Low temperature epoxy resin curing agent comprising blend of an anhydride mixture, an anhydride half ester, and uranyl salt
    11.
    发明授权
    Low temperature epoxy resin curing agent comprising blend of an anhydride mixture, an anhydride half ester, and uranyl salt 失效
    低温环氧树脂固化剂,包含无水混合物,无机盐和盐酸盐的混合物

    公开(公告)号:US3852245A

    公开(公告)日:1974-12-03

    申请号:US37007673

    申请日:1973-06-14

    申请人: HONEYWELL INC

    发明人: GREGORNIK N SWANSON F

    摘要: An epoxy resin composition which is useful for encapsulating materials which are sensitive to shock, extreme temperature or chemical attack in which an epoxy resin is cured by the use of a curing agent comprised of an anhydride which is partially reacted to the corresponding half ester by reaction with a polyol under catalysis with a uranyl salt. The anhydride, anhydride half ester uranyl salt mixture forms a storable curing agent capable of promoting the complete cure of epoxy resin compositions in short time periods at temperatures of 170*F or less.

    摘要翻译: 一种环氧树脂组合物,其可用于包封对冲击,极端温度或化学侵蚀敏感的材料,其中环氧树脂通过使用由通过反应部分地与相应的半酯反应的酸酐组成的固化剂固化 与多元醇在催化下与铀酰盐反应。 酸酐,酸酐半酯铀盐混合物形成能够在170°F或更低温度下在短时间内促进环氧树脂组合物完全固化的可储存固化剂。

    Catalysis of oxirane-imide systems
    12.
    发明授权
    Catalysis of oxirane-imide systems 失效
    氧化物系统的催化

    公开(公告)号:US3819746A

    公开(公告)日:1974-06-25

    申请号:US21801572

    申请日:1972-01-14

    发明人: KATZAKIAN A STEELE R

    摘要: THIS PATENT DESCRIBES A NOVEL STORABLE EPOXY-IMIDE RESIN PRECURSOR COMPRISING A CURABLE OXIRANE MONOMER AND AN IMIDE, THE IMPROVEMENT WHEREIN THE SYSTEM IS PROVIDED WITH AN ACTIVATED CHROMIUM III TRICARBOXYLATE SALT CATALYST WHICH CONTAINS AVAILABLE COORDIATION SITES, AND WHICH SITES ARE RENDERED UNAVAILABLE IN THE PRESENCE OF CERTAIN NON-REACTIVE, REMOVABLE ELECTRON DONATING SOLVENTS. THAT IS TO SAY, THE CATALYST COMPOUND, IN THE PRESENCE OF PARTICULAR SOLVENTS IS RENDERED NONCATALYTIC; ON THE REMOVAL OF SAID SOLVENTS, CATALYTIC ACTIVITY IS RESTORED. THESE SOLVENTS INCLUDE BUT ARE NOT LIMITED TO SUCH POLAR ELECTRON COORDINATING SOLVENTS AS REMOVABLE METHANOL, ETHANOL, N,N-DIMETHYL FORMAMIDE, DIOXANE, TETRAHYDROFURAN, DIMETHYL SULFOXIDE, DIMETHYL SULFOLANE, NITRO ALKANES, NITRO AROMATICS, TETRAMETHYL UREA, N,N-DIMETHYLACETAMIDE, N-METHYLCAPROLACTAM AND N-METHYL PYRROLIDONE. UPON THE REMOVAL OF ONLY THE SOLVENT AS BE EVAPORATION, THE ACTIVITY OF THE CATALYST IS RESTORED, BY THE FORMATION OF UNOCCUPIED COORDINATION SITES, WHEREBY THE REACTION OF THE OXIRANE COMPOUND WITH THE IMIDE CAN TAKE PLACE.

    PHOTOCATIONICALLY CURABLE COMPOSITION AND DENTAL CURABLE COMPOSITION

    公开(公告)号:US20230320940A1

    公开(公告)日:2023-10-12

    申请号:US18010594

    申请日:2021-07-26

    摘要: To prevent gelling even during storage for a long time period under high temperature or room temperature, and to achieve rapid curing under a room-temperature condition at the time of photoirradiation, provided are a photocationically curable composition containing a cationically polymerizable monomer and photoacid generators, and being substantially free of a hydrogen ion scavenger, wherein the photoacid generators include: at least one kind of photoacid generator selected from a photoacid generator formed of an ion pair whose anion is a noncoordinating anion, and a photoacid generator formed of a zwitterionic compound whose anionic moiety is a noncoordinating anionic moiety; and at least one kind of photoacid generator selected from a photoacid generator formed of an ion pair whose anion is not a noncoordinating anion and a photoacid generator formed of a zwitterionic compound whose anionic moiety is not a noncoordinating anionic moiety, and a dental curable composition using the same.

