公开(公告)号：US4450303A

公开(公告)日：1984-05-22

申请号：US468823

申请日：1983-02-23

Applicant: Charles A. Drake

Inventor： Charles A. Drake

IPC: C07C409/08 ,  C07C409/10 ,  C07C409/14 ,  C07C179/02

CPC classification number: C07C409/08 ,  C07C407/00 ,  C07C409/10 ,  C07C409/14 ,  C07C2101/14 ,  Y02P20/582

Abstract: High selectivities (>90%) for the production of secondary-alkyl substituted benzene hydroperoxides are achieved by heating a secondary-alkyl substituted benzene in the presence of oxygen and a samarium salt. Preferably, a free radical initiator is also present.

Abstract translation: 通过在氧和钐盐的存在下加热仲烷基取代的苯来实现用于制备仲烷基取代的苯氢过氧化物的高选择性（> 90％）。 优选还存在自由基引发剂。

公开(公告)号：US4408083A

公开(公告)日：1983-10-04

申请号：US293510

申请日：1981-08-17

Applicant: Masakazu Toyoura ,  Koichi Shomura ,  Hirotoshi Tsuchida ,  Tadateru Murakami

Inventor： Masakazu Toyoura ,  Koichi Shomura ,  Hirotoshi Tsuchida ,  Tadateru Murakami

IPC: C07C27/00 ,  C07C29/132 ,  C07C37/08 ,  C07C39/02 ,  C07C67/00 ,  C07C407/00 ,  C07C409/08 ,  C07C179/02

CPC classification number: C07C407/003

Abstract: Disclosed is a method of treating hydroperoxide mixtures, which comprises bringing an oily hydroperoxide mixture containing (A) an aromatic hydroperoxide having a hydroperoxymethyl group directly bonded to the aromatic nucleus and (B) an aromatic hydroperoxide having a 2-hydroperoxy-2-propyl group bonded directly to the aromatic nucleus into contact with an aqueous alkali solution, separating the aqueous phase from the oil phase and decomposing at least a part of the component (A) extracted in the aqueous phase.According to this method, the starting oily hydroperoxide mixture can be converted to a mixture in which the primary hydroperoxide content is reduced without substantial loss of the tertiary hydroperoxide. Therefore, aromatic hydroperoxide mixtures suitable for production of phenols can advantageously be proceeded.

Abstract translation: 公开了一种处理氢过氧化物混合物的方法，其包括将含有（A）具有直接键合到芳香核上的氢过氧甲基的芳族氢过氧化物的油性过氧化氢混合物和（B）具有2-氢过氧-2-丙基的芳族氢过氧化物 直接与芳族核键合，与碱性水溶液接触，将水相与油相分离，并分解至少部分在水相中萃取的组分（A）。 根据该方法，起始的油性过氧化氢混合物可以转化为其中初级氢过氧化物含量降低而不会显着损失叔氢过氧化物的混合物。 因此，可以有利地进行适合于生产苯酚的芳族氢过氧化物混合物。

公开(公告)号：US4329514A

公开(公告)日：1982-05-11

申请号：US225939

申请日：1981-01-19

Applicant: Ludovicus B. J. O. van der Weijst ,  Enno B. De Vries ,  Gerard J. Heiszwolf

Inventor： Ludovicus B. J. O. van der Weijst ,  Enno B. De Vries ,  Gerard J. Heiszwolf

IPC: C07C409/02 ,  B01J19/00 ,  C07C67/00 ,  C07C407/00 ,  C07C409/04 ,  C07C409/06 ,  C07C409/08 ,  C07C409/10 ,  C07C409/14 ,  C07C179/02

CPC classification number: B01J19/002 ,  C07C407/00 ,  C07C409/08

Abstract: Episodes of accelerated decomposition, or runaway, during the preparation of hydrocarbon hydroperoxides by reaction of hydrocarbons with molecular oxygen at elevated temperature, are brought under control through the addition to the oxidation reaction mixture of a small quantity of base in a substantially instantaneous manner at the onset of the runaway.

