公开(公告)号：US08877962B2

公开(公告)日：2014-11-04

申请号：US14304382

申请日：2014-06-13

申请人： Nippon Shokubai Co, Ltd

发明人： Masato Nakano ,  Akihiko Kanzaki ,  Takahiro Tsumori

IPC分类号： C07C309/00 ,  C07C309/20

CPC分类号： C07C309/20 ,  C07C303/02 ,  C07C309/09 ,  C08F216/1466

摘要： The present invention provides a method for efficiently producing a sulfonic acid group-containing ether compound having a high purity and a good polymerizability while preventing production of a byproduct, and provides a sulfonic acid group-containing ether compound containing fewer impurities and having a good radical (co)polymerizability.The present invention provides a method of producing a sulfonic acid group-containing ether compound by reacting a sulfurous acid compound with a compound represented by the formula (1): wherein R1 represents a single bond, a CH2 group, or a CH2CH2 group, and R2 represents H, or a CH3 group, the method comprising the steps of: adjusting pH of a reaction system to 5.5 or greater with use of an alkaline substance; and adding the compound represented by the formula (1) to a reaction vessel containing the sulfurous acid compound.

公开(公告)号：US20110305971A1

公开(公告)日：2011-12-15

申请号：US13214273

申请日：2011-08-22

申请人： Atsushi WATAKABE ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

发明人： Atsushi WATAKABE ,  Takeshi Eriguchi ,  Toshihiro Tanuma ,  Yasuhiro Kunisa

IPC分类号： H01M8/10

CPC分类号： H01M8/1067 ,  B01D71/32 ,  B01D71/44 ,  B01D71/72 ,  B01D71/76 ,  C08F216/1466 ,  C08F228/02 ,  C08J5/2268 ,  C08J2327/18 ,  C08J2365/00 ,  C08J2387/00 ,  C08L65/00 ,  H01B1/122 ,  H01M6/181 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M10/0525 ,  H01M10/0565

摘要： A solid polymer electrolyte material made of a copolymer comprising a repeating unit based on a fluoromonomer A which gives a polymer having an alicyclic structure in its main chain by radical polymerization, and a repeating unit based on a fluoromonomer B of the following formula (1): CF2═CF(Rf)jSO2X   (1) wherein j is 0 or 1, X is a fluorine atom, a chlorine atom or OM {wherein M is a hydrogen atom, an alkali metal atom or a group of NR1R2R3R4 (wherein each of R1, R2, R3 and R4 which may be the same or different, is a hydrogen atom or a monovalent organic group)}, and Rf is a C1-20 polyfluoroalkylene group having a straight chain or branched structure which may contain ether oxygen atoms.

摘要翻译： 一种由共聚物制成的固体聚合物电解质材料，该共聚物包含基于通过自由基聚合在主链中具有脂环结构的聚合物的基于含氟单体A的重复单元和基于下式（1）的含氟单体B的重复单元， ：CF2 = CF（Rf）jSO2X（1）其中j为0或1，X为氟原子，氯原子或OM（其中M为氢原子，碱金属原子或NR1R2R3R4基团 R 1，R 2，R 3和R 4可以相同或不同，为氢原子或一价有机基团}}，R f为可含有醚氧原子的具有直链或支链结构的C1-20多氟亚烷基。

公开(公告)号：US20110172459A1

公开(公告)日：2011-07-14

申请号：US13063563

申请日：2009-09-14

申请人： Masato Nakano ,  Akihiko Kanzaki ,  Takahiro Tsumori

发明人： Masato Nakano ,  Akihiko Kanzaki ,  Takahiro Tsumori

IPC分类号： C07C309/20 ,  C07C303/20

CPC分类号： C07C309/20 ,  C07C303/02 ,  C07C309/09 ,  C08F216/1466

摘要： The present invention provides a method for efficiently producing a sulfonic acid group-containing ether compound having a high purity and a good polymerizability while preventing production of a byproduct, and provides a sulfonic acid group-containing ether compound containing fewer impurities and having a good radical (co)polymerizability.The present invention provides a method of producing a sulfonic acid group-containing ether compound by reacting a sulfurous acid compound with a compound represented by the formula (1): wherein R1 represents a single bond, a CH2 group, or a CH2CH2 group, and R2 represents H, or a CH3 group, the method comprising the steps of: adjusting pH of a reaction system to 5.5 or greater with use of an alkaline substance; and adding the compound represented by the formula (1) to a reaction vessel containing the sulfurous acid compound.

