公开(公告)号：US20010044563A1

公开(公告)日：2001-11-22

申请号：US09884655

申请日：2001-06-20

Inventor： Ulrich Steinbrenner ,  Eugen Gehrer

IPC: C07C015/067 ,  C07C002/04 ,  C07C005/25 ,  C07C002/24

CPC classification number: C07C2/72 ,  B01J23/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/18 ,  C07C2523/50 ,  C07C2523/52

Abstract: A catalyst comprising at least one alkali metal and at least one metallic or semimetallic promoter selected from the group consisting of Ca, Sr, Ba, Ag, Au, Zn, Cd, Hg, In, Tl, Sn, As, Sb and Bi, on a support which may be doped with one or more compounds of an alkali metal and/or alkaline earth metal, where the alkali metal/support ratio by weight is from 0.01 to 5, the promoter/alkali metal ratio by weight is from 0.0001 to 5 and, when a dopant is present, the dopant/support ratio by weight is from 0.01 to 5.

Abstract translation: 一种包含至少一种碱金属和至少一种选自Ca，Sr，Ba，Ag，Au，Zn，Cd，Hg，In，Tl，Sn，As，Sb和Bi的金属或半金属助催化剂的催化剂， 在可以掺杂一种或多种碱金属和/或碱土金属的化合物的载体上，其中碱金属/载体比例为0.01至5，助催化剂/碱金属重量比为0.0001至 并且当存在掺杂剂时，掺杂剂/载体的重量比为0.01至5。

公开(公告)号：US6060423A

公开(公告)日：2000-05-09

申请号：US296658

申请日：1999-04-23

Applicant: Yu-Wen Chen ,  Sung-Cheng Hu

Inventor： Yu-Wen Chen ,  Sung-Cheng Hu

IPC: B01J23/00 ,  B01J23/46 ,  B01J23/62 ,  B01J37/03 ,  B01J37/16 ,  C07B61/00 ,  C07C5/11 ,  C07C13/18 ,  B01J23/06 ,  B01J23/08

CPC classification number: C07C5/11 ,  B01J23/002 ,  B01J23/462 ,  B01J23/62 ,  B01J2523/00 ,  C07C2101/16 ,  C07C2523/06 ,  C07C2523/08 ,  C07C2523/40 ,  C07C2523/46 ,  C07C2523/62 ,  C07C2523/74 ,  Y02P20/52

Abstract: A catalyst suitable for partially hydrogenating aromatic olefins to cyclohexene is disclosed. The catalyst is composed on a metallic active component deposited on a bi-oxide of gallium oxide-zinc oxide, and the metallic active component is selected from group VIII of the period table. The characteristic of the catalyst comprises a higher selectivity and yield in preparing cyclohexene.

Abstract translation: 公开了一种适用于将芳族烯烃部分氢化成环己烯的催化剂。 催化剂由沉积在氧化镓 - 氧化锌的双氧化物上的金属活性组分构成，金属活性组分选自周期表的VIII族。 催化剂的特性在制备环己烯时具有更高的选择性和产率。

公开(公告)号：US6015930A

公开(公告)日：2000-01-18

申请号：US892508

申请日：1997-07-14

Applicant: Donald S. Santilli ,  Cong-Yan Chen

Inventor： Donald S. Santilli ,  Cong-Yan Chen

IPC: B01J29/068 ,  C07B61/00 ,  C07C5/13 ,  C07C5/367 ,  C07C15/24 ,  C07C1/00 ,  C07C5/22

CPC classification number: C07C15/24 ,  C07C5/13 ,  C07C5/367 ,  C07C2102/10 ,  C07C2102/28 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/26 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/656 ,  C07C2523/745 ,  C07C2529/04 ,  C07C2529/08 ,  C07C2529/44 ,  C07C2529/74 ,  C07C2529/85

Abstract: The invention discloses a method of making 2,6-dimethylnaphthalene from any DMN with one methyl on each ring in a two-step hydroisomerization/dehydrogenation process. The catalyst used in the hydroisomerization step is an acidic catalyst such as a silica aluminum catalyst with a hydrogenation/dehydrogenation metal. The catalyst used in the dehydrogenation step is a reforming type catalyst.

