公开(公告)号：US20160009638A1

公开(公告)日：2016-01-14

申请号：US14865948

申请日：2015-09-25

申请人： INVISTA NORTH AMERICA S.A R.L.

发明人： Sergio MASTROIANNI

IPC分类号： C07C253/10

CPC分类号： C07C253/10 ,  B01J31/122 ,  B01J31/146 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/2208 ,  B01J31/2409 ,  B01J2231/322 ,  B01J2523/305 ,  B01J2523/41 ,  B01J2523/42 ,  B01J2523/43 ,  B01J2531/847 ,  C07C255/04

摘要： Process for producing compounds comprising nitrile functionsThe present invention relates to a process for producing compounds comprising at least one nitrile function by hydrocyanation of a compound comprising at least one non-conjugated unsaturation.The invention proposes a process for producing compounds comprising at least one nitrile function by hydrocyanation of an organic compound comprising at least one non-conjugated unsaturation, comprising from 2 to 20 carbon atoms, by reaction with hydrogen cyanide in the presence of a catalytic system comprising a complex of nickel having the oxidation state of zero with at least one organophosphorus ligand chosen from the group comprising organophosphites, organophosphonites, organophosphinites and organosphosphines and a cocatalyst of the Lewis acid type.

摘要翻译： 用于生产包含腈功能的化合物的方法本发明涉及通过氢化氰化化合物制备包含至少一种腈官能团的化合物的方法，所述化合物包含至少一种非共轭不饱和键。 本发明提出了一种制备包含至少一个腈官能团的化合物的方法，所述化合物包括至少一种包含至少一个含有2-20个碳原子的非共轭不饱和键的有机化合物，所述有机化合物包括2-20个碳原子，在氰化氢的存在下， 具有氧化态为零的镍与至少一种选自有机亚磷酸酯，有机亚膦酸酯，有机亚磷酸酯和有机膦的有机磷配体的络合物和路易斯酸型助催化剂。

公开(公告)号：US20150298105A1

公开(公告)日：2015-10-22

申请号：US14440270

申请日：2014-07-15

申请人： LG CHEM, LTD.

发明人： Jun Seon CHOI ,  Ji Yeon KIM ,  Joo Young CHEON ,  Wang Rae JOE

IPC分类号： B01J27/195 ,  C07C45/52 ,  B01J37/04 ,  B01J27/188 ,  B01J37/08

CPC分类号： B01J27/195 ,  B01J27/053 ,  B01J27/055 ,  B01J27/188 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/08 ,  B01J37/20 ,  B01J37/28 ,  B01J2523/00 ,  C07C29/60 ,  C07C45/29 ,  C07C45/52 ,  C07C31/225 ,  C07C47/22 ,  B01J2523/17 ,  B01J2523/62 ,  B01J2523/69 ,  B01J2523/305 ,  B01J2523/51 ,  B01J2523/56 ,  B01J2523/3712

摘要： The present invention relates to a catalyst for glycerin dehydration, a preparation method thereof, and a preparation method of acrolein, and more particularly, to a catalyst for glycerin dehydration which minimizes by-product formation during glycerin dehydration to improve acrolein selectivity and maintains high catalytic activity during reaction.

摘要翻译： 本发明涉及一种用于甘油脱水的催化剂及其制备方法和丙烯醛的制备方法，更具体地说，涉及甘油脱水催化剂，其使甘油脱水期间的副产物形成最小化以改善丙烯醛选择性并保持高催化性 反应过程中的活性。

公开(公告)号：US20150259265A1

公开(公告)日：2015-09-17

申请号：US14210610

申请日：2014-03-14

申请人： CLARIANT CORPORATION

发明人： Vladimir FRIDMAN ,  Michael A. URBANCIC

IPC分类号： C07C5/333

CPC分类号： C07C5/3332 ,  B01J23/002 ,  B01J23/26 ,  B01J23/8892 ,  B01J23/92 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/04 ,  B01J37/18 ,  B01J38/12 ,  B01J2523/00 ,  C07C2521/04 ,  C07C2523/04 ,  C07C2523/26 ,  C07C2523/72 ,  C07C2523/86 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06 ,  C07C11/09 ,  B01J2523/17 ,  B01J2523/23 ,  B01J2523/31 ,  B01J2523/67 ,  B01J2523/72 ,  B01J2523/13 ,  B01J2523/25 ,  B01J2523/305