    ORGANIC VEGETABLE OIL BASED RESIN AND PREPARATION METHOD THEREOF
    19.
    发明申请
    ORGANIC VEGETABLE OIL BASED RESIN AND PREPARATION METHOD THEREOF 审中-公开
    有机蔬菜油基树脂及其制备方法

    公开(公告)号:US20160046759A1

    公开(公告)日:2016-02-18

    申请号:US14920970

    申请日:2015-10-23

    申请人: Craig Katzakian

    IPC分类号: C08G59/42 C08G59/68 C08G59/24

    摘要: Disclosed are organic, UV resistant epoxy resins derived largely from vegetable oil based materials. More specifically, the present invention provides a virtually non-toxic, hypoallergenic UV resistant resin and method of producing and using the same that gives off substantially no VOCs and no disagreeable odors. The composition comprises a vegetable oil-based polyfunctional carboxylic acid, a cycloaliphatic anhydride, and an epoxy compound either of bicyclic difunctional epoxy resin, epoxidized vegetable oil or epoxidized polymer chains. The composition further comprises a catalyst and a wetting agent. In its cured state the material is leather like and exhibits high tensile strength as well as unusually high, totally reversible elongation. In an alternative embodiment, the resin comprises a cyclic anhydride (Lindride 16E). With increased amounts of cyclic anhydride, increased heat distortion temperature is exhibited; all while maintaining a high reversible elongation and high tensile strength In an additional alternative, an increased amount of Chromium III Octoate is used and in another alternative Phosphoric Acid.

    摘要翻译: 公开了主要由植物油基材料衍生的有机,耐紫外线的环氧树脂。 更具体地说,本发明提供了几乎无毒的,低过敏性的抗紫外线树脂及其制造和使用方法,其基本上不发出VOC并且没有令人不愉快的气味。 该组合物包含植物油基多官能羧酸,脂环族酸酐和双环双官能环氧树脂,环氧化植物油或环氧化聚合物链的环氧化合物。 组合物还包含催化剂和润湿剂。 在其固化状态下,材料是皮革样的并且表现出高拉伸强度以及异常高的完全可逆的伸长率。 在替代实施方案中,树脂包含环状酸酐(Lindride 16E)。 随着环酐的增加,显示出增加的热变形温度; 同时保持高的可逆伸长率和高拉伸强度。另外一种替代方案是使用增加量的铬酸铬III,另一种替代的磷酸。

    Polymerizable Composition
    20.
    发明申请
    Polymerizable Composition 有权
    可聚合组合物

    公开(公告)号:US20080139758A1

    公开(公告)日:2008-06-12

    申请号:US11661208

    申请日:2005-08-24

    申请人: Hirofumi Nishida

    发明人: Hirofumi Nishida

    IPC分类号: C08G59/68 C08L63/00

    摘要: A polymerizable epoxy compound composition containing an anionic polymerization initiator which can be easily produced, can attain a high polymerization rate and a high degree of polymerization, and can realize an epoxy polymer having properties unobtainable so far, an improvement in cured polymer properties, etc.; and a method of polymerizing an epoxy compound. The composition is an anionically polymerizable composition comprising a monofunctional epoxy compound or a di- or more functional epoxy resin and a polymerization initiator, the polymerization initiator comprising the potassium or sodium salt of a monocarboxylic acid monomer. The method, which is for producing a polymer of epoxy compounds, comprises polymerizing a monofunctional epoxy compound or a di- or more functional epoxy resin by anionic polymerization with the aid of the potassium or sodium salt of a monocarboxylic acid monomer.

    摘要翻译: 可以容易地制造含有阴离子聚合引发剂的可聚合环氧化合物组合物可以获得高聚合速率和高聚合度,并且可以实现迄今为止无法获得的性能,聚合物固化性能的改善等的环氧聚合物。 ; 和环氧化合物的聚合方法。 该组合物是包含单官能环氧化合物或二官能或更多功能的环氧树脂和聚合引发剂的阴离子可聚合组合物,聚合引发剂包含单羧酸单体的钾盐或钠盐。 用于生产环氧化合物的聚合物的方法包括通过阴离子聚合在一元羧酸单体的钾盐或钠盐的作用下聚合单官能环氧化合物或二官能以上的环氧树脂。