公开(公告)号：US06794037B2

公开(公告)日：2004-09-21

申请号：US10318110

申请日：2002-12-13

申请人： Curtis J. Zimmermann ,  Steven A. Jones

发明人： Curtis J. Zimmermann ,  Steven A. Jones

IPC分类号： B32B516

CPC分类号： C09C1/0066 ,  C01P2002/02 ,  C01P2004/84 ,  C09C1/0015 ,  C09C1/0078 ,  C09C2200/1004 ,  C09C2200/1008 ,  C09C2200/102 ,  C09C2200/1025 ,  C09C2200/1087 ,  C09C2200/1091 ,  C09C2220/103 ,  C09C2220/20 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2996 ,  Y10T428/2998

摘要： A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective silver layer which acts as a reflector to light directed thereon, a spacer layer which is selectively transparent to light directed thereon, and an iron oxide layer on the spacer layer.

摘要翻译： 彩色效果材料被描述为由多个封装的衬底血小板组成，其中每个血小板被用作反射器的高度反射的银层封装，用于指向其上的光，对于其上指向的光选择性透明的间隔层，以及 间隔层上的氧化铁层。

公开(公告)号：US20040112252A1

公开(公告)日：2004-06-17

申请号：US10318058

申请日：2002-12-13

发明人： Curtis J. Zimmermann ,  James D. Christie ,  Vivian K. Doxey ,  Daniel Stevenson Fuller

IPC分类号： C09C001/62 ,  C04B014/00 ,  C04B018/04 ,  C04B002/00

CPC分类号： C09C1/0078 ,  B82Y30/00 ,  C01P2004/64 ,  C01P2006/12 ,  C09C1/0015 ,  C09C1/0066 ,  C09C2200/1004 ,  C09C2200/102 ,  C09C2200/1087 ,  C09C2220/103

摘要： A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective layer which acts as a reflector to light directed thereon and a spacer pigment layer which is selectively transparent to light directed thereon.

摘要翻译： 描述了一种颜色效应材料，其由多个封装的基片血小板组成，其中每个血小板被用作反射器的高反射层进行封装，以及指向其上的光的选择性透明的间隔颜料层。

公开(公告)号：US06710103B2

公开(公告)日：2004-03-23

申请号：US09964713

申请日：2001-09-27

申请人： William C. Norris ,  Josef Rademacher

发明人： William C. Norris ,  Josef Rademacher

IPC分类号： C08J300

CPC分类号： C09C1/0066 ,  C01P2004/62 ,  C01P2004/84 ,  C09C1/0015 ,  C09C2200/1004 ,  C09C2200/102 ,  C09C2200/1054 ,  C09C2200/1058 ,  C09C2200/302 ,  C09C2200/303 ,  C09C2200/306 ,  C09D5/032 ,  C09D5/36

摘要： A powder-based coating composition for coating a substrate, having a first color effect, with a film layer is disclosed. Application of the film layer to the substrate produces a second color effect different from the first color effect. The composition includes a powder-based binder and a color effect-providing pigment. The powder-based binder is the reaction product of a resin, having a functional group, and a cross-linking agent reactive with the functional group. The color effect-providing pigment includes a pigment substrate and an inorganic coating. The pigment substrate has first and second substantially parallel and planar surfaces, and the inorganic coating is disposed on the first and second surfaces. The inorganic coating has an index of refraction of 1.8 or less. To produce the second color effect, the inorganic coating and the pigment substrate of the color effect-providing pigment interact with the first color effect of the substrate upon application of the film layer to the substrate.

摘要翻译： 公开了一种用于涂覆具有第一颜色效果的基材的薄膜层的粉末涂料组合物。 将薄膜层应用于基板产生与第一颜色效果不同的第二颜色效果。 组合物包括粉末状粘合剂和着色效果颜料。 粉末状粘合剂是具有官能团的树脂和与官能团反应的交联剂的反应产物。 着色效果颜料包括颜料基材和无机涂层。 颜料基材具有第一和第二基本上平行和平坦的表面，并且无机涂层设置在第一表面和第二表面上。 无机涂层的折射率为1.8以下。 为了产生第二颜色效果，在将膜层施加到基板上时，着色效果颜料的无机涂层和颜料基底与基板的第一颜色效应相互作用。

公开(公告)号：US20030203222A1

公开(公告)日：2003-10-30

申请号：US10413091

申请日：2003-04-14

申请人： Flex Products, Inc.