摘要翻译： 本发明提供了一种有效地制备具有高纯度和良好的聚合性同时防止副产物生成的含磺酸基的醚化合物的方法，并且提供了含少量杂质和具有良好基团的含磺酸基的醚化合物 （共）聚合性。 本发明提供一种通过使亚硫酸化合物与式（1）表示的化合物反应制备含磺酸基醚化合物的方法：其中R1表示单键，CH2基或CH2CH2基，和 R 2表示H或CH 3基团，该方法包括以下步骤：使用碱性物质将反应体系的pH调节至5.5以上; 并将由式（1）表示的化合物加入到含有亚硫酸化合物的反应容器中。

公开(公告)号：US20100330317A1

公开(公告)日：2010-12-30

申请号：US12878444

申请日：2010-09-09

申请人： Bruno Michel AMEDURI ,  Michel Armand ,  Mario Boucher ,  Abdellatif Manseri

发明人： Bruno Michel AMEDURI ,  Michel Armand ,  Mario Boucher ,  Abdellatif Manseri

IPC分类号： C08F214/20 ,  B32B1/08 ,  C08F4/04 ,  C08F4/34

CPC分类号： C08F214/28 ,  C08F216/1466 ,  Y10T428/139 ,  Y10T428/1397 ,  Y10T428/215

摘要： The present invention describes the synthesis of new fluorinated elastomers with very low glass transition temperatures (Tg), a good resistance to bases, gasoline and other carburants and good workability properties, these elastomers contain hexafluoropropene (HFP), perfluoro(4-methyl-3,6-dioxaoct-7-ene) sulfonyl fluoride (PFSO2F), vinylidene fluoride (VDF) and/or at least one fluorinated alkene and/or one vinyl perfluorinated ether. In a precise case, they are prepared by radical polymerisation of HFP and PFSO2F or by radical terpolymerisation HFP, PFSO2F and VDF in the presence of different organic initiator, such as peroxides, peresters or diazo compounds.

摘要翻译： 本发明描述了具有非常低的玻璃化转变温度（Tg），良好的耐碱性，汽油和其它渗碳剂的良好的加工性能的新的氟化弹性体的合成，这些弹性体含有六氟丙烯（HFP），全氟（4-甲基-3 ，6-二氧杂-7-烯）磺酰氟（PFSO2F），偏二氟乙烯（VDF）和/或至少一种氟化烯烃和/或一种乙烯基全氟化醚。 在精确的情况下，它们通过HFP和PFSO2F的自由基聚合或通过在不同有机引发剂如过氧化物，过酸酯或重氮化合物的存在下的自由基三聚HFP，PFSO2F和VDF来制备。

公开(公告)号：US07522333B2

公开(公告)日：2009-04-21

申请号：US11379188

申请日：2006-04-18

申请人： Hitoshi Yamamoto ,  Takeo Kawase ,  Toshiyuki Miyabayashi

发明人： Hitoshi Yamamoto ,  Takeo Kawase ,  Toshiyuki Miyabayashi

IPC分类号： G02B26/00 ,  G03G13/00 ,  G02F1/133

CPC分类号： G02F1/167 ,  B01J13/16 ,  B01J13/18 ,  C08F216/1466 ,  C08F290/06 ,  C08F290/062

摘要： A method for producing electrophoretic particles includes dispersing particles having a charge on the surfaces thereof in an polar dispersion medium; adding a first polymerizable surfactant including a first polar group having a polarity opposite to the charge of the surfaces of the particles, a hydrophobic group, and a polymerizable group to the polar dispersion medium and mixing the liquid; adding a second polymerizable surfactant including a second polar group, a hydrophobic group, and a polymerizable group to the polar dispersion medium and emulsifying the mixture; and adding a polymerization initiator to induce polymerization reaction, thereby preparing electrophoretic particles in which the particles are coated with an organic polymer. In the method, the charge polarity and the amount of charge of the electrophoretic particles are controlled by setting the polarity of the second polar group included in the second polymerizable surfactant, and at least one condition of the number of the second polar groups in second polymerizable surfactant, the valence of the second polymerizable surfactant, and the molar amount of the second polymerizable surfactant added.

