesse ,  Daniel Heineke ,  Heinz-Josef Kneuper ,  Gerhard Fritz

IPC: B01J23/89 ,  B01J27/045 ,  C07D309/18 ,  C07D507/02 ,  C07D309/00 ,  C07D319/12

CPC classification number: B01J27/045 ,  B01J23/8913 ,  C07D309/18

Abstract: Unsaturated cyclic ethers of the formula I ##STR1## whereZ is --(CHR.sup.4).sub.q -- or --(CHR.sup.4).sub.q --O--,q is 0, 1, 2 or 3 andR.sup.1,R.sup.2,R.sup.3,R.sup.4 are hydrogen or C.sub.1 -C.sub.4 -alkylare prepared by reacting diols of the formula II ##STR2## where Z, R.sup.1, R.sup.2 and R.sup.3 are as defined above, in the liquid phase at from 150 to 300.degree. C. in the presence of a cobalt-containing supported catalyst which has not been activated by reduction before use and comprises cobalt and a noble metal selected from the group consisting of platinum, palladium, rhodium, iridium, ruthenium, osmium, rhenium or a mixture thereof applied by sol impregnation on an inert support, wherein the supported catalyst is doped with sulfur. Sulfur-doped supported catalysts comprising cobalt and noble metals are also provided.

Abstract translation: Z为 - （CHR 4）q-或 - （CHR 4）q O - ，q为0,1,2或3且R 1，R 2，R 3，R 4为氢或C 1 -C 4烷基的式I的不饱和环醚为 通过使其中Z，R 1，R 2和R 3如上所定义的式II的二醇在150-300℃的液相中，在没有被还原活化的含钴担载催化剂存在下反应制备 并且包括钴和选自铂，钯，铑，铱，钌，锇，铼的贵金属或其通过溶胶浸渍施加到惰性载体上的混合物，其中负载型催化剂掺杂有硫。 还提供了包含钴和贵金属的硫掺杂负载型催化剂。

公开(公告)号：US5773648A

公开(公告)日：1998-06-30

申请号：US793987

申请日：1997-03-07

Applicant: Rainer Becker ,  Christoph Sigwart ,  Michael Hesse ,  Rolf Fischer ,  Karsten Eller ,  Gerd Heilen ,  Klaus-Dieter Plitzko

Inventor： Rainer Becker ,  Christoph Sigwart ,  Michael Hesse ,  Rolf Fischer ,  Karsten Eller ,  Gerd Heilen ,  Klaus-Dieter Plitzko

IPC: B01J23/24 ,  C08G65/10 ,  C08G65/20 ,  C08G65/26 ,  C08G65/28 ,  C07C67/24 ,  C07C43/18

CPC classification number: C08G65/266 ,  B01J23/24 ,  C08G65/20 ,  C08G65/2693

Abstract: A process for the preparation of polytetrahydrofuran or polytetrahydrofuran monoesters of C.sub.1 -C.sub.10 monocarboxylic acids by the polymerization of tetrahydrofuran over a heterogeneous catalyst in the presence of one of the telogens water, 1,4-butanediol or polytetrahydrofuran having a molecular weight of from 200 to 700 dalton or a C.sub.1 -C.sub.10 monocarboxylic acid or mixtures of these telogens, wherein a supported catalyst is used as catalyst, which contains a catalytically active amount of an oxygen-containing tungsten or molybdenum compound or mixtures of these compounds on an oxidic support material and which was calcined at temperatures ranging from 500.degree. to 1000.degree. C. following the application of the precursor compounds of said oxygen-containing molybdenum and/or tungsten compounds to the support material precursor.

