Abstract:
A retarder film provides a first light retardation and can be heat processed in one or more selected areas to provide a second light retardation in the selected area(s). The retarder film may have an absorption characteristic such that the heat processing can be carried out by selectively exposing the film to a suitable radiant beam. The retarder film is composed of a stack of contiguous ultrathin layers configured to provide an effective optical medium for visible light. Visible light propagates through the stack as an effective medium having effective refractive indices along principal x-, y-, and z-axes. At least some of the ultrathin layers possess intrinsic birefringence, and the effective indices of the stack are functions of the intrinsic refractive indices of the constituent ultrathin layers. The heat processing is carried out so that the ultrathin layer stack structural integrity is not substantially altered in the processed area(s).
Abstract:
A method of making an optical film includes providing a film, substantially uniaxially orienting the film, and heat setting the oriented film. The film includes a polymeric material capable of developing birefringence.
Abstract:
Compositions and films are described comprising a polylactic (PLA) polymer and a copolymer comprising a first moiety comprising a C12-C30 alkyl group and a second moiety that is miscible in the composition. Suitable first moieties include a C12-C30 alkyl (meth)acrylate or a polyvinyl alcohol comprising pendent C12-C30 alkyl groups. Suitable second moieties include C1-C10 (meth)acrylic acid or ester thereof, vinyl acetate and ethylene vinyl acetate. The aforementioned composition may be used to form a release layer of an adhesive article such as a pressure sensitive adhesive tape. The films may be a monolithic film or a film layer of a multilayer film. The release layer may be disposed upon a substrate layer that may also comprise PLA. The films are produced by melt extrusion of the aforementioned composition and may be oriented.
Abstract:
A composition is described comprising semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) of at least 25° C.; plasticizer; and optionally amorphous polylactic acid polymer. In another embodiment the composition further comprises nucleating agent. Also described are films comprising the composition as well as articles, such as a tape or sheet, comprising the film described herein and a layer of pressure sensitive adhesive disposed on the film.
Abstract:
In one embodiment, a film is described comprising a mixture of semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) midpoint as measured by differential scanning calorimetry of at least 25° C.; and plasticizer; wherein the film is oriented. In another embodiment, a film is described comprising a mixture comprising semicrystalline polylactic acid polymer, polymer having a midpoint Tg as measured by differential scanning calorimetry of at least 25° C., and plasticizer; wherein the mixture exhibits a single midpoint Tg and the single midpoint Tg ranges from 40° C. to 65° C.; and wherein the film is oriented and the oriented film exhibits a higher midpoint Tg ranging from 40° C. to 65° C. and a lower midpoint Tg ranging from 5 to 25° C.
Abstract:
A method of making an optical film includes providing a film, substantially uniaxially orienting the film, and heat setting the oriented film. The film includes a polymeric material capable of developing birefringence.
Abstract:
A multilayer optical film has a packet of microlayers that selectively reflect light by constructive or destructive interference to provide a first reflective characteristic. At least some of the microlayers are birefringent. A stabilizing layer attaches to and covers the microlayer packet proximate an outer exposed surface of the film. Heating element(s) can physically contact the film to deliver heat to the packet through the stabilizing layer by thermal conduction, at altered region(s) of the film, such that the first reflective characteristic changes to an altered reflective characteristic in the altered region(s) to pattern the film. The stabilizing layer provides sufficient heat conduction to allow heat from the heating elements to change (e.g. reduce) the birefringence of the birefringent microlayers disposed near the outer exposed surface in the altered region(s), while providing sufficient mechanical support to avoid substantial layer distortion of the microlayers near the outer exposed surface in the altered region(s).
Abstract:
In one embodiment, a film is described comprising a mixture of semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) midpoint as measured by differential scanning calorimetry of at least 25° C.; and plasticizer; wherein the film is oriented. In another embodiment, a film is described comprising a mixture comprising semicrystalline polylactic acid polymer, polymer having a midpoint Tg as measured by differential scanning calorimetry of at least 25° C., and plasticizer; wherein the mixture exhibits a single midpoint Tg and the single midpoint Tg ranges from 40° C. to 65° C.; and wherein the film is oriented and the oriented film exhibits a higher midpoint Tg ranging from 40° C. to 65° C. and a lower midpoint Tg ranging from 5 to 25° C.
Abstract:
A multilayer optical film has a packet of microlayers that selectively reflect light by constructive or destructive interference to provide a first reflective characteristic. At least some of the microlayers are birefringent. A stabilizing layer attaches to and covers the microlayer packet proximate an outer exposed surface of the film. Heating element(s) can physically contact the film to deliver heat to the packet through the stabilizing layer by thermal conduction, at altered region(s) of the film, such that the first reflective characteristic changes to an altered reflective characteristic in the altered region(s) to pattern the film. The stabilizing layer provides sufficient heat conduction to allow heat from the heating elements to change (e.g. reduce) the birefringence of the birefringent microlayers disposed near the outer exposed surface in the altered region(s), while providing sufficient mechanical support to avoid substantial layer distortion of the microlayers near the outer exposed surface in the altered region(s).
Abstract:
A composition is described comprising semicrystalline polylactic acid polymer; polyvinyl acetate polymer having a glass transition temperature (Tg) of at least 25 C; plasticizer; and optionally amorphous polylactic acid polymer. In another embodiment the composition further comprises nucleating agent. Also described are films comprising the composition as well as articles, such as a tape or sheet, comprising the film described herein and a layer of pressure sensitive adhesive disposed on the film.