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公开(公告)号:US20230150823A1
公开(公告)日:2023-05-18
申请号:US17300820
申请日:2021-11-16
IPC分类号: C01B32/40 , B01J21/00 , B01J21/04 , B01J21/10 , B01J37/08 , B01J37/02 , B01J35/10 , B01J23/78 , B01J23/755
CPC分类号: C01B32/40 , B01J21/005 , B01J21/04 , B01J21/10 , B01J37/082 , B01J37/0207 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J37/0225 , B01J23/78 , B01J23/755 , C01B2203/0283 , C01B2203/061 , C01B2203/062 , C25B1/04
摘要: The present invention is generally directed to the production of low-carbon syngas from captured CO2 and renewable H2. The H2 is generated from water using an electrolyzer powered by renewable electricity, or from any other method of low-carbon H2 production. The improved catalysts use low-cost metals, they can be produced economically in commercial quantities, and they are chemically and physically stable up to 2,100° F. CO2 conversion is between 80% and 100% with CO selectivity of greater than 99%. The catalysts don't sinter or form coke when converting H2:CO2 mixtures to syngas in the operating ranges of 1,300-1,800° F., pressures of 75-450 psi, and space velocities of 2,000-100,000 hr−1. The catalysts are stable, exhibiting between 0 and 1% CO2 conversion decline per 1,000 hrs. The syngas can be used for the synthesis of low-carbon fuels and chemicals, or for the production of purified H2. The H2 can be used at the production site for the synthesis of low-carbon chemical products or compressed for transportation use.
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公开(公告)号:US08921256B2
公开(公告)日:2014-12-30
申请号:US13479767
申请日:2012-05-24
申请人: Joel M. Cizeron , Erik Scher , Fabio R. Zurcher , Wayne P. Schammel , Greg Nyce , Anja Rumplecker , Jarod McCormick , Marian Alcid , Joel Gamoras , Daniel Rosenberg , Erik-Jan Ras
发明人: Joel M. Cizeron , Erik Scher , Fabio R. Zurcher , Wayne P. Schammel , Greg Nyce , Anja Rumplecker , Jarod McCormick , Marian Alcid , Joel Gamoras , Daniel Rosenberg , Erik-Jan Ras
IPC分类号: B01J23/00 , B01J23/10 , B01J23/34 , B01J23/54 , B01J23/76 , C07C2/84 , B01J37/03 , B01J23/889 , B01J23/63 , B01J23/83 , B01J19/00
CPC分类号: C07C2/84 , B01J19/0046 , B01J21/066 , B01J21/08 , B01J23/002 , B01J23/10 , B01J23/34 , B01J23/54 , B01J23/63 , B01J23/76 , B01J23/83 , B01J23/8892 , B01J27/16 , B01J35/0006 , B01J37/031 , B01J37/035 , B01J2219/00527 , B01J2219/00536 , B01J2219/00702 , B01J2219/00747 , B01J2523/00 , C07C2521/10 , C07C2521/14 , C07C2523/10 , C07C2523/18 , C07C2523/34 , C07C2529/072 , C07C2529/076 , C07C2529/89 , Y02P20/52 , B01J2523/24 , B01J2523/3706 , B01J2523/3725 , B01J2523/3712 , B01J2523/54 , B01J2523/23 , B01J2523/11 , B01J2523/22 , B01J2523/305 , B01J2523/72 , B01J2523/845 , B01J2523/12 , B01J2523/69 , C07C11/04
摘要: Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.
摘要翻译: 提供了包含各种掺杂剂的金属氧化物催化剂。 催化剂可用作各种催化反应中的异质催化剂,例如甲烷与C 2烃如乙烷和乙烯的氧化偶联。 还公开了相关的使用和制造方法。
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公开(公告)号:US20130023709A1
公开(公告)日:2013-01-24
申请号:US13479767
申请日:2012-05-24
申请人: Joel M. Cizeron , Erik Scher , Fabio R. Zurcher , Wayne P. Schammel , Greg Nyce , Anja Rumplecker , Jarod McCormick , Marian Alcid , Joel Gamoras , Daniel Rosenberg , Erik-Jan Ras
发明人: Joel M. Cizeron , Erik Scher , Fabio R. Zurcher , Wayne P. Schammel , Greg Nyce , Anja Rumplecker , Jarod McCormick , Marian Alcid , Joel Gamoras , Daniel Rosenberg , Erik-Jan Ras
IPC分类号: B01J23/10 , C01F17/00 , C07C2/76 , C01G45/02 , B01J27/18 , B01J27/224 , C01B35/10 , B01J23/12
CPC分类号: C07C2/84 , B01J19/0046 , B01J21/066 , B01J21/08 , B01J23/002 , B01J23/10 , B01J23/34 , B01J23/54 , B01J23/63 , B01J23/76 , B01J23/83 , B01J23/8892 , B01J27/16 , B01J35/0006 , B01J37/031 , B01J37/035 , B01J2219/00527 , B01J2219/00536 , B01J2219/00702 , B01J2219/00747 , B01J2523/00 , C07C2521/10 , C07C2521/14 , C07C2523/10 , C07C2523/18 , C07C2523/34 , C07C2529/072 , C07C2529/076 , C07C2529/89 , Y02P20/52 , B01J2523/24 , B01J2523/3706 , B01J2523/3725 , B01J2523/3712 , B01J2523/54 , B01J2523/23 , B01J2523/11 , B01J2523/22 , B01J2523/305 , B01J2523/72 , B01J2523/845 , B01J2523/12 , B01J2523/69 , C07C11/04
摘要: Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.
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