摘要： The disclosure provides an improved endothermic hydrocarbon conversion process that comprises reacting a hydrocarbon with a multi-component catalyst bed, and regenerating the catalyst bed with air, where the air used in regeneration step and hydrocarbon are at low air to hydrocarbon ratios and optionally at near-atmospheric pressures.

摘要翻译： 本公开提供了一种改进的吸热烃转化方法，其包括使烃与多组分催化剂床反应，并且用空气再生催化剂床，其中在再生步骤中使用的空气和烃处于低的空气与烃比，并且任选地在近 大气压力。

公开(公告)号：US09024070B2

公开(公告)日：2015-05-05

申请号：US13980641

申请日：2012-01-30

申请人： Tatsuyuki Kumano ,  Yukiya Ibi ,  Kuniaki Arasuna ,  Shinichi Nagao

发明人： Tatsuyuki Kumano ,  Yukiya Ibi ,  Kuniaki Arasuna ,  Shinichi Nagao

IPC分类号： C07C211/00 ,  C07C209/48 ,  B01J23/22 ,  B01J23/26 ,  B01J37/00 ,  B01J23/00 ,  B01J23/75 ,  B01J23/755

CPC分类号： C07C209/48 ,  B01J23/002 ,  B01J23/22 ,  B01J23/26 ,  B01J23/75 ,  B01J23/755 ,  B01J37/0045 ,  B01J2523/00 ,  C07C211/27 ,  B01J2523/12 ,  B01J2523/13 ,  B01J2523/305 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/67 ,  B01J2523/68

摘要： Provided is a method for stably and economically producing xylylenediamine with a high yield and long catalyst service life by hydrogenating dicyanobenzene that is obtained by ammoxidating xylene. By bringing an aqueous basic solution into contact with a dicyanobenzene-absorbed liquid, which is obtained by bringing an ammoxidation reaction gas into contact with an organic solvent, under specified temperature conditions, and subjecting a base and a carboxylic acid in the dicyanobenzene-absorbed liquid to a neutralization reaction so as to form an aqueous phase that contains a water-soluble salt, and then subjecting an organic phase and the aqueous phase to liquid-liquid separation so as to remove the aqueous phase, it is possible to remove the carboxylic acid contained in the dicyanobenzene-absorbed liquid with high selectivity while inhibiting loss of the dicyanobenzene. By subjecting the raw material dicyanobenzene, which is obtained by separating low boiling point compounds from the post liquid-liquid separation organic phase by distillation under reduced pressure, to hydrogenation, xylylenediamine is produced with a high yield and the service life of the hydrogenation catalyst is extended.

摘要翻译： 本发明提供一种通过氢化二甲苯得到的二氰基苯来稳定和经济地制备苯二甲胺的方法，其产率高，催化剂使用寿命长。 通过使碱性水溶液与规定的温度条件下使氨氧化反应气体与有机溶剂接触而获得的二氰基苯吸收液接触，并将二羧酸吸收液中的碱和羧酸 进行中和反应，形成含有水溶性盐的水相，然后使有机相和水相进行液 - 液分离以除去水相，可以除去羧酸 包含在二氰基苯吸收液体中，同时抑制二氰基苯的损失。 通过将来自后液 - 液分离有机相的低沸点化合物通过减压蒸馏分离得到的原料二氰基苯进行氢化，以高产率生产苯二甲胺，氢化催化剂的使用寿命为 延长

公开(公告)号：US20150073192A1

公开(公告)日：2015-03-12

申请号：US14517524

申请日：2014-10-17

申请人： Siluria Technologies, Inc.