摘要翻译： 一种电泳粒子的制造方法，其特征在于，在极性分散介质中分散有表面电荷的粒子， 向所述极性分散介质中加入第一可聚合表面活性剂，所述第一可聚合表面活性剂包含与所述颗粒表面的电荷极性相反的第一极性基团，疏水基团和可聚合基团，并混合所述液体; 向所述极性分散介质中加入包含第二极性基团，疏水基团和聚合性基团的第二可聚合表面活性剂并使所述混合物乳化; 并加入聚合引发剂以诱导聚合反应，从而制备其中颗粒被有机聚合物涂覆的电泳颗粒。 在该方法中，通过设定第二可聚表面活性剂中包括的第二极性基团的极性和第二可聚合的表面活性剂中的第二极性基团的数量的至少一个条件来控制电泳粒子的电荷极性和电荷量 表面活性剂，第二可聚合表面活性剂的化合价和第二可聚合表面活性剂的摩尔量。

公开(公告)号：US06417379B1

公开(公告)日：2002-07-09

申请号：US10021159

申请日：2001-12-13

申请人： Ming-Hong Hung

发明人： Ming-Hong Hung

IPC分类号： C07C24700

CPC分类号： C08F228/02 ,  C07C311/49 ,  C08F214/184 ,  C08F214/262 ,  C08F216/1466

摘要： Fluorinated olefins and fluorinated vinyl ethers, each having sulfonyl azide groups, are useful monomers in preparing fluoropolymers having functional side groups. Such functional side groups are useful in curing the fluoropolymers and also for enhancing the adhesion of the fluoropolymers to other substrates.

摘要翻译： 各自具有磺酰基叠氮基的氟化烯烃和氟化乙烯基醚是制备具有官能侧基的含氟聚合物的有用单体。 这样的官能侧基可用于固化含氟聚合物，也可用于增强含氟聚合物与其它基材的粘合性。

公开(公告)号：US4915845A

公开(公告)日：1990-04-10

申请号：US324509

申请日：1989-03-16

申请人： John C. Leighton ,  Michael J. Sanders

发明人： John C. Leighton ,  Michael J. Sanders

IPC分类号： B01F17/00 ,  C02F5/10 ,  C02F5/12 ,  C04B24/20 ,  C08F216/14 ,  C09D17/00 ,  C09K8/24

CPC分类号： C08F216/1466 ,  B01F17/0057 ,  C02F5/10 ,  C02F5/12 ,  C04B24/20 ,  C09D17/004 ,  C09K8/24

摘要： Water soluble polymers comprising at least one mole percent of a recurring monomer unit represented by the chemical structure ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are independently hydrogen or C.sub.1 -C.sub.6 alkyl; and X is hydrogen, an alkali or alkaline earth metal or ammonium are disclosed.

摘要翻译： 包含至少1摩尔％的由化学结构表示的重复单体单元的水溶性聚合物，其中R 1，R 2，R 3和R 4独立地为氢或C 1 -C 6烷基; X是氢，碱金属或碱土金属或铵。

公开(公告)号：US4734474A

公开(公告)日：1988-03-29

申请号：US831509

申请日：1986-02-21

申请人： Masato Hamada ,  Tetsuro Ohta

发明人： Masato Hamada ,  Tetsuro Ohta

IPC分类号： C08F16/00 ,  C08F14/18 ,  C08F16/14 ,  C08F214/18 ,  C08F216/14 ,  C08F228/02

CPC分类号： C08F216/1466

摘要： A novel fluorine-containing crosslinkable copolymer comprising fluorine-containing monomer units each having a sulfonyl chloride group and monomer units of at least one ethylenically unsaturated compound is disclosed. The present fluorine-containing crosslinkable copolymer has a specific range of a sulfonyl chloride group content and can be easily crosslinked to give a fluorine-containing elastomer which is excellent in heat resistance and chemicals resistance.