Abstract translation: 通过在升高的温度下通过烃与分子氧的反应制备烃氢过氧化物期间加速分解或失控的情节通过在基本上瞬时的方式下加入少量碱的氧化反应混合物而得到控制 发作失控。

公开(公告)号：US4326088A

公开(公告)日：1982-04-20

申请号：US223450

申请日：1981-01-08

Applicant: Harry Braus

Inventor： Harry Braus

IPC: C07C43/295 ,  C07C409/08 ,  C07C41/26 ,  C07C43/263

CPC classification number: C07C409/08 ,  C07C407/00 ,  C07C43/295

Abstract: 4,4'-dihydroxydiphenyl ether (DHDPE) is prepared by the catalytic oxidation of 4,4'-diisopropyldiphenyl ether to the corresponding dihydroperoxide, the latter being subjected to acid cleavage to provide the desired dihydroxy compound.

Abstract translation: 通过将4,4'-二异丙基二苯醚催化氧化成相应的二氢过氧化物制备4,4'-二羟基二苯醚（DHDPE），后者进行酸裂解以提供所需的二羟基化合物。

公开(公告)号：US4293719A

公开(公告)日：1981-10-06

申请号：US135306

申请日：1980-03-31

Applicant: Louis J. Velenyi ,  Serge R. Dolhyj ,  Marcia H. Sundeen

Inventor： Louis J. Velenyi ,  Serge R. Dolhyj ,  Marcia H. Sundeen

IPC: B01J31/00 ,  C07C67/00 ,  C07C407/00 ,  C07C409/02 ,  C07C409/08 ,  C07C409/10 ,  C07C409/14 ,  C07C179/035

CPC classification number: C07C409/14 ,  C07C407/00 ,  C07C409/08 ,  C07C409/10 ,  C07C2101/14

Abstract: Hydroperoxides, such as cyclohexylbenzene hydroperoxide, are manufactured by the oxidation of aryl compounds, such as cyclohexylbenzene, in the presence of a catalyst selected from the group consisting of C.sub.6 -C.sub.18 primary amines and polyvinylpyrrolidone.

Abstract translation: 氢过氧化物，如环己基苯氢过氧化物，是在选自C6-C18伯胺和聚乙烯吡咯烷酮的催化剂存在下，通过芳基化合物如环己基苯的氧化来制备的。

公开(公告)号：US4282384A

公开(公告)日：1981-08-04

申请号：US146232

申请日：1980-05-05

Applicant: Ching-Yong Wu ,  Harold E. Swift ,  John E. Bozik

Inventor： Ching-Yong Wu ,  Harold E. Swift ,  John E. Bozik

IPC: C07C409/08 ,  C07C409/12 ,  C07C179/035

CPC classification number: C07C409/12 ,  C07C407/00

Abstract: The hydroperoxides of diisopropylbenzene are prepared by the oxidation of diisopropylbenzene with molecular oxygen in the presence of a minute amount of solid barium oxide.

Abstract translation: 二异丙苯的氢过氧化物是通过在少量固体氧化钡的存在下用分子氧氧化二异丙基苯来制备的。

公开(公告)号：US4230894A

公开(公告)日：1980-10-28

申请号：US969627

申请日：1978-12-14

Applicant: Lewis B. Young

Inventor： Lewis B. Young

IPC: B01J29/00 ,  B01J29/40 ,  B01J29/70 ,  C07B61/00 ,  C07C2/66 ,  C07C7/148 ,  C07C27/00 ,  C07C37/08 ,  C07C39/02 ,  C07C45/53 ,  C07C67/00 ,  C07C409/08 ,  C07C409/12 ,  C07C15/085 ,  C07C179/047

CPC classification number: B01J29/40 ,  B01J29/70 ,  C07C2/66 ,  C07C37/08 ,  C07C407/00 ,  C07C409/08 ,  C07C45/53 ,  C07C7/148 ,  B01J2229/20 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/582

Abstract: Benzene or alkylbenzene (e.g. toluene) is alkylated with propylene to produce diisopropylbenzenes or isopropylalkylbenzenes, which in turn are selectively cracked to remove the 1,4-isomer. The resultant product, containing a high level of the 1,3-isomer, is then oxidized to 1,3-dihydroxybenzene or 3-alkylphenol (e.g. 3-methylphenyl) in significant yield.