发明人： Roger W. Phillips ,  Charlotte R. LeGallee ,  Paul T. Kohlmann ,  Vladimir Raksha ,  Alberto Argoitia

IPC分类号： B32B009/00

CPC分类号： G02B5/285 ,  C01P2006/60 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C01P2006/65 ,  C01P2006/66 ,  C09C1/0015 ,  C09C1/0021 ,  C09C1/0066 ,  C09C1/0078 ,  C09C2200/1054 ,  C09C2200/1058 ,  C09C2200/301 ,  C09C2220/106 ,  C09C2220/20 ,  C09D5/36 ,  Y10T428/12028 ,  Y10T428/12056 ,  Y10T428/12181 ,  Y10T428/1259 ,  Y10T428/12618 ,  Y10T428/24942 ,  Y10T428/265 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2996

摘要： Interference pigment flakes and foils are provided which have color shifting properties. The pigment flakes can have a symmetrical coating structure on opposing sides of a reflector layer, can have an asymmetrical coating structure with all of the layers on one side of the reflector layer, or can be formed with encapsulating coatings around a core reflector layer. The coating structure of the flakes and foils includes a reflector layer, a dielectric layer on the reflector layer, and a titanium-containing absorber layer on the dielectric layer. The pigment flakes and foils exhibit a discrete color shift so as to have a first color at a first angle of incident light or viewing and a second color different from the first color at a second angle of incident light or viewing. The pigment flakes can be interspersed into liquid media such as paints or inks to produce colorant compositions for subsequent application to objects or papers. The foils can be laminated to various objects or can be formed on a carrier substrate.

公开(公告)号：US20030165637A1

公开(公告)日：2003-09-04

申请号：US10328509

申请日：2002-12-23

申请人： Flex Products, Inc.

发明人： Roger W. Phillips ,  Charlotte R. LeGallee ,  Charles T. Markantes ,  Paul G. Coombs ,  Matthew R. Witzman

IPC分类号： B05D005/12

CPC分类号： B32B5/16 ,  B05D3/067 ,  B05D3/20 ,  B05D5/061 ,  B41M3/00 ,  B41M3/008 ,  B41M3/06 ,  B41M3/14 ,  B41M3/148 ,  B42D25/00 ,  B42D25/29 ,  B42D25/369 ,  B42D25/42 ,  B42D25/455 ,  B42D25/47 ,  B42D2033/16 ,  B42D2033/20 ,  B44F1/08 ,  C01P2004/54 ,  C01P2006/42 ,  C08J7/04 ,  C09C1/0015 ,  C09C1/0024 ,  C09C1/0033 ,  C09C1/0039 ,  C09C1/0045 ,  C09C1/0051 ,  C09C1/006 ,  C09C1/0066 ,  C09C1/0072 ,  C09C1/0078 ,  C09C2200/1004 ,  C09C2200/1008 ,  C09C2200/1054 ,  C09C2200/24 ,  C09C2200/301 ,  C09C2200/304 ,  D06P1/004 ,  D06P1/0076 ,  D06P1/44 ,  D06Q1/00 ,  Y10T428/24835 ,  Y10T428/29 ,  Y10T428/2982 ,  Y10T428/2989 ,  Y10T428/2991 ,  Y10T428/31504

摘要： Methods and devices for producing images on coated articles are provided. The methods generally comprise applying a layer of magnetizable pigment coating in liquid form on a substrate, with the magnetizable pigment coating containing a plurality of magnetic non-spherical particles or flakes. A magnetic field is then applied to selected regions of the pigment coating while the coating is in liquid form, with the magnetic field altering the orientation of selected magnetic particles or flakes. Finally, the pigment coating is solidified, affixing the reoriented particles or flakes in a non-parallel position to the surface of the pigment coating to produce an image such as a three dimensional-like image on the surface of the coating. The pigment coating can contain various interference or non-interference magnetic particles or flakes, such as magnetic color shifting pigments.

