公开(公告)号：US10525432B2

公开(公告)日：2020-01-07

申请号：US15547662

申请日：2016-02-01

申请人： CONSIGLIO NAZIONALE DELLE RICERCHE

发明人： Anna Luisa Costa ,  Magda Blosi

IPC分类号： B01J13/00 ,  A61K9/06 ,  A61K47/38 ,  A61K33/24 ,  A61K33/28 ,  A61K33/34 ,  A61K33/38 ,  C09D7/40 ,  B01J23/50 ,  B01J23/52 ,  B01J23/72 ,  B01J31/06 ,  B01J35/00 ,  B01J37/03 ,  B01J37/04 ,  C09D5/14

摘要： There is described a versatile and environment-friendly one-pot process for the preparation of nanoparticles of noble metals in hydrogel, obtainable at room temperature using quaternized hydroxyethylcellulose.

公开(公告)号：US20200001274A1

公开(公告)日：2020-01-02

申请号：US16457665

申请日：2019-06-28

申请人： Simon G. Podkolzin ,  Tao Chen ,  Yiteng Zheng ,  Muye Yang ,  Sunitha Rao Tadepalli ,  Geatesh Karunakaran Tampy ,  John P. Cherkauskas, JR.

发明人： Simon G. Podkolzin ,  Tao Chen ,  Yiteng Zheng ,  Muye Yang ,  Sunitha Rao Tadepalli ,  Geatesh Karunakaran Tampy ,  John P. Cherkauskas, JR.

IPC分类号： B01J23/44 ,  B01J35/00 ,  B01J37/02 ,  B01J21/18 ,  B01J23/50 ,  B01J23/58 ,  C07C5/10

摘要： Provided is a process for preparing partially or fully hydrogenated hydrocarbons through hydrogenation of aromatic hydrocarbons in the presence of a hydrogenation catalyst. The hydrogenation catalyst comprises palladium deposited on carbon with optional acid wash and calcination treatments and with optional additions of silver and/or alkali metals.

公开(公告)号：US20190176130A1

公开(公告)日：2019-06-13

申请号：US15839987

申请日：2017-12-13

申请人： Scientific Design Company, Inc.

发明人： Evgeny BELETSKIY

IPC分类号： B01J23/50 ,  B01J37/02 ,  C07D301/02

摘要： A silver impregnation solution containing: (i) silver ions, (ii) a polar organic additive containing two to four carbon atoms and two to four functional groups selected from hydroxy, carboxylic acid, and amine groups, provided that a carboxylic acid group can only be present along with a hydroxy or amine group, and provided that an amine group can only be present along with a hydroxy or carboxylic acid group; and (iii) water; wherein components (i) and (ii) are water soluble and dissolved in the impregnation solution. Also described herein is a method for producing a catalyst effective in the oxidative conversion of ethylene to ethylene oxide, the method comprising subjecting a refractory carrier impregnated with the above-described silver impregnation solution to a calcination process. Also described herein is a method for converting ethylene to ethylene oxide by use of the foregoing silver catalyst, as produced by the above-described silver impregnation solution.

公开(公告)号：US20190126261A1

公开(公告)日：2019-05-02

申请号：US15976925

申请日：2018-05-11

申请人： Saint-Gobain Ceramics & Plastics, Inc.

发明人： Michael A. Richard ,  John David Covey

IPC分类号： B01J35/04 ,  B01J35/00 ,  C07D301/08 ,  B01J37/02 ,  B01J23/68 ,  B01J35/10 ,  C07C213/04 ,  B01J23/50 ,  C07C29/10 ,  C07C41/03 ,  C07D301/04

摘要： A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.

公开(公告)号：US20190118167A1

公开(公告)日：2019-04-25

申请号：US16176786

申请日：2018-10-31

申请人： Manuel A.W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

发明人： Manuel A.W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

IPC分类号： B01J27/055 ,  B01J23/58 ,  C07C209/60 ,  B01J37/02 ,  B01J35/02 ,  B01J23/68 ,  C07D301/10 ,  B01J23/50 ,  B01J21/04 ,  B01J37/16

摘要： A supported silver catalyst and use thereof in a process for producing an alkylene oxide, such as ethylene oxide, by the direct oxidation of an alkylene with oxygen or an oxygen-containing gas, wherein the catalyst provides improved stability and improved resilience to reactor upsets and timely recovery to substantially pre-upset levels of catalyst activity and/or efficiency. In some embodiments, the catalyst also exhibits improved activity. A catalyst capable of producing ethylene oxide at a selectivity of at least 87 percent while achieving a work rate of at least 184 kg/h/m3 at a temperature of no greater than 235° C. when operated in a process where the inlet feed to a reactor containing the catalyst comprises ethylene, oxygen, and carbon dioxide, wherein the concentration of carbon dioxide in the inlet feed is greater than or equal to 2 mole percent.