Abstract translation: 苯或烷基苯（如甲苯）用丙烯烷基化，生成二异丙基苯或异丙基烷基苯，它们又被选择性裂化以除去1,4-异构体。 然后将含有高含量1,3-异构体的所得产物以显着的产率氧化成1,3-二羟基苯或3-烷基苯酚（如3-甲基苯基）。

公开(公告)号：US4088699A

公开(公告)日：1978-05-09

申请号：US462596

申请日：1974-04-22

Applicant: John E. Anderson ,  Ward J. Burkholder

Inventor： John E. Anderson ,  Ward J. Burkholder

IPC: C07C45/36 ,  C07C409/08 ,  C07C409/12 ,  C07C409/40 ,  C07C179/02

CPC classification number: C07C45/36 ,  C07C407/00 ,  C07C407/003 ,  C07C409/12 ,  C07C409/40

Abstract: A portion of a stream obtained by the oxidation of an aryl tertiary alkane and containing primarily aralkyl tertiary monohydroperoxide, substantial amounts of aryl tertiary alkane, smaller amounts of keto aryl tertiary alkanols, aralkyl tertiary dialkanols and other by-products is subjected to a separation step wherein a fraction containing the greater part of the aryl tertiary alkane and at least some of the monohydroperoxide, and a fraction containing the keto aryl tertiary alkanol are separated from one another and the fraction containing the aryl tertiary alkane and the monohydroperoxide is returned to the oxidation reaction.

公开(公告)号：US4080386A

公开(公告)日：1978-03-21

申请号：US672642

申请日：1976-04-01

Applicant: Jon G. Collins ,  David A. Hutchings

Inventor： Jon G. Collins ,  David A. Hutchings

IPC: C07C409/08 ,  C07C409/12 ,  C07C409/40 ,  C07C179/02

CPC classification number: C07C409/12 ,  C07C407/00 ,  C07C407/003 ,  C07C409/08 ,  C07C409/40

Abstract: A portion of a recycle stream obtained as a result of the oxidation of an aryl tertiary alkane and containing aralkyl tertiary monohydroperoxide, substantial amounts of unreacted aryl tertiary alkane and lesser amounts of poly-oxy-functional oxidation by-products is subjected to aqueous alkaline extraction to remove at least a portion of the poly-oxy-functional oxidation by-products therefrom followed by separation of the extraction mixture into an aqueous alkaline phase and an organic phase, the organic phase being recycled to the oxidation reaction.

Abstract translation: 由于芳基叔烷烃氧化并含有芳烷基叔氢过氧化物而获得的一部分循环料流，大量未反应的芳基叔烷烃和较少量的多氧官能氧化副产物进行含水碱性萃取 去除其中至少一部分多氧官能氧化副产物，然后将提取混合物分离成碱性水相和有机相，将有机相再循环至氧化反应。

公开(公告)号：US4022841A

公开(公告)日：1977-05-10

申请号：US772421

申请日：1968-10-31

Applicant: Howard P. Angstadt ,  William P. Griffin, Jr.

Inventor： Howard P. Angstadt ,  William P. Griffin, Jr.

IPC: B01J31/22 ,  C07C45/36 ,  C07C409/08 ,  C07C409/10 ,  C07C179/02 ,  C07C179/04

CPC classification number: B01J31/1855 ,  B01J31/22 ,  C07C407/00 ,  C07C409/08 ,  C07C409/10 ,  C07C45/36 ,  B01J2231/70 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/26 ,  B01J2531/38 ,  B01J2531/39 ,  B01J2531/44 ,  B01J2531/46 ,  B01J2531/50 ,  B01J2531/54 ,  B01J2531/72 ,  B01J2531/84 ,  B01J31/26

Abstract: Organometallic complexes formed between hexaalkylphosphoramides (HAPA) and metal salts, including rare earth metals, have been found to be effective catalyst for the oxidation of secondary and tertiary alkylaromatics to form valuable oxidation products, particularly the corresponding hydroperoxides. Novel complexes formed between HAPA and metal salts of the lanthanide series have been found to be especially effective in the selective formation of the hydroperoxides at high conversion rates. By substantially increasing the agitation and/or aeration of the reaction medium it is possible to increase these high conversion rates still further.

Abstract translation: 已经发现在六烷基磷酰胺（HAPA）和金属盐（包括稀土金属）之间形成的有机金属络合物是用于氧化仲和叔烷基芳族化合物以形成有价值的氧化产物，特别是相应的氢过氧化物的有效催化剂。 已经发现HAPA与镧系金属盐之间形成的新型络合物在高转化率下选择性形成氢过氧化物是特别有效的。 通过显着增加反应介质的搅拌和/或通气，可以进一步提高这些高转化率。