公开(公告)号：US09765164B2

公开(公告)日：2017-09-19

申请号：US14316877

申请日：2014-06-27

申请人： Dow Global Technologies LLC

发明人： David W. Kababik ,  Kathleen E. Pletcher ,  Jian Wang ,  Jason C. Brodil ,  Troy M. Tambling ,  Robert N. Reib ,  Mridula Kapur

IPC分类号： B32B1/02 ,  C08F210/16 ,  B65D43/02 ,  B32B1/08

CPC分类号： C08F210/16 ,  B65D43/02 ,  B65D2543/00296 ,  C08F4/65925 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/13 ,  C08F2500/19

摘要： A linear low density polyethylene composition suitable for injection molding applications comprising less than or equal to 100 percent by weight of the units derived from ethylene, less than 35 percent by weight of units derived from one or more α-olefin comonomers, and characterized by its density, molecular weight distribution (Mw/Mn), a melt index (I2), a molecular weight distribution (Mz/Mw), vinyl unsaturation, and zero shear viscosity ratio (ZSVR). The linear low density polyethylene composition exhibits low hexane extractable levels.

公开(公告)号：US20170226396A1

公开(公告)日：2017-08-10

申请号：US15501878

申请日：2014-09-22

申请人： Dow Global Technologies LLC

发明人： Yunfeng Yang ,  Hongyu Chen ,  Brad C. Bailey ,  Mohamed Esseghir ,  Suh Joon Han

IPC分类号： C09K5/10 ,  C08K3/28 ,  C08K3/22

CPC分类号： C09K5/10 ,  B01J31/22 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/02 ,  C08K3/22 ,  C08K3/28 ,  C08K2003/2227 ,  C08K2003/2296 ,  C08K2003/282 ,  C10M107/06 ,  C10M169/02 ,  C10M2201/0416 ,  C10M2201/0616 ,  C10M2201/0626 ,  C10M2201/0656 ,  C10M2205/0225 ,  C10M2229/041 ,  C10M2229/042 ,  C10M2229/045 ,  C10N2220/022 ,  C10N2220/028 ,  C10N2230/08 ,  C08F2500/10 ,  C08F2500/02 ,  C08F10/02 ,  C08F4/64193 ,  C08F210/16 ,  C08F210/06 ,  C08F2500/17 ,  C08L23/14 ,  C08L23/06 ,  C10M2205/0245 ,  C10M2205/0285

摘要： Disclosed is an effective thermal grease comprising a hyperbranched olefinic fluid and a thermally conductive filler. Property-modifying additives and fillers may also be included. The hyperbranched olefinic fluid is selected to have an average of at least 1.5 methine carbons per oligomer molecule and at least 40 methine carbons per one thousand total carbons. The thermal grease exhibits a flash point of 180° C. or higher, a pour point of 0° C. or lower, and a kinematic viscosity at 40° C. of no more than 200 cSt (0.0002 m 2/s). The composition may offer improved thermal conductivity, reduced tendency to migrate, and lower cost when compared with many other thermal greases, including silicone-based thermal greases.

公开(公告)号：US09718898B1

公开(公告)日：2017-08-01

申请号：US15365848

申请日：2016-11-30

申请人： LION COPOLYMER GEISMAR, LLC

发明人： Willie Charles Burton ,  David G. Ward

IPC分类号： C08F4/6592 ,  C08F2/06 ,  C08F10/14 ,  C08F4/659

CPC分类号： C08F4/6592 ,  C08F2/06 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/14 ,  C08F110/14 ,  C08F2500/17 ,  C08F2500/02 ,  C08F4/65904 ,  C08F4/68 ,  C08F4/651

摘要： A homogeneous polymerization catalyst system for polymerization or copolymerization of at least one alpha olefin has a Lewis acid, an alkyl aluminum in a hexane or a heptane, and at least one dry metallocene. The at least one dry metallocene has a transition metal compound. The Lewis acid is capable of forming an ion pair with the at least one dry metallocene. The homogeneous polymerization catalyst system produces a poly alpha olefin from alpha olefin monomers or mixed alpha olefins. A produced poly alpha olefin has a kinematic viscosity at 100 degrees Celsius ranging from 1 cSt to 1000 cSt.