Abstract translation: 本发明公开了一种在两步加氢异构化/脱氢方法中从每个环上由一个甲基制备2,6-二甲基萘的方法。 用于加氢异构化步骤的催化剂是酸性催化剂，例如具有氢化/脱氢金属的二氧化硅铝催化剂。 在脱氢步骤中使用的催化剂是重整型催化剂。

公开(公告)号：US5955641A

公开(公告)日：1999-09-21

申请号：US86295

申请日：1998-05-28

Applicant: Cong-Yan Chen ,  William L. Schinski ,  Dennis J. O'Rear ,  Thomas V. Harris

Inventor： Cong-Yan Chen ,  William L. Schinski ,  Dennis J. O'Rear ,  Thomas V. Harris

IPC: C07C2/66 ,  C07C2/68 ,  C07C5/367 ,  C07C5/41 ,  C07C15/24 ,  C10G57/00 ,  C07C1/00 ,  C07C2/70 ,  C10G35/06

CPC classification number: C07C15/24 ,  C07C2/66 ,  C07C2/68 ,  C07C5/415 ,  C07C2521/16 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/36 ,  C07C2523/74 ,  C07C2527/126 ,  C07C2529/06 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/50 ,  C07C2529/65 ,  C07C2529/70 ,  C10G2400/30

Abstract: The method of the invention includes making dimethyinaphthalenes by first contacting, in an alkylation zone, at alkylation conditions, a toluene-containing stream with a pentene-containing stream in the presence of an acid alkylation catalyst. At least a portion of the toluene and pentenes react to form pentyltoluenes. At least a portion of the pentyltoluenes is then contacting in a reforming zone with reforming catalyst, at reforming conditions. At least a portion of the pentyltoluenes is converted to dimethylnaphthalenes.

Abstract translation: 本发明的方法包括通过在烷基化区，在烷基化条件下，在酸性烷基化催化剂的存在下，将含甲苯的物流与含戊烯的物流接触来制备二甲基萘。 至少一部分甲苯和戊烯反应形成戊基甲苯。 在重整条件下，至少一部分戊基甲苯然后在重整区与重整催化剂接触。 将至少一部分戊基甲苯转化为二甲基萘。

公开(公告)号：US5677260A

公开(公告)日：1997-10-14

申请号：US494313

申请日：1995-06-23

Applicant: Rajeshwer Dongara ,  Arun Gurudath Basrur ,  Dattatraya Tammannashastri Gokak ,  Karumanchi Venkateshwara Rao ,  Konda Ramaswamy Krishnamurthy ,  Ishwar Singh Bhardwaj

Inventor： Rajeshwer Dongara ,  Arun Gurudath Basrur ,  Dattatraya Tammannashastri Gokak ,  Karumanchi Venkateshwara Rao ,  Konda Ramaswamy Krishnamurthy ,  Ishwar Singh Bhardwaj

IPC: B01J23/89 ,  B01J37/02 ,  C07C5/333 ,  B01J23/32 ,  B01J23/72

CPC classification number: B01J37/0205 ,  B01J23/8966 ,  C07C5/3337 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/38 ,  C07C2523/58 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/89

Abstract: A novel catalyst composite for use in the dehydrogenation of paraffins to the corresponding monoolefins said composite incorporating within its spatial geometry on a percentage by weight basis a predetermined concentration gradient of a noble metal, a metal of Group IV A, a metal of Group III A, an alkali or alkaline earth metal element, a halogen; and a metal of Group VIII selected from. Fe, Co and Ni provided on a high surface area mesoporous support and a process for the preparation thereof.