摘要翻译： 公开了一种包含各自具有磺酰氯基团的含氟单体单元和至少一种烯键式不饱和化合物的单体单元的新型含氟可交联共聚物。 本发明的含氟交联性共聚物具有磺酰氯基团含量的特定范围，并且可以容易地交联，得到耐热性和耐化学性优异的含氟弹性体。

公开(公告)号：US20180265384A1

公开(公告)日：2018-09-20

申请号：US15762782

申请日：2016-08-18

申请人： Nippon Shokubai Co., Ltd.

发明人： Shigeru Yamaguchi ,  Yui Nishida

IPC分类号： C02F5/10 ,  C09K8/528 ,  C08L33/02 ,  C08F220/06 ,  C08L33/26

CPC分类号： C02F5/10 ,  C02F2101/101 ,  C02F2103/08 ,  C02F2103/10 ,  C08F216/14 ,  C08F220/06 ,  C08L33/02 ,  C08L33/26 ,  C08L2201/54 ,  C09K8/528 ,  C08F216/1466

摘要： Provided are a barium-sulfate scale inhibitor and a barium-sulfate scale inhibitor composition each of which can express a high barium-sulfate scale-inhibiting ability. Also provided is a method of inhibiting a barium-sulfate scale that can express a high barium-sulfate scale-inhibiting ability. The barium-sulfate scale inhibitor of the present invention includes a sulfonic acid group-containing copolymer obtained by polymerizing a monomer composition containing a carboxyl group-containing monomer and a sulfonic acid group-containing monomer, in which when the barium-sulfate scale inhibitor is added at a solid content concentration of 1 wt % to high-salt-concentration water having a metal salt concentration of 10 wt % or more, the sulfonic acid group-containing copolymer is free from precipitating.

公开(公告)号：US09464176B2

公开(公告)日：2016-10-11

申请号：US14657844

申请日：2015-03-13

申请人： Asahi Glass Company, Limited

发明人： Susumu Saito ,  Kaori Abe ,  Tetsuji Shimohira

IPC分类号： C08J5/22 ,  B01J47/12 ,  C08F214/18 ,  C25B13/08 ,  C08F2/00 ,  C08L27/12 ,  C08F6/00 ,  C08F216/14

CPC分类号： C08J5/225 ,  B01J47/12 ,  C08F2/00 ,  C08F6/003 ,  C08F6/008 ,  C08F214/18 ,  C08F216/1408 ,  C08F216/1466 ,  C08F2216/1475 ,  C08J5/22 ,  C08J2329/10 ,  C25B13/04 ,  C25B13/08 ,  C08L27/12

摘要： To provide a process by which from a mixture containing a fluorinated copolymer, an unreacted monomer and a polymerization medium, the unreacted monomer and the polymerization medium can efficiently be recovered, and a lower polymer contained in the obtainable fluorinated copolymer can readily be reduced. A process for producing a fluorinated copolymer comprising (I) a step of polymerizing a fluorinated monomer having a carboxylic acid functional group or a sulfonic acid fanctional group and a fluorinated olefin in a polymerization medium to obtain a mixture containing a fluorinated copolymer, the unreacted monomer and the polymerization medium, (II) a step of continuously or intermittently transferring the mixture to an evaporation container equipped with a stirring machine and heating the mixture in the evaporation container with stirring to evaporate and recover the unreacted monomer and the polymerization medium and to obtain the fluorinated copolymer, and (III) a step of washing the fluorinated copolymer with a washing medium.

摘要翻译： 为了提供从包含含氟共聚物，未反应单体和聚合介质的混合物中可以有效地回收未反应单体和聚合介质的方法，并且可以容易地降低所得含氟共聚物中所含的低聚物。 一种含氟共聚物的制造方法，其特征在于，含有（I）在聚合介质中聚合具有羧酸官能团或磺酸官能团的氟化单体和氟化烯烃的步骤，得到含氟共聚物的混合物，未反应单体 和聚合介质，（II）将混合物连续或间歇地转移到装有搅拌机的蒸发容器中并在搅拌下加热蒸发容器中的混合物蒸发并回收未反应的单体和聚合介质并获得 氟化共聚物，（III）用洗涤介质洗涤含氟共聚物的工序。