公开(公告)号：US20020041047A1

公开(公告)日：2002-04-11

申请号：US09849512

申请日：2001-05-04

发明人： Karl Josephy ,  James P. Rettker ,  Howard H. Enlow

IPC分类号： B29C069/00 ,  C23C016/00

CPC分类号： B22F1/0055 ,  B22F2999/00 ,  B82Y30/00 ,  C01P2004/03 ,  C01P2004/20 ,  C01P2004/51 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2004/64 ,  C01P2004/80 ,  C01P2004/86 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/60 ,  C01P2006/90 ,  C09C1/0015 ,  C09C1/0018 ,  C09C1/0021 ,  C09C1/0066 ,  C09C1/62 ,  C09C1/64 ,  C09C2200/1004 ,  C09C2200/1037 ,  C09C2200/1054 ,  C09C2200/1087 ,  C09C2200/301 ,  C09C2200/304 ,  C09C2200/401 ,  C09C2200/405 ,  C09C2220/20 ,  C09D5/36 ,  C09D7/70 ,  C23C14/0005 ,  C23C14/024 ,  B22F9/12 ,  C23C14/00

摘要： A process for making functional or decorative flakes or platelets economically and at high production rates comprises applying a multi-layer sandwich of vapor deposited metal and release coats in alternating layers to a rotating chilled drum or suitable carrier medium contained in a vapor deposition chamber. The alternating metallized layers are applied by vapor deposition and the intervening release layers are preferably solvent soluble thermoplastic polymeric materials applied by vapor deposition sources contained in the vapor deposition chamber. The multi-layer sandwich built up in the vacuum chamber is removed from the drum or carrier and treated with a suitable organic solvent to dissolve the release coating from the metal in a stripping process that leaves the metal flakes essentially release coat free. The solvent and dissolved release material are then removed by centrifuging to produce a cake of concentrated flakes which can be air milled and let down in a preferred vehicle and further sized and homogenized for final use in inks, paints or coatings. In one embodiment the finished flakes comprise single-layer thin metal or metal alloy flakes or flakes of inorganic materials, and in another embodiment flakes are coated on both sides with protective polymeric coatings that were applied from suitable vacuum deposition sources or the like contained in the vapor deposition chamber.

摘要翻译： 经济地和以高生产率制造功能性或装饰性薄片或片剂的方法包括将蒸镀金属的多层三明治和交替层的脱模涂层施加到旋转的冷却滚筒或包含在气相沉积室中的合适的载体介质。 交替的金属化层通过气相沉积施加，并且中间释放层优选地是通过包含在气相沉积室中的气相沉积源施加的溶剂可溶性热塑性聚合物材料。 建立在真空室中的多层夹层从滚筒或载体中移出，并用合适的有机溶剂进行处理，以便在剥离过程中从金属中溶解脱模涂层，使脱模膜基本上脱离外壳。 然后通过离心除去溶剂和溶解的释放材料以产生浓缩的薄片饼，其可以在优选的载体中进行空气研磨和放下，并进一步定型并均化以最终用于油墨，油漆或涂料。 在一个实施方案中，成品薄片包括无机材料的单层薄金属或金属合金薄片或薄片，并且在另一个实施方案中，薄片在两侧涂覆有保护性聚合物涂层，所述保护性聚合物涂层由适当的真空沉积源或类似物 蒸镀室。

公开(公告)号：US20130213260A1

公开(公告)日：2013-08-22

申请号：US13881820

申请日：2011-10-12

申请人： Koshiro Kunii

发明人： Koshiro Kunii

IPC分类号： C08K5/5425 ,  C08K5/5435 ,  C08K5/54 ,  C08K3/22

CPC分类号： C08K5/5425 ,  C01P2004/30 ,  C01P2004/84 ,  C08K3/22 ,  C08K5/5403 ,  C08K5/5435 ,  C09C1/0021 ,  C09C1/0024 ,  C09C1/0039 ,  C09C1/0051 ,  C09C1/0066 ,  C09C2200/1004 ,  C09C2200/102 ,  C09C2200/301 ,  C09C2200/401 ,  C09C2200/407 ,  C09C2200/409 ,  C09D5/36

摘要： The present invention relates to effect pigments based on substrates having an outer coating comprising metal oxide, hydroxide and/or oxide hydrate and at least one organic coupling agent.