Abstract translation: 一种用于将链烷烃脱氢成相应的单烯烃的新型催化剂复合材料，所述复合材料在其空间几何形状内基于重量百分比以预定的贵金属浓度梯度，IVA族金属，IIIA族金属 ，碱金属或碱土金属元素，卤素; 和选自第Ⅷ族的金属。 在高表面积介孔载体上提供Fe，Co和Ni及其制备方法。

公开(公告)号：US5434118A

公开(公告)日：1995-07-18

申请号：US134854

申请日：1993-10-12

Applicant: Angela Carati ,  Enrico Davini ,  Mario G. Clerici ,  Giuseppe Bellussi

Inventor： Angela Carati ,  Enrico Davini ,  Mario G. Clerici ,  Giuseppe Bellussi

IPC: B01J21/08 ,  B01J23/08 ,  B01J23/14 ,  B01J23/22 ,  B01J27/18 ,  B01J37/00 ,  B01J37/03 ,  C01B33/16 ,  C07B33/00 ,  C07B37/02 ,  C07B61/00 ,  C07C2/10 ,  C07C2/58 ,  C07C2/66 ,  C07C11/02 ,  C07C15/02 ,  C07C37/60 ,  C07C249/04 ,  C07C251/44 ,  C07D301/19 ,  C07D303/04 ,  C07D303/14 ,  B01J21/12

CPC classification number: C07D301/19 ,  B01J21/08 ,  B01J37/033 ,  C07C2/10 ,  C07C2/66 ,  C07C249/04 ,  C07C37/60 ,  C07D303/04 ,  C07D303/14 ,  C07C2521/08 ,  C07C2523/08 ,  C07C2523/745

Abstract: A catalytically active gel product is described consisting of a silica matrix which is amorphous to x-rays with uniform porosity, monomodal pore distribution and high surface area, within which one or more metal oxides possessing catalytic activity are dispersed. A process for preparing this catalytic gel is also described.

Abstract translation: 描述了一种催化活性凝胶产物，其由具有均匀孔隙率，单峰孔分布和高表面积的x射线无定形的二氧化硅基质组成，其中分散了一种或多种具有催化活性的金属氧化物。 还描述了制备该催化凝胶的方法。

公开(公告)号：US5149679A

公开(公告)日：1992-09-22

申请号：US517334

申请日：1990-05-01

Applicant: Geoffrey L. Price ,  Vladislav I. Kanazirev ,  Kerry M. Dooley

Inventor： Geoffrey L. Price ,  Vladislav I. Kanazirev ,  Kerry M. Dooley

IPC: B01J29/40 ,  B01J29/70 ,  C07C2/00

CPC classification number: B01J29/405 ,  B01J29/40 ,  C07C2/00 ,  B01J2229/26 ,  B01J2229/42 ,  B01J29/70 ,  C07C2523/08 ,  C07C2529/40 ,  C07C2529/70

Abstract: A catalyst useful in the aromatization of light paraffins and other hydrocarbons conversion reactions, formed by preparing an intimate mechanical mixture of a gallium-containing species, such as Ga.sub.2 O.sub.3, with a zeolite having a pore mouth comprising 10 oxygen atoms, such as ZSM-5, preferably followed by treatment with a reducing agent, such as hydrogen.

Abstract translation: 通过制备含镓物质如Ga 2 O 3的密实机械混合物与具有10个氧原子的孔口的沸石（例如ZSM-5）形成的可用于轻质链烷烃和其它烃转化反应芳构化的催化剂 优选用还原剂如氢气处理。

公开(公告)号：US5089459A

公开(公告)日：1992-02-18

申请号：US500248

申请日：1990-03-27

Applicant: Kimihiko Sato ,  Risuke Suzuki ,  Hiroshi Horiuchi

Inventor： Kimihiko Sato ,  Risuke Suzuki ,  Hiroshi Horiuchi

IPC: B01J29/40 ,  B01J29/44 ,  B01J29/65 ,  B01J29/70 ,  C07B61/00 ,  C07C4/06 ,  C07C5/27 ,  C07C15/08

CPC classification number: C07C4/06 ,  B01J29/40 ,  B01J29/405 ,  B01J29/44 ,  C07C5/2724 ,  B01J29/65 ,  B01J29/70 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/62 ,  C07C2529/40

Abstract: A catalyst composition consisting essentially of(A) a crystalline aluminosilicate zeolite having a silica/alumina mole ratio of at least 10, at least 50% of all its cation sites bing occupied by an alkali metal cation (component A), and(B) a refractory inorganic oxide having (b-1) platinum and (b-2) tin and/or indium supported thereon (component B). A process for cracking non-aromatic hydrocarbons in the presence of the catalyst composition, and a process for isomerizing C.sub.8 aromatic hydrocarbons, particularly xylenes, by applying the catalyst composition in combination with a conventional isomerization catalyst.