公开(公告)号：US20190091663A1

公开(公告)日：2019-03-28

申请号：US15772586

申请日：2016-10-14

申请人： ExxonMobil Chemical Company - Law Technology

发明人： Ulrich Kortz ,  Yixian Xiang ,  Zhengguo Lin ,  Peng Yang ,  Helge Jaensch ,  Wassim Ayass

IPC分类号： B01J23/66 ,  B01J23/50 ,  B01J21/08 ,  B01J35/02 ,  B01J37/04 ,  B01J37/16 ,  B01J37/34 ,  B01J37/02 ,  C07C5/10

摘要： The invention relates to polyoxometalates represented by the formula (An)m+{M′s[M″M12X8OyRzHq]}m− or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal-clusters, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in reductive conversion of organic substrate.

公开(公告)号：US20190070588A1

公开(公告)日：2019-03-07

申请号：US16178148

申请日：2018-11-01

申请人： Scientific Design Company, Inc.

发明人： Wojciech L. Suchanek ,  Matthew Julian

IPC分类号： B01J21/04 ,  B01J35/10 ,  B01J37/08 ,  C07D301/22 ,  C04B41/45 ,  B01J23/36 ,  B01J19/00 ,  B01J23/04 ,  C04B38/00 ,  B01J23/50 ,  C07D301/10 ,  C04B41/88 ,  C04B38/08 ,  B01J35/04 ,  B01J37/00

摘要： A precursor mixture for producing a porous body, wherein the precursor mixture comprises: (i) milled alpha alumina powder having a particle size of 0.1 to 6 microns, (ii) boehmite powder that functions as a binder of the alpha alumina powders, and (iii) burnout materials having a particle sizes of 1-10 microns. In some embodiments, an unmilled alpha alumina powder having a particle size of 10 to 100 microns is also included in said precursor mixture. Also described herein is a method for producing a porous body in which the above-described precursor mixture is formed to a given shape, and subjected to a heat treatment step in which the formed shape is sintered to produce the porous body.

公开(公告)号：US10118821B2

公开(公告)日：2018-11-06

申请号：US15204609

申请日：2016-07-07

申请人： Marine Power Products Incorporated

发明人： Jeff Carey

IPC分类号： C25B1/04 ,  C25B15/08 ,  C25B15/02 ,  C01B3/04 ,  B01J7/02 ,  C01B13/02 ,  B01J21/02 ,  B01J23/50 ,  B01J23/72 ,  B01J38/48 ,  C25B11/04

摘要： A method of and apparatus for efficient on-demand production of H2 and O2 from water and heat using environmentally safe metals are disclosed. In one aspect, the apparatus for the hydrogen generation through water decomposition reaction includes a main reactor, an oxidizer reactor, and a computer controlling system. The main reactor contains a hydrogen generating substance, such as aluminum hydroxide. In some embodiments, the main reactor includes hydroxide shuttles, such as Cu ion and Ag ion. In another aspect, the system for hydrogen generation through water decomposition includes the steps of (1) REDOX reaction, (2) pre-generation reaction, (3) generation reaction, (4) regeneration reaction, (5) second hydrogen reaction, and (6) oxygen reaction.

公开(公告)号：US10081060B2

公开(公告)日：2018-09-25

申请号：US15065076

申请日：2016-03-09

申请人： King Abdulaziz University

发明人： Hassan Amroun Ewais ,  Iqbal Mohamed Ismail

IPC分类号： B82Y40/00 ,  B22F9/24 ,  A61K8/04 ,  A61Q19/00 ,  A61K9/10 ,  A61K33/38 ,  A61K9/16 ,  A61K8/19 ,  B01J23/50 ,  B01J35/00 ,  B22F1/00 ,  B82Y5/00

CPC分类号： B22F9/24 ,  A61K8/04 ,  A61K8/19 ,  A61K9/10 ,  A61K9/1688 ,  A61K33/38 ,  A61K2800/10 ,  A61K2800/413 ,  A61K2800/805 ,  A61Q19/00 ,  B01J23/50 ,  B01J35/0013 ,  B01J37/16 ,  B22F1/0022 ,  B22F1/0044 ,  B22F1/0048 ,  B22F2009/245 ,  B22F2301/255 ,  B22F2304/054 ,  B22F2998/10 ,  B82Y5/00 ,  B82Y40/00

摘要： A method of reducing silver(I) salts to silver nanoparticles employing a carbohydrate reductant in the presence of an inorganic base, a surfactant and optionally a polymer. The method is performed in an aqueous solution at a temperature up to 60° C. and for a duration of up to 40 minutes.

公开(公告)号：US10052692B2

公开(公告)日：2018-08-21

申请号：US14420897

申请日：2013-08-12

申请人： Council of Scientific & Industrial Research

发明人： Prasad Lakshmi Vara Bhagavatula ,  Jhumur Seth

IPC分类号： B22F9/24 ,  B22F1/00 ,  B82Y30/00 ,  B01J23/42 ,  B01J23/44 ,  B01J23/46 ,  B01J23/50 ,  B01J35/02 ,  B01J37/16

CPC分类号： B22F9/24 ,  B01J23/42 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/50 ,  B01J35/026 ,  B01J37/16 ,  B22F1/0011 ,  B22F1/0018 ,  B22F2009/245 ,  B82Y30/00

摘要： Disclosed is a one pot process for the synthesis of ultra-small uniform-sized (1-3 nm) transition metal nanoparticles with shape tunability. These nanoparticles have uses in various fields, including catalysis and fuel cells.