Abstract:
The present invention discloses an optimized preparation method of a carbonization-based lightweight CO2 foamed cement-based material, and belongs to the field of geotechnical engineering materials. The preparation method includes: step S1: pre-screening existing common cement-based foaming agents and foam stabilizers; step S2: preparing a water-based carbon dioxide foam; step S3: preparing a cement slurry, and mixing the water-based carbon dioxide foam with the cement slurry to prepare a lightweight CO2 foamed cement-based material; step S4: selecting foaming agents of different types and different concentrations and foam stabilizers of different types and different concentrations to prepare slurries, subjecting the slurries to slurry performance tests, and selecting the optimal ones; step S5: optimizing initial water-to-cement ratio and foam-to-slurry ratio parameters; and step S6: optimizing a gas-filling volume parameter (water pump speed).
Abstract:
The disclosure discloses an ultra-dry three-phase flue gas foam for oil-gas fields and preparation method thereof. The ultra-dry three-phase flue gas foam is produced by a gas phase, a liquid phase and a solid phase; the gas phase is a flue gas; the foaming solution is an aqueous solution of a surfactant, a pH adjuster, and an inorganic salt; the solid phase is a composite of fly ash and nano silica; the foam quality is 90%-99%. The solid phase foam stabilizer is a compounded system of fly ash particles and nano silica particles, which is not only low in cost but also can form a stable solid particle adsorption layer on the foam film. Thus the instability of the foam such as film rupture, gas diffusion and bubble aggregation can be greatly reduced, and the stability of the foam can be effectively improved.
Abstract:
Described are admixture composition and method for integrally waterproofing cementitious compositions, such as concrete and mortar, wherein an organosilicon compound (e.g., silane) is mixed with animal oil, vegetable oil, or mixture thereof, and defoaming agent. The organosilicon/oil mixtures of the present invention enhances the water repellent efficacy of the organosilicon, even as it displays inherently greater product stability, as compared to emulsion-based (and thus substantial free-water containing) admixture formulations of the prior art. Cementitious materials made in accordance with the present invention demonstrate excellent air consistency and air neutrality.
Abstract:
The present invention provides compositions useful as a replacement for cellulose ether in cement, plaster or mortar compositions comprising i) nonionic or substantially nonionic vinyl or acrylic brush polymers having pendant or side chain polyether groups, and having a relative weight average molecular weight of from 140,000 to 50,000,000 g/mole, and ii) aromatic cofactors containing one or more phenolic groups, such as catechol tannins, phenolic resins, polyphenolics, and napthhols or, in combination, one or more aromatic groups with at least one sulfur acid group, such as naphthalene sulfonate aldehyde condensate polymers, poly(styrene-co-styrene sulfonate) copolymers, and lignin sulfonates, preferably branched cofactors, including phenolic resins, aldehyde condensate polymers and lignin sulfonates. The compositions may comprise a dry powder blend of i) and ii), one dry powder of both i) and ii), or an aqueous mixture.
Abstract:
The present invention provides a composition and method for modifying a hydratable cementitious composition such as concrete or mortar using at least three different, distinct carboxylate polymers, even when clay is present in the concrete or mortar that would otherwise diminish dosage efficiency of polycarboxylate polymer used as dispersant. The three polycarboxylate polymers, designated as Polymer I, Polymer II, and Polymer II, are derived from monomer Components A, B, and C wherein Component A is an unsaturated carboxylic acid, Component B is a polyoxyalkylene, and Component C is an unsaturated carboxylate ester. The component molar ratio ranges for A:B:C are different as between Polymers I and II; while a distinct component molar ratio A:B+C is identified for Polymer III. When treated with these three different polycarboxylate polymers, the hydratable cementitious composition is surprisingly enhanced in terms of initial workability and slump retention, especially if clay is present.
Abstract:
Grout slurries are provided that have high thermal conductivities of greater than about 1.4 Btu/hr-ft-° F. and low hydraulic conductivities ranging from about 5×10−9 cm/s to about 1×10−8 cm/s. Such grout slurries comprise water and a grout composition that is available as a one-sack product. The grout composition includes calcium bentonite present in an amount of from about 15% to about 45%, sodium bentonite present in an amount of from about 15% to about 45%, silica flour present in an amount of from about 10% to about 35%, and flaked graphite present in an amount of from about 10% to about 75%, all by weight of the grout composition. Further, methods of installing a conduit such as a heat transfer loop in a hole in the earth include placing the conduit in the hole, forming the foregoing grout slurry, and placing the grout slurry in the hole adjacent to the conduit.
Abstract translation:提供了具有大于约1.4Btu / hr-ft-°F的高热导率和约5×10 -9 cm / s至约1×10 -8 cm / s的低水力电导率的浆料浆料。 这种浆料浆料包括水和可作为单袋产品获得的灌浆组合物。 水泥浆组合物包含以约15%至约45%的量存在的钙膨润土,钠膨润土的存在量为约15%至约45%,二氧化硅粉的存在量为约10%至约35% %,并且片状石墨以水泥浆组合物的重量计约10%至约75%的量存在。 此外,在地球的孔中安装诸如传热回路的导管的方法包括将导管放置在孔中,形成上述浆料浆料,并将灌浆浆料放置在与导管相邻的孔中。
Abstract:
An aqueous concrete mixture having an air pore volume between 10 and 85%, preferably between 20 and 85%. When the aqueous concrete mixture is cured, a concrete having uniform density and high strength is obtained. This is achieved by including in the concrete mixture an aqueous, anionic surface-active compound containing two sulphonic acid groups of the general formula(R).sub.m --R.sub.1 --(SO.sub.3 M).sub.2 (1)wherein R is an aliphatic group having 4-20 carbon atoms, m is a number 1 or 2, the sum of the number of carbon atoms in the 1 or 2 R groups being 6-30, R.sub.1 is an aromatic group containing at least 2 aromatic rings and 10-20 carbon atoms, and M is a cation or hydrogen. The anionic compound has an air-entraining effect and improves the homogeneity of the concrete mixture.
Abstract:
An additive for cementitious compositions comprises at least one sulfated polysaccharide obtained by the sulfation of a polysaccharide, preferably under moderate conditions. The additive enhances the fluidity and workability of cementitious mixes, and gives higher final compressive strength.
Abstract:
Process for making a cement mixture containing fibers wherein a paste is formed by mixing cement and, per 100 parts by weight of cement, approximately 5 to 20 parts by weight of a first pulverized material of which the grains have an average diameter of between 1/5 and 1/10 of the average diameter of the grains of the cement and approximately 20 to 35 parts by weight of water. The paste is then mixed with reinforcing fibers. The paste may also include a second pulverized material the average grain diameter of which is between 1/5 and 1/10 of the average diameter of the first pulverized material. The invention further includes products made from a cement mixture manufactured according to one of the foregoing processes.
Abstract:
Cementing compositions having improved fluid loss capabilities for use in oil, gas, water and other well cementing operations are disclosed. Such compositions are comprised of water, hydraulic cement and a fluid-loss additive comprising a polymerization reaction product of styrene with 2-acrylamido-2-methylpropanesulfonic acid and their salts, said styrene being present in an amount of from about 15 to about 60 mole percent and said 2-acrylamido-2-methylpropanesulfonic acid being present in an amount of from about 40 to about 85 mole percent of said polymer.