公开(公告)号：US20240336715A1

公开(公告)日：2024-10-10

申请号：US18746829

申请日：2024-06-18

Applicant: Lion Copolymer Geismar, LLC

Inventor： SOLOMON H. K. TANG ,  Willie Charles Burton ,  Alrica L.J. Payne ,  Michael Durousseau

IPC: C08F210/18 ,  C08L23/16

CPC classification number: C08F210/18 ,  C08L23/16 ,  C08L2205/025

Abstract: Disclosed herein are EPDM-diene copolymers that have a low molecular weight and are liquid at room temperature. In a specific embodiment, the method of making the copolymer includes: adding a solvent to a reactor; adding a propylene and a catalyst mixture to the solvent in the reactor to make a first reaction mixture, where the catalyst mixture includes: one or more catalysts, one or more cocatalysts, and one or more catalyst reactivators; contacting an ethylene to the first reaction mixture to make a second reaction mixture; and contacting a vinyl norbornene to the second reaction mixture to make a copolymer, where the copolymer has a molecular weight from about 2,500 g/mol to about 1,000,000 g/mol, and where the copolymer has a viscosity from about 1,000 cP to about 2,500,000 cP at 100° C.

公开(公告)号：US20220340786A1

公开(公告)日：2022-10-27

申请号：US17730634

申请日：2022-04-27

Applicant: LION COPOLYMER GEISMAR, LLC

Inventor： Xianjie (Tony) REN ,  John D. Jacquin ,  Qiang Luo ,  Gregory J. Brust

IPC: C09J7/38 ,  C09J7/10 ,  C09J11/08

Abstract: Disclosed herein are pressure sensitive adhesive compositions that can include a styrene-butadiene rubber latex and a tackifier agent. In another example, the pressure sensitive adhesive compositions can include a styrene-butadiene rubber latex and acrylic polymer. The adhesive compositions can further include mineral oil and ethylene propylene diene monomer rubber. The pressure sensitive adhesives compositions can have a have low volatile organic compound vapor pressures while having effective adhesion properties on low surface energy substrates.

公开(公告)号：US09718897B1

公开(公告)日：2017-08-01

申请号：US15365806

申请日：2016-11-30

Applicant: LION COPOLYMER GEISMAR, LLC

Inventor： Willie Charles Burton ,  David G. Ward

IPC: C08F2/06 ,  C08F10/14 ,  C08F4/6592 ,  C08F4/659

CPC classification number: C08F4/6592 ,  C08F2/06 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/14 ,  C08F110/14 ,  C08F2500/17 ,  C08F2500/02 ,  C08F4/68 ,  C08F4/651 ,  C08F4/65904

Abstract: A solution process for the polymerization or copolymerization of at least one alpha olefin can include adding a Lewis acid to an alkyl aluminum in a hexane or heptane to form a coordination complex, stirring the coordination complex continuously forming a near homogeneous solution in an inert anhydrous environment, adding at least one dry metallocene to the near homogenous solution forming a soluble polymerization initiator, then stirring to form a near homogenous metallocene enriched polymerization initiator, and polymerizing an alpha olefin with the metallocene enriched polymerization initiator and optionally adding additional alkyl aluminum as a moisture scavenger or an impurities scavenger to yield a poly alpha olefin. The at least one dry metallocene can have a transition metal compound. The Lewis acid is capable of forming an ion pair with the at least one dry metallocene.

公开(公告)号：US09139727B2

公开(公告)日：2015-09-22

申请号：US14554760

申请日：2014-11-26

Applicant: LION COPOLYMER GEISMAR, LLC

Inventor： Solomon H. K. Tang ,  Willie Charles Burton ,  Garrett Doucet

IPC: C08L47/00 ,  C08L23/16 ,  C08F210/06 ,  C08F210/18 ,  C08L23/14 ,  C08F4/68

CPC classification number: C08L47/00 ,  C08F210/06 ,  C08F210/18 ,  C08L23/145 ,  C08L23/16 ,  C08L2201/56 ,  C08L2205/025 ,  Y10S526/905 ,  C08F4/68 ,  C08F236/20 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/25 ,  C08F210/08 ,  C08F2/001

Abstract: A low damping high strength polymer with a blend of a terpolymer and a tetrapolymer utilizing ethylene, propylene, and non-conjugated dienes. This polymer allows for the creation of products with high diene contents and broad molecular weight distributions while utilizing a continuous flow reactor and a known catalyst. The polymer allows for these products to be made without gelling or fouling of the reactor, which are problems known in the art.