摘要翻译： 本发明涉及基于具有包含金属氧化物，氢氧化物和/或氧化物水合物和至少一种有机偶联剂的外涂层的底物的效果颜料。

公开(公告)号：US20110031640A1

公开(公告)日：2011-02-10

申请号：US12911148

申请日：2010-10-25

申请人： Karl JOSEPHY ,  James P. RETTKER ,  Howard H. ENLOW

发明人： Karl JOSEPHY ,  James P. RETTKER ,  Howard H. ENLOW

IPC分类号： B22F9/12 ,  C23C14/00 ,  B29C69/00 ,  B82Y30/00 ,  B82Y40/00

CPC分类号： B22F1/0055 ,  B22F2999/00 ,  B82Y30/00 ,  C01P2004/03 ,  C01P2004/20 ,  C01P2004/51 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2004/64 ,  C01P2004/80 ,  C01P2004/86 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/60 ,  C01P2006/90 ,  C09C1/0015 ,  C09C1/0018 ,  C09C1/0021 ,  C09C1/0066 ,  C09C1/62 ,  C09C1/64 ,  C09C2200/1004 ,  C09C2200/1037 ,  C09C2200/1054 ,  C09C2200/1087 ,  C09C2200/301 ,  C09C2200/304 ,  C09C2200/401 ,  C09C2200/405 ,  C09C2220/20 ,  C09D5/36 ,  C09D7/70 ,  C23C14/0005 ,  C23C14/024 ,  B22F9/12 ,  C23C14/00

摘要： A process for making functional or decorative flakes or platelets economically and at high production rates comprises applying a multi-layer sandwich of vapor deposited metal and release coats in alternating layers to a rotating chilled drum or suitable carrier medium contained in a vapor deposition chamber. The alternating metallized layers are applied by vapor deposition and the intervening release layers are preferably solvent soluble thermoplastic polymeric materials applied by vapor deposition sources contained in the vapor deposition chamber. The multi-layer sandwich built up in the vacuum chamber is removed from the drum or carrier and treated with a suitable organic solvent to dissolve the release coating from the metal in a stripping process that leaves the metal flakes essentially release coat free. The solvent and dissolved release material are then removed by centrifuging to produce a cake of concentrated flakes which can be air milled and let down in a preferred vehicle and further sized and homogenized for final use in inks, paints or coatings. In one embodiment the finished flakes comprise single-layer thin metal or metal alloy flakes or flakes of inorganic materials, and in another embodiment flakes are coated on both sides with protective polymeric coatings that were applied from suitable vacuum deposition sources or the like contained in the vapor deposition chamber.

公开(公告)号：US07820088B2

公开(公告)日：2010-10-26

申请号：US10758985

申请日：2004-01-16

申请人： Karl Josephy ,  James P. Rettker ,  Howard H. Enlow

发明人： Karl Josephy ,  James P. Rettker ,  Howard H. Enlow

IPC分类号： B29C69/00 ,  B29D11/00

CPC分类号： B22F1/0055 ,  B22F2999/00 ,  B82Y30/00 ,  C01P2004/03 ,  C01P2004/20 ,  C01P2004/51 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2004/64 ,  C01P2004/80 ,  C01P2004/86 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/60 ,  C01P2006/90 ,  C09C1/0015 ,  C09C1/0018 ,  C09C1/0021 ,  C09C1/0066 ,  C09C1/62 ,  C09C1/64 ,  C09C2200/1004 ,  C09C2200/1037 ,  C09C2200/1054 ,  C09C2200/1087 ,  C09C2200/301 ,  C09C2200/304 ,  C09C2200/401 ,  C09C2200/405 ,  C09C2220/20 ,  C09D5/36 ,  C09D7/70 ,  C23C14/0005 ,  C23C14/024 ,  B22F9/12 ,  C23C14/00

摘要： A process for making functional or decorative flakes or platelets economically and at high production rates comprises applying a multi-layer sandwich of vapor deposited metal and release coats in alternating layers to a rotating chilled drum or suitable carrier medium contained in a vapor deposition chamber. The alternating metallized layers are applied by vapor deposition and the intervening release layers are preferably solvent soluble thermoplastic polymeric materials applied by vapor deposition sources contained in the vapor deposition chamber. The multi-layer sandwich built up in the vacuum chamber is removed from the drum or carrier and treated with a suitable organic solvent to dissolve the release coating from the metal in a stripping process that leaves the metal flakes essentially release coat free. The solvent and dissolved release material are then removed by centrifuging to produce a cake of concentrated flakes which can be air milled and let down in a preferred vehicle and further sized and homogenized for final use in inks, paints or coatings. In one embodiment the finished flakes comprise single-layer thin metal or metal alloy flakes or flakes of inorganic materials, and in another embodiment flakes are coated on both sides with protective polymeric coatings that were applied from suitable vacuum deposition sources or the like contained in the vapor deposition chamber.