公开(公告)号：US09688792B2

公开(公告)日：2017-06-27

申请号：US14725540

申请日：2015-05-29

申请人： TOTAL RESEARCH & TECHNOLOGY FELUY

发明人： Alexandre Welle ,  Jeroen Wassenaar ,  Martine Slawinski

IPC分类号： C08F4/6592 ,  C08F10/14 ,  C07F17/00 ,  C08F110/14 ,  C08F4/659 ,  C07C2/34 ,  C07C5/03 ,  B01J31/22

CPC分类号： C08F110/14 ,  B01J31/2295 ,  B01J2531/48 ,  C07C2/34 ,  C07C5/03 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/755 ,  C07C2523/882 ,  C07C2531/14 ,  C07C2531/22 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/14 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/17 ,  C07C11/02 ,  C07C9/22

摘要： A process may include contacting an olefin monomer and a racemic bridged metallocene catalyst at a temperature of 80° C. to 150° C. in the presence of hydrogen. The racemic bridged metallocene catalyst may include a metallocene compound (A) and an activator component (B). The process may include recovering an effluent containing polyalpha-olefins (PAOs). The metallocene compound (A) may be represented by the formula R(Cp1)(Cp2)MX1X2. In the formula, R may be a C1-C20 alkylene bridging group; Cp1 and Cp2 may be the same or different substituted or unsubstituted tetrahydroindenyl rings; M may be a transition metal; and X1 and X2 may be independently selected from hydrogen, halogen, hydride radicals, hydrocarbyl radicals, substituted hydrocarbyl radicals, halocarbyl radicals, substituted halocarbyl radicals, silylcarbyl radicals, substituted silylcarbyl radicals, germylcarbyl radicals, substituted germylcarbyl radicals.

公开(公告)号：US20170137550A1

公开(公告)日：2017-05-18

申请号：US15310553

申请日：2015-07-23

申请人： Dow Global Technologies LLC

发明人： Sean W. Ewart ,  Richard J. Keaton ,  Jerzy Klosin ,  Ruth Figueroa

IPC分类号： C08F210/16

CPC分类号： C08F210/16 ,  B01J31/2226 ,  C07F7/00 ,  C07F7/003 ,  C08F4/65904 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F4/64193 ,  C08F2500/02 ,  C08F2500/08 ,  C08F2500/17

摘要： The invention provides a process, and transition metal complex, to form an ethylene-based polymer, said process comprising polymerizing ethylene, and optionally at least one comonomer, in the presence of at least one molecular transition metal complex selected from Formula 1, as described herein.

公开(公告)号：US09631038B2

公开(公告)日：2017-04-25

申请号：US14052490

申请日：2013-10-11

申请人： University of Massachusetts ,  Infineum International Limited

发明人： Rudolf Faust ,  Rajeev Kumar ,  Jacob Emert

IPC分类号： C08F4/52 ,  C08F4/70 ,  C08F4/80 ,  C08F110/10

CPC分类号： C08F110/10 ,  C08F4/52 ,  C08F4/70 ,  C08F4/80 ,  C08F4/26 ,  C08F4/14 ,  C08F4/12 ,  C08F4/16 ,  C08F4/22 ,  C08F2500/02 ,  C08F2500/03

摘要： A method for producing highly reactive olefin polymers wherein at least 50 mol. % of the polymer chains have terminal double bonds, and a novel polymerization initiating system for accomplishing same.

公开(公告)号：US20170101354A1

公开(公告)日：2017-04-13

申请号：US15126792

申请日：2015-02-02

申请人： NOVA Chemicals (International) S.A.

发明人： Stephen Brown ,  Peter Zoricak ,  Eric Clavelle

IPC分类号： C07C2/32 ,  B01J19/00 ,  B01J14/00

CPC分类号： C07C2/32 ,  B01J8/10 ,  B01J14/00 ,  B01J19/002 ,  B01J19/0066 ,  B01J19/18 ,  B01J2208/00867 ,  B01J2219/00033 ,  B01J2219/00247 ,  B01J2219/00252 ,  B01J2219/0099 ,  C07C2/36 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24 ,  C07C2531/34 ,  C08F10/02 ,  C08F2/002 ,  C08F2/01 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/02 ,  C07C11/107 ,  C07C11/02

摘要： This invention relates to a self cleaning reactor and to a process for the oligomerization of ethylene that employs a self-cleaning reactor. The reactor includes a mass of inert, particulate cleaning bodies that are entrained by the liquid in the reactor and scour the internal surfaces of the reactor during normal operation. This scouring action reduces the level of fouling on the reactor surfaces. Foulant material (polyethylene) is removed from the process on a continuous basis but the cleaning bodies remain within the reactor.