Abstract translation: 低阻尼高强度聚合物，其具有三元共聚物和使用乙烯，丙烯和非共轭二烯的四元共聚物的共混物。 该聚合物允许产生具有高二烯含量和宽分子量分布的产物，同时使用连续流动反应器和已知的催化剂。 聚合物允许制造这些产品而不会使反应器凝胶化或结垢，这是本领域已知的问题。

公开(公告)号：US09574034B1

公开(公告)日：2017-02-21

申请号：US15247049

申请日：2016-08-25

Applicant: LION COPOLYMER GEISMAR, LLC

Inventor： Solomon H. K. Tang ,  Willie Charles Burton ,  Garrett Doucet

IPC: C08F210/18 ,  C08K5/101 ,  C08K5/134

CPC classification number: C08F210/18 ,  C08F4/65908 ,  C08F4/65912 ,  C08K5/005 ,  C08K5/1345 ,  C08L23/145 ,  C08L91/00 ,  C08F4/68 ,  C08F4/65927 ,  C08F2/001 ,  C08F210/06 ,  C08F236/20 ,  C08F2500/01 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/19

Abstract: A process and articles for continuously making a tetrapolymer can use two reactors connected in series with two saturated hydrocarbon streams, two injections of ethylene monomer, two injections of propylene monomer, and two injections of two different non-conjugated diene monomers simultaneously. Also, the process has a metallocene catalyst and a metallocene co-catalyst in the first reactor and a Ziegler-Natta catalyst, a Ziegler-Natta co-catalyst, and optionally a promoter in the second reactor. This process allows for the creation of products with high molecular weights while utilizing continuous flow reactors in series. The process allows for manufacture of anti-vibration articles made from the high molecular weight tetrapolymers.

Abstract translation: 用于连续制备四聚物的方法和制品可以使用两个与两个饱和烃流串联的反应器，两次注入乙烯单体，两次注入丙烯单体，同时两次注入两种不同的非共轭二烯单体。 此外，该方法在第一反应器中具有茂金属催化剂和茂金属助催化剂，在第二反应器中具有齐格勒 - 纳塔催化剂，齐格勒 - 纳塔助催化剂和任选的促进剂。 该方法允许创建具有高分子量的产物，同时使用串联的连续流动反应器。 该方法允许制造由高分子量四元共聚物制成的抗振动制品。

公开(公告)号：US20140364534A1

公开(公告)日：2014-12-11

申请号：US14254219

申请日：2014-04-16

Applicant: LION COPOLYMER GEISMAR, LLC

Inventor： Michael J. Molnar ,  George A. Von Bodungen ,  Subir Debnath ,  Harold William Young, JR. ,  Zhiyong Zhu

IPC: C08L23/08 ,  C08L67/00 ,  C08L63/00 ,  C08L33/08 ,  C08L75/04

CPC classification number: C08L23/0823 ,  C08F8/34 ,  C08F210/18 ,  C08J3/05 ,  C08J3/07 ,  C08J3/11 ,  C08J3/243 ,  C08J3/244 ,  C08J3/248 ,  C08J3/26 ,  C08J2323/16 ,  C08K13/02 ,  C08L33/08 ,  C08L63/00 ,  C08L67/00 ,  C08L75/04 ,  C08L2201/54 ,  C08L2312/00 ,  C09D123/16 ,  C08L23/16 ,  C08L2205/025

Abstract: Latex blend formulations that include a high solids cross-linked ethylene propylene diene terpolymer latex with acrylics, polyurethane, epoxy, or alkyd resin usable as a waterproofing material for roofs or usable in paints and adhesives.

Abstract translation: 乳胶共混物配方包括高固含量交联乙丙丙烯二烯三元共聚物胶乳与丙烯酸，聚氨酯，环氧树脂或醇酸树脂，可用作屋顶防水材料或可用于油漆和粘合剂。

公开(公告)号：US08901194B2

公开(公告)日：2014-12-02

申请号：US14179448

申请日：2014-02-12

Applicant: Lion Copolymer Geismar, LLC

Inventor： Michael J. Molnar ,  Daniel S. Nelson ,  Arthur J. Fontenot, III ,  Harold William Young, Jr. ,  Augusto Caesar Ibay ,  Zhiyong Zhu

IPC: C08F299/02 ,  C08F2/50 ,  C08F2/46 ,  B29C71/04 ,  A61L2/08 ,  A61L24/00 ,  C08G61/04 ,  C09D123/16 ,  C08K13/02 ,  C08K3/36 ,  C08K5/01 ,  C08K5/5419 ,  C09D7/00 ,  C09D109/00 ,  C09D5/14 ,  C09D7/02 ,  C09D7/12 ,  C08L9/00

CPC classification number: C09D123/16 ,  C08K3/36 ,  C08K5/01 ,  C08K5/09 ,  C08K5/13 ,  C08K5/1515 ,  C08K5/3415 ,  C08K5/3417 ,  C08K5/5419 ,  C08K13/02 ,  C08L9/00 ,  C09D5/14 ,  C09D7/00 ,  C09D109/00 ,  C08K5/14 ,  C08L23/16

Abstract: A durable ambient light curable waterproof liquid rubber coating with volatile organic compound (VOC) content of less than 450 grams per liter made from ethylene propylene diene terpolymer (EPDM) in a solvent, a photoinitiator, an additive, pigments, and fillers, and a co-agent and a method for making the formulation, wherein the formulation is devoid of thermally activated accelerators.