发明人： Joel M. Cizeron ,  Erik C. Scher ,  Fabio R. Zurcher ,  Wayne P. Schammel ,  Greg Nyce ,  Anja Rumplecker ,  Jarod McCormick ,  Marian Alcid ,  Joel Gamoras ,  Daniel Rosenberg ,  Erik-Jan Ras

IPC分类号： C07C2/84

CPC分类号： C07C2/84 ,  B01J19/0046 ,  B01J21/066 ,  B01J21/08 ,  B01J23/002 ,  B01J23/10 ,  B01J23/34 ,  B01J23/54 ,  B01J23/63 ,  B01J23/76 ,  B01J23/83 ,  B01J23/8892 ,  B01J27/16 ,  B01J35/0006 ,  B01J37/031 ,  B01J37/035 ,  B01J2219/00527 ,  B01J2219/00536 ,  B01J2219/00702 ,  B01J2219/00747 ,  B01J2523/00 ,  C07C2521/10 ,  C07C2521/14 ,  C07C2523/10 ,  C07C2523/18 ,  C07C2523/34 ,  C07C2529/072 ,  C07C2529/076 ,  C07C2529/89 ,  Y02P20/52 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/3725 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/23 ,  B01J2523/11 ,  B01J2523/22 ,  B01J2523/305 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/12 ,  B01J2523/69 ,  C07C11/04

摘要： Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.

摘要翻译： 提供了包含各种掺杂剂的金属氧化物催化剂。 催化剂可用作各种催化反应中的异质催化剂，例如甲烷与C 2烃如乙烷和乙烯的氧化偶联。 还公开了相关的使用和制造方法。

公开(公告)号：US20140275679A1

公开(公告)日：2014-09-18

申请号：US14289995

申请日：2014-05-29

申请人： John A. Sofranko

发明人： John A. Sofranko

IPC分类号： C07C2/84 ,  B01J19/08

CPC分类号： C25B5/00 ,  B01D71/024 ,  B01J8/02 ,  B01J19/087 ,  B01J19/2475 ,  B01J23/002 ,  B01J23/34 ,  B01J35/002 ,  B01J35/0033 ,  B01J37/04 ,  B01J37/08 ,  B01J2219/0803 ,  B01J2523/00 ,  C07C2/84 ,  C10G2/34 ,  C10G50/00 ,  C25B3/02 ,  H01M8/1004 ,  B01J2523/11 ,  B01J2523/22 ,  B01J2523/305 ,  B01J2523/72

摘要： A reactor and process capable of concurrently producing electric power and selectively oxidizing gaseous components in a feed stream, such as hydrocarbons to unsaturated products, which are useful intermediates in the production of liquid fuels. The reactor includes an oxidation membrane, a reduction membrane, an electron barrier, and a conductor. The oxidation membrane and reduction membrane include an MIEC oxide. The electron barrier, located between the oxidation membrane and the reduction membrane, is configured to allow transmission of oxygen anions from the reduction membrane to the oxidation membrane and resist transmission of electrons from the oxidation membrane to the reduction membrane. The conductor conducts electrons from the oxidation membrane to the reduction membrane.

摘要翻译： 能够同时生产电力并选择性地将进料流中的气体组分（例如烃）转化成不饱和产物的反应器和方法，这些是生产液体燃料的有用中间体。 反应器包括氧化膜，还原膜，电子势垒和导体。 氧化膜和还原膜包括MIEC氧化物。 位于氧化膜和还原膜之间的电子势垒被配置为允许氧阴离子从还原膜传递到氧化膜并阻止电子从氧化膜传递到还原膜。 导体将电子从氧化膜传导到还原膜。

