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248 条记录 (耗时 0.019 秒)

    Preparation of bimetallic catalysts for hydrodechlorination of chlorinated hydrocarbons
    22.
    发明授权
    Preparation of bimetallic catalysts for hydrodechlorination of chlorinated hydrocarbons 失效
    用于氯化烃加氢脱氯的双金属催化剂的制备

    公开(公告)号：US5637548A

    公开(公告)日：1997-06-10

    申请号：US499693

    申请日：1995-07-07

    申请人： Larry N. Ito ,  Mark E. Jones ,  Simon R. Bare

    发明人： Larry N. Ito ,  Mark E. Jones ,  Simon R. Bare

    IPC分类号： B01J37/02 ,  C07C1/26 ,  C07C17/23 ,  B01J37/00 ,  B01J23/58 ,  B01J23/72 ,  C07C1/00

    CPC分类号： C07C17/23 ,  B01J37/0205 ,  C07C1/26 ,  C07C2523/42 ,  C07C2523/46 ,  C07C2523/72 ,  C07C2523/89 ,  Y10S502/514

    摘要： A process for preparing a bimetallic catalyst useful for the hydrodechlorination of chlorinated hydrocarbons, comprising impregnating a support with an active hydrogenating metal from a salt solution of the metal, recovering and drying the thus-impregnated support, reducing the impregnated support by exposure to hydrogen and oxidizing the active hydrogenating metal on said support to an oxidized state by exposure to an oxidizing environment, then impregnating the thus-treated support with a surface segregating metal from a salt solution thereof, aging the support/salt solution mixture over a period of time at an elevated temperature, and finally cooling, recovering and drying the catalyst before charging the same to a reactor for reduction or reduction and chloride source pretreatment and subsequent use.

    摘要翻译： 一种用于制备用于氯代烃加氢脱氯的双金属催化剂的方法，包括用金属盐溶液浸渍活性氢化金属的载体，回收和干燥由此浸渍的载体，通过暴露于氢来还原浸渍的载体; 通过暴露于氧化环境将所述载体上的活性氢化金属氧化为氧化态，然后用表面偏析金属从其盐溶液中浸渍如此处理的载体，使载体/盐溶液混合物在一段时间内老化 升温，最后冷却，回收和干燥催化剂，然后将其装入反应器进行还原或还原和氯化物源预处理和随后的使用。

    Hydrocarbon dehydrogenation with a nonacidic multimetallic catalytic composite
    27.
    发明授权
    Hydrocarbon dehydrogenation with a nonacidic multimetallic catalytic composite 失效
    用非酸性多金属催化复合物进行烃脱氢

    公开(公告)号：US4268707A

    公开(公告)日：1981-05-19

    申请号：US148117

    申请日：1980-05-09

    申请人： George J. Antos

    发明人： George J. Antos

    IPC分类号： B01J23/89 ,  C07C5/333 ,  C07C5/367 ,  C07C5/41

    CPC分类号： C07C5/3337 ,  B01J23/8946 ,  C07C5/367 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/42 ,  C07C2523/75 ,  C07C2523/89 ,  Y02P20/52

    摘要： Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a nonacidic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a cobalt component, a lanthanide series component and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.05 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % lanthanide series metal and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal.

    摘要翻译： 可脱氢烃通过在脱氢条件下与含有催化有效量的铂族组分，钴组分，镧系元素组分和碱金属或碱土金属组分与多孔载体材料的组合的非酸催化复合物接触而脱氢 其量足以导致含有约0.01至约2wt。 ％铂族金属，约0.05至约5wt。 ％钴，约0.01至约5wt。 ％镧系金属和约0.1至约5wt。 ％碱金属或碱土金属。

    Dehydrogenation method and nonacidic multimetallic catalytic composite for use therein
    29.
    发明授权
    Dehydrogenation method and nonacidic multimetallic catalytic composite for use therein 失效
    脱氢方法和非酸性多金属催化复合材料用于其中

    公开(公告)号：US4125565A

    公开(公告)日：1978-11-14

    申请号：US813905

    申请日：1977-07-08

    申请人： George J. Antos

    发明人： George J. Antos

    IPC分类号： B01J23/89 ,  C07C5/32 ,  C07C5/333 ,  C07C5/367 ,  C07C5/41 ,  C10G35/09 ,  C07C15/02 ,  B01J23/64 ,  C07C3/28

    CPC分类号： C10G35/09 ,  B01J23/8973 ,  C07C5/325 ,  C07C5/3337 ,  C07C5/367 ,  C07C5/417 ,  C07C2521/04 ,  C07C2523/18 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/755 ,  C07C2523/89 ,  Y02P20/52

    摘要： Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a nickel component, and a bismuth component with a porous carrier material. A specific example of the nonacidic catalytic composite disclosed herein is a combination of a platinum group component, a nickel component, a bismuth component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum group metal, about 0.05 to about 5 wt. % nickel, about 0.01 to about 5 wt. % bismuth and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal.