Abstract translation: 在溶剂，光引发剂，添加剂，颜料和填料中由乙烯丙烯二烯三元共聚物（EPDM）制成的具有小于450克/升的挥发性有机化合物（VOC）含量的耐用环境光可固化防水液体橡胶涂层和 助剂和制备该制剂的方法，其中制剂没有热活化促进剂。

公开(公告)号：US08859638B1

公开(公告)日：2014-10-14

申请号：US14228153

申请日：2014-03-27

Applicant: Lion Copolymer Geismar, LLC

Inventor： Michael J. Molnar ,  George A. Von Bodungen ,  Subir Debnath ,  Harold William Young, Jr. ,  Zhiyong Zhu

IPC: C09D5/16 ,  C08K13/02 ,  C08L23/08 ,  C09D145/00 ,  C09D123/14 ,  C09J145/00 ,  C09J123/14 ,  C08J3/11 ,  C08J3/05 ,  C08J3/24 ,  C08J3/26 ,  C08J3/07 ,  C08F8/34 ,  C08F210/18

CPC classification number: C08L23/0823 ,  C08F8/34 ,  C08F210/18 ,  C08J3/05 ,  C08J3/07 ,  C08J3/11 ,  C08J3/243 ,  C08J3/244 ,  C08J3/248 ,  C08J3/26 ,  C08J2323/16 ,  C08K13/02 ,  C08L33/08 ,  C08L63/00 ,  C08L67/00 ,  C08L75/04 ,  C08L2201/54 ,  C08L2312/00 ,  C09D123/16 ,  C08L23/16 ,  C08L2205/025

Abstract: A low pressure, low volatile, low energy method to make an ethylene, propylene diene terpolymer latex usable in paints, adhesives, and as a coating.

Abstract translation: 一种低压，低挥发性，低能量的方法来制备可用于油漆，粘合剂和作为涂层的乙烯，丙烯二烯三元共聚物胶乳。

公开(公告)号：US20140228476A1

公开(公告)日：2014-08-14

申请号：US14179482

申请日：2014-02-12

Applicant: LION COPOLYMER GEISMAR, LLC

Inventor： Michael J. Molnar ,  Arthur J. Fontenot, III ,  Harold William Young, JR. ,  Daniel S. Nelson ,  Augusto Caesar Ibay

IPC: C09D5/14 ,  C08K13/02

CPC classification number: C09D123/16 ,  C08K3/36 ,  C08K5/01 ,  C08K5/09 ,  C08K5/13 ,  C08K5/1515 ,  C08K5/3415 ,  C08K5/3417 ,  C08K5/5419 ,  C08K13/02 ,  C08L9/00 ,  C09D5/14 ,  C09D7/00 ,  C09D109/00 ,  C08K5/14 ,  C08L23/16

Abstract: A two part low volatile organic compounds (VOC) content ethylene propylene diene terpolymer formulation with a solids content of at least 60 percent solids by volume of the total formulation and a volatile organic compounds content less than 450 grams per liter, wherein a first component has EPDM, a solvent, a curative, an additive, and a blend of a pigment and a filler. The second component contains solvent and a metal drier. The invention includes a method for making the coating and a cured coated substrate with the cured waterproof rubber coating disposed thereon.

Abstract translation: 一种两部分低挥发性有机化合物（VOC）含量的乙烯丙烯二烯三元共聚物制剂，其固体含量为总制剂的至少60体积％固体含量，挥发性有机化合物含量低于450克/升，其中第一组分具有 EPDM，溶剂，固化剂，添加剂和颜料和填料的共混物。 第二组分含有溶剂和金属干燥剂。 本发明包括一种制备涂层的方法以及固化的涂覆的基材，其上固化的防水橡胶涂层设置在其上。

公开(公告)号：US20140228469A1

公开(公告)日：2014-08-14

申请号：US14179436

申请日：2014-02-12

Applicant: LION COPOLYMER GEISMAR, LLC

Inventor： Michael J. Molnar ,  Daniel S. Nelson ,  Arthur J. Fontenot, III ,  Harold William Young, JR. ,  Augusto Caesar Ibay ,  Zhiyong Zhu

IPC: C09D7/12 ,  C09D5/14 ,  C09D7/02

CPC classification number: C09D123/16 ,  C08K3/36 ,  C08K5/01 ,  C08K5/09 ,  C08K5/13 ,  C08K5/1515 ,  C08K5/3415 ,  C08K5/3417 ,  C08K5/5419 ,  C08K13/02 ,  C08L9/00 ,  C09D5/14 ,  C09D7/00 ,  C09D109/00 ,  C08K5/14 ,  C08L23/16

Abstract: A durable ambient light curable waterproof liquid rubber coating with volatile organic compound (VOC) content of less than 450 grams per liter made from ethylene propylene diene terpolymer (EPDM) in a solvent, a photoinitiator, an additive, pigments, and fillers, and a co-agent and a method for making the formulation, wherein the formulation is devoid of thermally activated accelerators.

Abstract translation: 在溶剂，光引发剂，添加剂，颜料和填料中由乙烯丙烯二烯三元共聚物（EPDM）制成的具有小于450克/升的挥发性有机化合物（VOC）含量的耐用环境光可固化防水液体橡胶涂层和 助剂和制备该制剂的方法，其中所述制剂没有热活化促进剂。