公开(公告)号：US20130296609A1

公开(公告)日：2013-11-07

申请号：US13980641

申请日：2012-01-30

申请人： Tatsuyuki Kumano ,  Yukiya Ibi ,  Kuniaki Arasuna ,  Shinichi Nagao

发明人： Tatsuyuki Kumano ,  Yukiya Ibi ,  Kuniaki Arasuna ,  Shinichi Nagao

IPC分类号： C07C209/48

CPC分类号： C07C209/48 ,  B01J23/002 ,  B01J23/22 ,  B01J23/26 ,  B01J23/75 ,  B01J23/755 ,  B01J37/0045 ,  B01J2523/00 ,  C07C211/27 ,  B01J2523/12 ,  B01J2523/13 ,  B01J2523/305 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/67 ,  B01J2523/68

摘要： Provided is a method for stably and economically producing xylylenediamine with a high yield and long catalyst service life by hydrogenating dicyanobenzene that is obtained by ammoxidating xylene. By bringing an aqueous basic solution into contact with a dicyanobenzene-absorbed liquid, which is obtained by bringing an ammoxidation reaction gas into contact with an organic solvent, under specified temperature conditions, and subjecting a base and a carboxylic acid in the dicyanobenzene-absorbed liquid to a neutralization reaction so as to form an aqueous phase that contains a water-soluble salt, and then subjecting an organic phase and the aqueous phase to liquid-liquid separation so as to remove the aqueous phase, it is possible to remove the carboxylic acid contained in the dicyanobenzene-absorbed liquid with high selectivity while inhibiting loss of the dicyanobenzene. By subjecting the raw material dicyanobenzene, which is obtained by separating low boiling point compounds from the post liquid-liquid separation organic phase by distillation under reduced pressure, to hydrogenation, xylylenediamine is produced with a high yield and the service life of the hydrogenation catalyst is extended.

摘要翻译： 本发明提供一种通过氢化二甲苯得到的二氰基苯来稳定和经济地制备苯二甲胺的方法，其产率高，催化剂使用寿命长。 通过使碱性水溶液与规定的温度条件下使氨氧化反应气体与有机溶剂接触而获得的二氰基苯吸收液接触，并将二羧酸吸收液中的碱和羧酸 进行中和反应，形成含有水溶性盐的水相，然后使有机相和水相进行液 - 液分离以除去水相，可以除去羧酸 包含在二氰基苯吸收液体中，同时抑制二氰基苯的损失。 通过将来自后液 - 液分离有机相的低沸点化合物通过减压蒸馏分离得到的原料二氰基苯进行氢化，以高产率生产苯二甲胺，氢化催化剂的使用寿命为 延长

公开(公告)号：US20130023709A1

公开(公告)日：2013-01-24

申请号：US13479767

申请日：2012-05-24

申请人： Joel M. Cizeron ,  Erik Scher ,  Fabio R. Zurcher ,  Wayne P. Schammel ,  Greg Nyce ,  Anja Rumplecker ,  Jarod McCormick ,  Marian Alcid ,  Joel Gamoras ,  Daniel Rosenberg ,  Erik-Jan Ras

发明人： Joel M. Cizeron ,  Erik Scher ,  Fabio R. Zurcher ,  Wayne P. Schammel ,  Greg Nyce ,  Anja Rumplecker ,  Jarod McCormick ,  Marian Alcid ,  Joel Gamoras ,  Daniel Rosenberg ,  Erik-Jan Ras

IPC分类号： B01J23/10 ,  C01F17/00 ,  C07C2/76 ,  C01G45/02 ,  B01J27/18 ,  B01J27/224 ,  C01B35/10 ,  B01J23/12

CPC分类号： C07C2/84 ,  B01J19/0046 ,  B01J21/066 ,  B01J21/08 ,  B01J23/002 ,  B01J23/10 ,  B01J23/34 ,  B01J23/54 ,  B01J23/63 ,  B01J23/76 ,  B01J23/83 ,  B01J23/8892 ,  B01J27/16 ,  B01J35/0006 ,  B01J37/031 ,  B01J37/035 ,  B01J2219/00527 ,  B01J2219/00536 ,  B01J2219/00702 ,  B01J2219/00747 ,  B01J2523/00 ,  C07C2521/10 ,  C07C2521/14 ,  C07C2523/10 ,  C07C2523/18 ,  C07C2523/34 ,  C07C2529/072 ,  C07C2529/076 ,  C07C2529/89 ,  Y02P20/52 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/3725 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/23 ,  B01J2523/11 ,  B01J2523/22 ,  B01J2523/305 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/12 ,  B01J2523/69 ,  C07C11/04

摘要： Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.