公开(公告)号：US5032561A

公开(公告)日：1991-07-16

申请号：US413721

申请日：1989-09-28

Applicant: Tamio Onodera, deceased ,  by Mieko Onodera, legal representative ,  by Shiyou Onodera, legal representative ,  by Toru Onodera, legal representative

Inventor： Tamio Onodera, deceased ,  by Mieko Onodera, legal representative ,  by Shiyou Onodera, legal representative ,  by Toru Onodera, legal representative

IPC: B01J23/62 ,  B01J29/068 ,  B01J29/40 ,  B01J29/44 ,  B01J35/00 ,  C07B61/00 ,  C07C1/00 ,  C07C4/06 ,  C07C5/27 ,  C07C15/08 ,  C07C67/00 ,  C10G35/095

CPC classification number: C10G35/095 ,  B01J29/068 ,  B01J29/44 ,  C07C4/06 ,  C07C5/2724 ,  B01J2229/26 ,  B01J2229/42 ,  B01J23/62 ,  B01J23/626 ,  B01J29/405 ,  B01J35/0006 ,  C07C2521/04 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/62 ,  C07C2527/11 ,  C07C2529/40

Abstract: A catalyst composition consisting essentially of (a) a crystalline aluminosilicate zeolite having a silica/alumina mole ratio of at least 10 (component A) in which at least 50% of its cationic sites are occupied by alkaline earth metal cations, (b) a refractory inorganic oxide having platinum and tin supported thereon (component B) and (c) indium (component C), the indium being supported on the zeolite in component A and/or the refractory inorganic oxide in component (B). A process for decomposing non-aromatic hydrocarbons in the presence of the catalyst composition, and a process for isomerizing C.sub.8 -aromatic hydrocarbon, particularly xylenes, in the presence of the catalyst composition.

公开(公告)号：US5012028A

公开(公告)日：1991-04-30

申请号：US884474

申请日：1986-07-11

Applicant: Victor Gupta ,  Christopher L. Bodolus ,  Christos Paparizos ,  Wilfrid G. Shaw

Inventor： Victor Gupta ,  Christopher L. Bodolus ,  Christos Paparizos ,  Wilfrid G. Shaw

IPC: B01J8/02 ,  B01J12/00 ,  B01J23/14 ,  C07C2/00 ,  C07C2/84

CPC classification number: B01J8/0242 ,  B01J12/005 ,  B01J23/14 ,  C07C2/00 ,  C07C2/84 ,  B01J2208/00212 ,  B01J2208/00504 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2521/16 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/18 ,  C07C2523/20 ,  C07C2523/30 ,  C07C2523/34 ,  C07C2523/50 ,  C07C2527/18 ,  C07C2527/224 ,  Y02P20/52 ,  Y10S585/91

Abstract: A process for converting a gaseous reactant comprising methane or natural gas to higher molecular weight hydrocarbon products is disclosed which comprises: (1) contacting said gaseous reactant with an oxidative coupling catalyst at a reaction temperature in the range of about 500.degree. C. to about 1100.degree. C. for an effective period of time to form an intermediate product comprising ethane, ethylene or a mixture thereof; and (2) pyrolyzing said intermediate product at a temperature in the range of about 900.degree. C. to about 1500.degree. C. for an effective period of time to form said higher molecular weight hydrocarbon products.

Abstract translation: 公开了一种将包含甲烷或天然气的气态反应物转化为较高分子量烃产物的方法，其包括：（1）将反应物与氧化偶联催化剂在约500℃至约 1100℃，有效的时间以形成包含乙烷，乙烯或其混合物的中间产物; 和（2）在约900℃至约1500℃的温度下将所述中间产物热解有效的一段时间以形成所述较高分子量的烃产物。