公开(公告)号：US09593171B2

公开(公告)日：2017-03-14

申请号：US14111144

申请日：2012-03-29

申请人： Simona Guidotti ,  Giampiero Morini ,  Simona Esposito ,  Alessandro Mignogna ,  Joachim T. M. Pater ,  Fabrizio Piemontesi ,  Diego Brita

发明人： Simona Guidotti ,  Giampiero Morini ,  Simona Esposito ,  Alessandro Mignogna ,  Joachim T. M. Pater ,  Fabrizio Piemontesi ,  Diego Brita

IPC分类号： C08F4/16 ,  C08F10/06

CPC分类号： C08F4/16 ,  C08F10/06 ,  C08F4/651 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/02 ,  C08F210/06 ,  C08F2/001

摘要： A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.

摘要翻译： 一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于 事实上，ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或 等于0.60。

公开(公告)号：US09586982B2

公开(公告)日：2017-03-07

申请号：US14901394

申请日：2014-06-26

申请人： IFP ENERGIES NOUVELLES ,  UNIVERSITEIT VAN AMSTERDAM

发明人： Pierre-Alain Breuil ,  Pierre Boulens ,  Joost Reek ,  Helene Olivier-Bourbigou

IPC分类号： C07F9/09 ,  C07F15/04 ,  C08F4/80 ,  C07C2/36 ,  B01J31/18 ,  C07C2/32

CPC分类号： C07F15/045 ,  B01J31/00 ,  B01J31/188 ,  B01J2231/20 ,  B01J2531/847 ,  C07C2/32 ,  C07C2/36 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24 ,  C08F4/80 ,  C08F110/02 ,  C08F2500/02 ,  C08F110/06 ,  C07C11/107 ,  C07C11/08

摘要： The invention describes a novel dissymmetric nickel-based complex and the method of preparation thereof from at least one diphosphinamine ligand B1 of formula (R1)(R′1)P—N(R3)—P(R2)(R′2), or an iminobisphosphine ligand B2 of formula (R3)N═P(R1)(R′1)—P(R2)(R′2). The invention also concerns the use of said complex in a method for oligomerisation of olefins.

摘要翻译： 本发明描述了一种新的不对称镍基络合物及其由式（R1）（R'1）P-N（R3）-P（R2）（R'2）的至少一种二磷酸胞嘧啶配体B1制备的方法， 或式（R3）N = P（R1）（R'1）-P（R2）（R'2）的亚氨基双膦配体B2。 本发明还涉及在烯烃低聚方法中使用所述络合物。

公开(公告)号：US20170008983A1

公开(公告)日：2017-01-12

申请号：US15117816

申请日：2015-02-10

申请人： UNIVATION TECHNOLOGIES, LLC

发明人： Francis C. Rix ,  Ching-Tai Lue ,  Timothy M. Boller ,  Garth R. Giesbrecht ,  C. Jeff Harlan

IPC分类号： C08F210/02

CPC分类号： C08F210/16 ,  C07F17/00 ,  C08F2/00 ,  C08F2/34 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/76 ,  C08F210/02 ,  C08F210/08 ,  C08F210/14 ,  C08F2410/02 ,  C08F2420/00 ,  C08F2420/01 ,  C08F2500/01 ,  C08F2500/02 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/18 ,  C08F2800/20 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08F2500/03

摘要： Catalyst systems and methods for making and using the same are described. A method includes selecting a catalyst blend using a blend polydispersity index (bPDI) map. The polydispersity map is generated by generating a number of polymers for at least two catalysts. Each polymer is generated at a different hydrogen to ethylene ratio. At least one catalyst generates a higher molecular weight polymer and another catalyst generates a lower molecular weight polymer. A molecular weight for each polymer is measured. The relationship between the molecular weight of the polymers generated by each of the catalysts and the ratio of hydrogen to ethylene is determined. A family of bPDI curves for polymers that would be made using a number of ratios of a blend of the at least two catalysts for each of a number of ratios of hydrogen to ethylene. A ratio for the catalyst blend of the catalysts that generates a polymer having a bPDI that matches a polymer fabrication process is selected, and the product specific polyolefin is made using the catalyst blend.

摘要翻译： 描述了用于制造和使用催化剂体系的催化剂体系和方法。 一种方法包括使用共混多分散指数（bPDI）图选择催化剂共混物。 通过产生用于至少两种催化剂的多种聚合物来产生多分散性图。 每个聚合物以不同的氢气与乙烯的比例产生。 至少一种催化剂产生较高分子量的聚合物，另一种催化剂产生较低分子量的聚合物。 测量每种聚合物的分子量。 确定由各催化剂产生的聚合物的分子量与氢与乙烯的比例之间的关系。 对于聚合物的一组bPDI曲线，其将使用多种比例的氢与乙烯的比例的至少两种催化剂的共混物来制备。 选择产生具有与聚合物制造工艺匹配的bPDI的聚合物的催化剂的催化剂共混物的比例，并且使用催化剂共混物制备产品特定聚烯烃。