公开(公告)号：US20120196744A1

公开(公告)日：2012-08-02

申请号：US13500760

申请日：2010-09-10

申请人： Kenichi Miyaki ,  Motoo Yanagita ,  Hirokazu Watanabe ,  Takashi Karasuda

发明人： Kenichi Miyaki ,  Motoo Yanagita ,  Hirokazu Watanabe ,  Takashi Karasuda

IPC分类号： B01J23/843

CPC分类号： B01J35/023 ,  B01J21/08 ,  B01J23/002 ,  B01J23/8435 ,  B01J23/888 ,  B01J23/8885 ,  B01J27/0576 ,  B01J37/0045 ,  B01J37/03 ,  B01J2523/00 ,  B01J2523/17 ,  B01J2523/27 ,  B01J2523/305 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/64 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/13 ,  B01J2523/22 ,  B01J2523/55 ,  B01J2523/845 ,  B01J2523/48 ,  B01J2523/67 ,  B01J2523/72

摘要： A process for producing a composite oxide catalyst which includes a step of preparing an aqueous slurry containing at least iron and antimony and composed of a liquid phase and a solid phase, a step of drying the aqueous slurry to obtain a dried material, and a step of calcining the obtained dried material, wherein of the precipitated particles having a particle size of not less than 1 μm but less than 150 μm contained within the aqueous slurry, the proportion of precipitated particles having a particle size of not less than 1 μm but less than 10 μm is within a range from 40 to 90% by volume, and the proportion of precipitated particles having a particle size of not less than 10 μm but less than 150 μm is within a range from 10 to 60% by volume.

摘要翻译： 一种复合氧化物催化剂的制造方法，其特征在于，包括至少含有铁和锑，由液相和固相组成的含水浆料的步骤，干燥所述含水浆料以获得干燥材料的工序， 煅烧所获得的干燥材料，其中，所述含水浆料中含有粒径为1μm以上且小于150μm的析出粒子，粒径为1μm以上的析出粒子的比例为1μm以下 10μm以上的范围为40〜90体积％，粒径10μm以上且小于150μm的析出粒子的比例在10〜60体积％的范围内。

公开(公告)号：US20110143931A1

公开(公告)日：2011-06-16

申请号：US12949532

申请日：2010-11-18

申请人： Wugeng Liang ,  Scott A. Stevenson ,  Angie McGuffey

发明人： Wugeng Liang ,  Scott A. Stevenson ,  Angie McGuffey

IPC分类号： B01J37/03 ,  B01J27/199 ,  B01J37/04 ,  B01J37/08

CPC分类号： B01J27/188 ,  B01J23/002 ,  B01J27/1853 ,  B01J27/199 ,  B01J2523/00 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/305 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/54 ,  B01J2523/55 ,  B01J2523/68

摘要： Methods for preparing catalystis for exidation of unsaturated and/or saturated aldehydes to unsaturated acids is disclosed where the catalyst includes at least molybenum (Mo), phosphorus (P), vanadium (V), bismuth (Bi), where the bismuth component was dissolved in an organic acid solution prior to adding the bismuth containing solution to a solution of the other components.

摘要翻译： 公开了用于将不饱和和/或饱和醛向不饱和酸进行催化的催化剂的方法，其中催化剂至少包含钼（Mo），磷（P），钒（V），铋（Bi），其中铋成分溶解 在将含铋溶液加入到其它组分的溶液之前的有机酸溶液中。