Abstract:
A method for removing tar from a gas by contacting a first gas containing tar with a second gas containing oxygen for time period sufficient to effect oxidation of at least a portion of the tar in the first gas, thus producing an oxidized product gas that contains less tar than the first gas.
Abstract:
A method and assembly for producing substantially tar free product gas from gasification of carbonaceous material. The assembly preferably includes a first stage gasifier to produce char-ash and tar laden product gas and a second stage gasifier which has a char-ash heating zone, at least one cyclone, and at least one standpipe for the purpose of allowing selective delivery of char-ash to the char-ash heating zone. A char-ash heating zone that utilizes oxidation of char-ash is preferred and this results in the heat required to convert tar, additional yield of product gas, and an oxidized, activated carbon surface to facilitate tar conversion in the riser, thereby reducing the temperature required to achieve the desired tar conversion. Alternatively, external heat is supplied to the heating zone.
Abstract:
A process of gasification and the production of synthesis gas. A process of biomass gasification and the reduction or elimination of tars from the hydrocarbon-rich product gas derived from biomass gasification. Systems and methods for the reduction of tar from a synthesis gas derived from biomass gasification are provided.
Abstract:
This invention provides a process for making ammonia from biomass. The biomass may be first reacted with oxygen and steam to generate a biosyngas comprising hydrogen (H2) and carbon monoxide (CO) as the active components. The gasification step may be regulated to reduce the amount of methane in the biosyngas that may leave the gasifier.
Abstract:
A gasification furnace for gasifying a biomass resource in a manner producing a low quantity of tar. The gasification furnace (10) is provided with a punching plate (11) partitioning the furnace interior into upper and lower spaces; a biomass resource supply port (10a) for supplying the biomass resource over the punching plate (11); a first oxidizer supply port (10c) and a second oxidizer supply port (10d) for supplying an oxidizer into the furnace; a first oxidizer supply path supplying the oxidizer from the first oxidizer supply port (10c) from above towards below the punching plate (11); a second oxidizer supply path distributing and supplying to a plurality of locations within a predetermined area in the vicinity of the punching plate (11) from the second oxidizer supply port (10d); and a dry distillation gas output (10b) for discharging dry distillation gas generated by the pyrolysis and partial oxidation of the biomass resource on the punching plate (11) to the outside.
Abstract:
Systems and methods for processing a methane rich producer gas are provided in which the producer gas is preferably produced via steam-hydrogasification. The product stream from the steam-hydrogasification is then subjected to autothermal reforming, steam is removed after the reforming step via condensation, and sulfur impurities are subsequently eliminated. In most preferred aspects, the process pressure is substantially maintained throughout all steps, typically in a range of 150 psi to 500 psi.
Abstract:
In a circulating fluidized-bed gasification system, an ammonia-off gas 30 from an ammonia remover 25 is fed to a catalytic denitrator 15 with a flow rate regulated such that a molar ratio of the ammonia in the ammonia off-gas 30 from the ammonia recover 25 to nitrogen oxides in an exhaust gas 6 from a combustion furnace 1 is kept within a setting range, and a reminder of the ammonia off-gas 30 is fed to the combustion furnace 1.
Abstract:
A process and apparatus are provided for gasification of a carbonaceous material. The process produces a raw syngas that can be further processed in a tar destruction zone to provide a hot syngas. The process includes contacting said carbonaceous material with molecular oxygen-containing gas in a gasification zone to gasify a portion of said carbonaceous material and to produce a first gaseous product. A remaining portion of the carbonaceous material is contacted with molecular oxygen-containing gas in a burn-up zone to gasify additional portion of the carbonaceous material and to produce a second gaseous product and a solid ash. The first gaseous product and said second gaseous product are combined to produce a raw syngas that includes carbon monoxide (CO), carbon dioxide (CO2) and tar. The raw syngas is contacted with molecular oxygen containing gas in a tar destruction zone to produce said hot syngas.
Abstract:
A process for producing synthesis gas from biomass in which biomass is contacted with oxygen and steam, wherein the oxygen is present in an amount effective to oxidize the biomass partially and to heat the biomass to a temperature of at least 500° C. and no greater than 750° C. At least a portion of the partially oxidized biomass then is treated with oxygen and steam to heat the biomass to a temperature of at least 800° C., thereby producing a synthesis gas, which then is recovered.
Abstract:
Reforming of a gasification gas is performed by supplying both a tar-containing gasification gas and oxygen to a reforming furnace and burning a part of the gasification gas to heat an inside of the reforming furnace to a target reforming temperature required for reforming. Oxygen 9 and a first stage gasification gas 3a are supplied to a reforming furnace at an end of the furnace in amounts so as to attain the target reforming temperature required for reforming by combustion of the gasification gas with the oxygen to form a heating zone A in the reforming furnace 1. The remaining gasification gas is supplied as second stage gasification gas 3b to a vicinity downstream of the heating zone A in the reforming furnace 1 to form a reforming zone B.