摘要翻译： 经济地和以高生产率制造功能性或装饰性薄片或片剂的方法包括将蒸镀金属的多层三明治和交替层的脱模涂层施加到旋转的冷却滚筒或包含在气相沉积室中的合适的载体介质。 交替的金属化层通过气相沉积施加，并且中间释放层优选地是通过包含在气相沉积室中的气相沉积源施加的溶剂可溶性热塑性聚合物材料。 建立在真空室中的多层夹层从滚筒或载体中移出，并用合适的有机溶剂进行处理，以便在剥离过程中从金属中溶解脱模涂层，使脱模膜基本上脱离外壳。 然后通过离心除去溶剂和溶解的释放材料以产生浓缩的薄片饼，其可以在优选的载体中进行空气研磨和放下，并进一步定型并均化以最终用于油墨，油漆或涂料。 在一个实施方案中，成品薄片包括无机材料的单层薄金属或金属合金薄片或薄片，在另一个实施方案中，薄片在两侧涂覆有保护性聚合物涂层，其由包含在 蒸镀室。

公开(公告)号：US20090185992A1

公开(公告)日：2009-07-23

申请号：US12016341

申请日：2008-01-18

申请人： Christelle Conan ,  Aaron M. Hollman ,  Philippe Schottland ,  Stephane Nicolas ,  Marguerite Debacker ,  Aurelie Antonowicz ,  Kenneth A. Fields, II

发明人： Christelle Conan ,  Aaron M. Hollman ,  Philippe Schottland ,  Stephane Nicolas ,  Marguerite Debacker ,  Aurelie Antonowicz ,  Kenneth A. Fields, II

IPC分类号： C09C1/00 ,  C09D11/00 ,  C09D1/00 ,  A61K8/19 ,  A61Q1/02 ,  A61Q1/06 ,  A61Q3/02 ,  A61Q5/06 ,  C11D3/14

CPC分类号： C09C1/0015 ,  A61K8/11 ,  A61K2800/412 ,  A61K2800/436 ,  A61K2800/47 ,  A61Q1/02 ,  A61Q1/04 ,  A61Q1/06 ,  A61Q1/08 ,  A61Q1/10 ,  A61Q1/12 ,  A61Q3/02 ,  A61Q5/00 ,  C01P2004/20 ,  C01P2004/61 ,  C01P2006/42 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C01P2006/65 ,  C01P2006/66 ,  C09C1/0021 ,  C09C1/0039 ,  C09C1/0066 ,  C09C1/24 ,  C09C2200/1004 ,  C09C2200/1016 ,  C09C2200/102 ,  C09C2200/1033 ,  C09C2200/1087 ,  C09C2200/301 ,  C09C2200/302 ,  C09C2200/303 ,  C09C2200/308 ,  C09C2220/10 ,  C09C2220/106 ,  C09D5/36

摘要： A pearlescent pigment, wherein the pigment is an inorganic material and the color of a homogeneous coating of the pigment, measured over a black background has a CIELAB hue angle, hab, from about 40 to about 320 degrees, wherein L* is from about 35 to about 80, and the chroma value is less than 5. A substrate is coated with iron oxide by oxidizing an iron salt to form a pigment. The pigment may be made by a process of coating iron oxide on a substrate by oxidizing an iron salt. During the coating of the iron oxide, the pH of the mixture is increased. The coating formed has a Fe(III)/Fe(II) ratio of greater than 2. The pigments may be used in a variety of applications including coating, ink, plastic, and cosmetic compositions.

摘要翻译： 一种珠光颜料，其中所述颜料是无机材料，并且在黑色背景上测量的颜料的均匀涂层的颜色具有约40至约320度的CIELAB色调角hab，其中L *为约35 至约80，色度值小于5.通过氧化铁盐形成颜料，用氧化铁涂覆基材。 颜料可以通过氧化铁盐在基材上涂覆氧化铁的方法制成。 在氧化铁的涂覆期间，混合物的pH增加。 形成的涂层具有大于2的Fe（III）/ Fe（II）比。该颜料可用于各种应用，包括涂料，油墨，塑料和化妆品组合物。