Abstract:
A method for converting carbonaceous raw materials and in particular biomass into hydrogen, includes the steps of: gasification of the carbon-containing raw materials in a gasifier, wherein heated water vapour is introduced into the gasifier and used for gasification; and cleaning of the hydrogen-containing synthesis gas produced in the gasification, wherein the gasification is an allothermal gasification and the heated water vapour is used both as gasification agent and as heat carrier for the gasification, wherein energy not used for H2 production is at least partially reused for the production and/or superheating of water vapour.
Abstract:
The invention pertains to a system for extracting hydrogen from an organic feedstock, comprising:
a thermolyzer supplied with the organic feedstock and adapted to heat it up the feedstock to a temperature of at least 800° C. while conveying it inside a gasification chamber by an auger and to collect a thermogas, a duct line to convey the thermogas to a high temperature reformer exposing it to a temperature comprised between 1200° C. and 1,400° C. and releasing a high temperature reformed gas, a duct line conveying the high temperature reformed gas to a heat chamber of the thermolyzer, the heat chamber comprising a chamber outlet to release the reformed gas after circulation in the heat chamber, a duct line conveying the reformed gas from the chamber outlet to an installation adapted to separate hydrogen from the reformed gas, and a hydrogen storage for the hydrogen produced by the installation.
Abstract:
A syngas cooler is configured to cool a syngas. The syngas cooler includes a superheater heat exchanger, which further includes a first header configured to receive saturated steam, a second header configured to discharge superheated steam, and a first group of tubes directly coupled to and vertically extending between the first and second headers. Each tube of the first group of tubes includes an outer surface that interfaces with the syngas and a respective length between the first and second headers, and each tube of the first group of tubes does not contact another tube along the respective length to enable a flow of the syngas around each tube's outer surface along its respective length and between each tube.
Abstract:
A solids circulation system receives a gas stream containing char or other reacting solids from a first reactor. The solids circulation system includes a cyclone configured to receive the gas stream from the first reactor, a dipleg from the cyclone to a second reactor, and a riser from the second reactor which merges with the gas stream received by the cyclone. The second reactor has a dense fluid bed and converts the received materials to gaseous products. A conveying fluid transports a portion of the bed media from the second reactor through the riser to mix with the gas stream prior to cyclone entry. The bed media helps manipulate the solids that is received by the cyclone to facilitate flow of solids down the dipleg into the second reactor. The second reactor provides additional residence time, mixing and gas-solid contact for efficient conversion of char or reacting solids.
Abstract:
A solids circulation system receives a gas stream containing char or other reacting solids from a first reactor. The solids circulation system includes a cyclone configured to receive the gas stream from the first reactor, a dipleg from the cyclone to a second reactor, and a riser from the second reactor which merges with the gas stream received by the cyclone. The second reactor has a dense fluid bed and converts the received materials to gaseous products. A conveying fluid transports a portion of the bed media from the second reactor through the riser to mix with the gas stream prior to cyclone entry. The bed media helps manipulate the solids that is received by the cyclone to facilitate flow of solids down the dipleg into the second reactor. The second reactor provides additional residence time, mixing and gas-solid contact for efficient conversion of char or reacting solids.
Abstract:
A method for producing energy including: producing fuel gases from biomass raw material in a main receptacle unit (8), feeding produced fuel gas to a consumer unit (2,3), transferring energy from the consumer unit to at least one energy user (7). The method includes recovering heat and producing pressurized superheated steam, intermittently loading biomass raw material into at least one vessel (8′), being included in the main receptacle unit (8), pressurizing the loaded at least one vessel (8′) with pressurized superheated steam, passing pressurized superheated steam through the loaded and pressurized at least one vessel (8′), thereby contacting and heat treating said biomass raw material with the pressurized superheated steam for the production of said fuel gases, supplying produced fuel gases together with still superheated steam to the consumer unit (2,3). The invention also concerns a plant.
Abstract:
A gasification system includes a countercurrent type heat exchanger that includes a low-temperature side flow channel through which a gasification feedstock flows, and a high-temperature side flow channel to which treated water in a supercritical state is introduced. The treated water raises a temperature of the gasification feedstock by exchanging heat with the gasification feedstock. The system further includes a reactor that gasifies the gasification feedstock, whose temperature has been raised by the countercurrent type heat exchanger, by heating and pressurizing the gasification feedstock to be in a supercritical state. The reactor discharges the gasification feedstock as treated water in the supercritical state. The system further includes a treated water flow channel that introduces, to the countercurrent type heat exchanger, the treated water that has been discharged from the reactor, and a feedstock introduction port that introduces the feedstock to the low-temperature side flow channel.
Abstract:
A method and apparatus for cooling hot gas streams in the temperature range 800° C. to 1600° C. using multi-stage circulating fluid bed (CFB) coolers is disclosed. The invention relates to cooling the hot syngas from coal gasifiers in which the hot syngas entrains substances that foul, erode and corrode heat transfer surfaces upon contact in conventional coolers. The hot syngas is cooled by extracting and indirectly transferring heat to heat transfer surfaces with circulating inert solid particles in CFB syngas coolers. The CFB syngas coolers are staged to facilitate generation of steam at multiple conditions and hot boiler feed water that are necessary for power generation in an IGCC process. The multi-stage syngas cooler can include internally circulating fluid bed coolers, externally circulating fluid bed coolers and hybrid coolers that incorporate features of both internally and externally circulating fluid bed coolers.
Abstract:
A method for gasifying biomass. The method includes: a) grinding the biomass, feeding the biomass into a gasifier while spraying superheated water vapor into the gasifier, controlling the gasifier at an operating temperature of 1200-1600° C., contacting the biomass with the superheated water vapor, desiccating, separating volatile matters, pyrolyzing, and gasifying the biomass to produce crude synthetic gas and ash; b) transporting the crude synthetic gas into a spray tower, quenching the crude synthetic gas by spraying water to cool down the crude synthetic gas to a temperature of 650-800° C., condensing a slag and a tar from the crude synthetic gas, dissolving and removing alkali metal oxides and part of acid gas to obtain primary synthetic gas; and c) cooling, dust removing, deacidifying, and desiccating the primary synthetic gas to transform the primary synthetic gas into clean synthetic gas.
Abstract:
This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in 1150° C. to 1500° C. range as well as in excess of 1500° C. In a preferred embodiment, such coals are dealt with a two stage gasification process—a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.