    摘要翻译： 可脱氢烃在脱氢条件下通过与包含催化有效量的铂族组分，镍组分和铋组分的组合的催化复合物与多孔载体材料接触而脱氢。 本文公开的非酸催化复合物的具体实例是铂族组分，镍组分，铋组分和碱金属或碱土金属组分与多孔载体材料的组合，其量足以导致含有约0.01 至约2重量％ ％铂族金属，约0.05至约5wt。 ％镍，约0.01至约5wt。 ％铋和约0.1至约5wt。 ％碱金属或碱土金属。

    Dehydrocyclization with an acidic multimetallic catalytic composite
    30.
    发明授权
    Dehydrocyclization with an acidic multimetallic catalytic composite 失效
    用酸性多金属催化复合材料脱氢环化

    公开(公告)号：US4119529A

    公开(公告)日：1978-10-10

    申请号：US779207

    申请日：1977-03-18

    申请人： John C. Hayes ,  Ernest L. Pollitzer

    发明人： John C. Hayes ,  Ernest L. Pollitzer

    IPC分类号： B01J23/89 ,  B01J27/08 ,  C07C5/10 ,  C07C5/32 ,  C07C5/333 ,  C07C5/367 ,  C07C5/41 ,  C10G35/09 ,  C10G45/52 ,  C10G45/62 ,  C10G35/08 ,  C07C5/22

    CPC分类号： C10G45/62 ,  B01J23/8913 ,  B01J23/8966 ,  B01J27/08 ,  C07C5/10 ,  C07C5/325 ,  C07C5/3337 ,  C07C5/367 ,  C07C5/417 ,  C10G35/09 ,  C10G45/52 ,  C07C2521/04 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/75 ,  C07C2523/89 ,  Y02P20/52 ,  Y10S585/906 ,  Y10S585/951

    摘要： Dehydrocyclizable hydrocarbons are converted to aromatics by contacting them at dehydrocyclization conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum or palladium component, a rhodium component, a cobalt component, and a halogen component with a porous carrier material. In a preferred embodiment, the catalytic composite also contains a catalytically effective amount of a Group IVA metallic component. The platinum or palladium, rhodium, cobalt and halogen components are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum or palladium metal, about 0.01 to about 2 wt. % rhodium, about 0.05 to about 5 wt. % cobalt, and about 0.1 to about 3.5 wt % halogen. Moreover, the catalytically active sites induced by these metallic components are uniformly dispersed throughout the porous carrier material and these metallic components are present in the catalyst in carefully controlled oxidation states. A specific example of the dehydrocyclization method disclosed herein is a method for converting a feed mixture of n-hexane and n-heptane to a product mixture of benzene and toluene which involves contacting the feed mixture and a hydrogen stream with the acidic multimetallic catalyst disclosed herein at dehydrocyclization conditions.

    摘要翻译： 可脱氢可环化的烃通过在脱氢环化条件下与含有催化有效量的铂或钯组分，铑组分，钴组分和卤素组分与多孔载体材料的组合的酸性多金属催化复合物接触而转化为芳族化合物。 在优选的实施方案中，催化复合物还含有催化有效量的IVA族金属组分。 铂或钯，铑，钴和卤素组分分别以基于元素计算的量存在于多金属催化剂中，相当于约0.01至约2重量％ ％铂或钯金属，约0.01至约2重量％ ％铑，约0.05至约5wt。 ％钴和约0.1至约3.5重量％的卤素。 此外，由这些金属组分诱导的催化活性位点均匀分散在整个多孔载体材料中，并且这些金属组分以仔细控制的氧化态存在于催化剂中。 本文公开的脱氢环化方法的具体实例是将正己烷和正庚烷的进料混合物转化为苯和甲苯的产物混合物的方法，其包括使进料混合物和氢气流与本文公开的酸性多金属催化剂接触 在脱氢环化条件下。