Abstract translation: PCT No.PCT / EP95 / 03651 Sec。 371日期1997年3月10日 102（e）1997年3月10日PCT PCT 1995年9月21日PCT公布。 公开号WO96 / 09335 日期：1996年3月28日一种通过四氢呋喃在多相催化剂上的存在下，在一种具有分子量的四氢呋喃水，1,4-丁二醇或聚四氢呋喃的存在下，通过四氢呋喃的聚合制备C1-C10单羧酸的聚四氢呋喃或聚四氢呋喃单酯的方法 重量为200至700道尔顿或C1-C10单羧酸或其混合物，其中使用负载催化剂作为催化剂，其含有催化活性量的含氧钨或钼化合物或这些化合物的混合物在 氧化载体材料，并且在将所述含氧钼和/或钨化合物的前体化合物施加到载体材料前体之后，在500℃至1000℃的温度下煅烧。

公开(公告)号：US5663438A

公开(公告)日：1997-09-02

申请号：US516147

申请日：1995-08-17

Applicant: Ulrich Kohler ,  Frank-Friedrich Pape ,  Matthias Irgang ,  Joachim Wulff-Doring ,  Michael Hesse ,  Peter Polanek

Inventor： Ulrich Kohler ,  Frank-Friedrich Pape ,  Matthias Irgang ,  Joachim Wulff-Doring ,  Michael Hesse ,  Peter Polanek

IPC: B01J23/40 ,  B01J23/42 ,  B01J23/58 ,  B01J23/63 ,  C07B61/00 ,  C07C209/16 ,  C07C209/68 ,  C07C211/45

CPC classification number: C07C209/68 ,  C07C209/16

Abstract: A process for the preparation of a phenyl amine which may be substituted by alkyl or cycloalkyl in which the corresponding cyolohexylamine is reduced at temperatures of 150.degree. to 300.degree. C. and pressures of 0.01 to 50 bar in the presence of a heterogeneous dehydrogenation catalyst consisting essentially of palladium or a palladium/platinum mixture supported on carrier consisting of the oxides of rare earth metals and and metals of Group IVb of the Periodic Table of Elements, with the proviso that the palladium/platinum mixture may also be supported on an alumina carrier. The cyclohexylamine reactant can be advantageously prepared by reacting the corresponding phenol with ammonia and hydrogen at 100.degree. to 250.degree. C. in the presence of the same heterogeneous catalyst as a preliminary step to provide a two stage process using the same catalyst in both stages.

Abstract translation: 制备苯基胺的方法，其可以被烷基或环烷基取代，其中相应的环己胺在150-300℃的温度和0.01至50巴的压力下在存在非均相脱氢催化剂的条件下还原， 基本上由负载在由稀土金属的氧化物构成的载体上的钯或钯/铂混合物和元素周期表IVb族金属组成，条件是钯/铂混合物也可以负载在氧化铝载体上 。 环己胺反应物可以有利地通过在相同的非均相催化剂的存在下在100-250℃下使相应的苯酚与氨和氢反应来制备，以提供在两个阶段中使用相同催化剂的两阶段方法。

公开(公告)号：US5648545A

公开(公告)日：1997-07-15

申请号：US494955

申请日：1995-07-05

Applicant: Wolfgang Reif ,  Michael Hesse ,  Horst Zimmermann ,  Heinz Lingk

Inventor： Wolfgang Reif ,  Michael Hesse ,  Horst Zimmermann ,  Heinz Lingk

IPC: B01J23/72 ,  B01J23/76 ,  C07C209/48 ,  C07C209/60 ,  C07C211/09

CPC classification number: B01J23/72 ,  B01J23/76 ,  C07C209/48 ,  C07C209/60 ,  Y02P20/582

Abstract: Catalysts consisting of from 85 to 100 wt % of copper oxide and zirconium oxide and from 15 to 0 wt % of metal oxides of the subgroups Ib to VIIb and VIII of the Periodic Table and a process for the preparation of amines from nitriles and nitrogen compounds selected from the group comprising ammonia and primary and secondary amines, at temperatures of from 80.degree. to 250.degree. C. and pressures of from 1 to 400 bar using hydrogen in the presence of said catalysts.

Abstract translation: 由85至100重量％的氧化铜和氧化锆和15至0重量％的元素周期表Ib至VIIb和VIII族的金属氧化物组成的催化剂和由腈和氮化合物制备胺的方法 在包含氨和伯胺和仲胺的基团中，在所述催化剂存在下，使用氢气在80-250℃的温度和1-400巴的压力下进行。