公开(公告)号：US11915937B2

公开(公告)日：2024-02-27

申请号：US17378017

申请日：2021-07-16

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Hsin-Yi Lee ,  Mao-Lin Huang ,  Lung-Kun Chu ,  Huang-Lin Chao ,  Chi On Chui

IPC: H01L21/28 ,  H01L21/3115 ,  H01L29/66 ,  H01L29/40 ,  H01L27/092 ,  H01L29/423

CPC classification number: H01L21/28158 ,  H01L21/3115 ,  H01L27/092 ,  H01L29/401 ,  H01L29/66742 ,  H01L29/42392 ,  H01L29/6653 ,  H01L29/66439 ,  H01L29/66553

Abstract: A method includes forming a plurality of nanostructures over a substrate; etching the plurality of nanostructures to form recesses; forming source/drain regions in the recesses; removing first nanostructures of the plurality of nanostructures leaving second nanostructures of the plurality of nanostructures; depositing a gate dielectric over and around the second nanostructures; depositing a protective material over the gate dielectric; performing a fluorine treatment on the protective material; removing the protective material; depositing a first conductive material over the gate dielectric; and depositing a second conductive material over the first conductive material.

公开(公告)号：US20230317859A1

公开(公告)日：2023-10-05

申请号：US17833348

申请日：2022-06-06

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Hsin-Yi Lee ,  Weng Chang ,  Chi On Chui

IPC: H01L29/786 ,  H01L29/423 ,  H01L29/66 ,  H01L29/78 ,  H01L29/06

CPC classification number: H01L29/78696 ,  H01L29/42392 ,  H01L29/66795 ,  H01L29/785 ,  H01L29/0669

Abstract: A device includes a semiconductor substrate; a vertically stacked set of nanostructures over the semiconductor substrate; a first source/drain region; and a second source/drain region, wherein the vertically stacked set of nanostructures extends between the first source/drain region and the second source/drain region along a first cross-section. The device further includes a gate structure encasing the vertically stacked set of nanostructures along a second cross-section. The second cross-section is along a longitudinal axis of the gate structure. The gate structure comprises: a gate dielectric encasing each of the vertically stacked set of nanostructures; a first metal carbide layer over the gate dielectric; and a gate fill material over the first metal carbide layer. The first metal carbide layer comprises Ce, Hf, V, Nb, Sc, Y, or
Mo.

公开(公告)号：US11742395B2

公开(公告)日：2023-08-29

申请号：US17656738

申请日：2022-03-28

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Hsin-Yi Lee ,  Ya-Huei Li ,  Da-Yuan Lee ,  Ching-Hwanq Su

IPC: H01L29/40 ,  H01L27/088 ,  H01L21/3215 ,  H01L21/8234 ,  H01L21/285 ,  H01L29/49

CPC classification number: H01L29/401 ,  H01L21/28568 ,  H01L21/3215 ,  H01L21/823437 ,  H01L27/0886 ,  H01L29/4966

Abstract: A method includes forming a gate dielectric comprising a portion extending on a semiconductor region, forming a barrier layer comprising a portion extending over the portion of the gate dielectric, forming a work function tuning layer comprising a portion over the portion of the barrier layer, doping a doping element into the work function tuning layer, removing the portion of the work function tuning layer, thinning the portion of the barrier layer, and forming a work function layer over the portion of the barrier layer.

公开(公告)号：US20220406598A1

公开(公告)日：2022-12-22

申请号：US17532204

申请日：2021-11-22

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Hsin-Yi Lee ,  Jia-Ming Lin ,  Kun-Yu Lee ,  Chi On Chui

IPC: H01L21/02

Abstract: A method includes removing a first dummy gate structure to form a recess around a first nanostructure and a second nanostructure; depositing a sacrificial layer in the recess with a flowable chemical vapor deposition (CVD); and patterning the sacrificial layer to leave a portion of the sacrificial layer between the first nanostructure and the second nanostructure. The method further include depositing a first work function metal in first recess; removing the first work function metal and the portion of the sacrificial layer from the recess; depositing a second work function metal in the recess, wherein the second work function metal is of an opposite type than the first work function metal; and depositing a fill metal over the second work function metal in the recess.

公开(公告)号：US11527621B2

公开(公告)日：2022-12-13

申请号：US17078655

申请日：2020-10-23

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Hsin-Yi Lee ,  Cheng-Lung Hung ,  Chi On Chui

IPC: H01L21/8238 ,  H01L29/40 ,  H01L29/49 ,  H01L29/66 ,  H01L29/78 ,  H01L27/092

Abstract: A method includes depositing a first work function tuning layer over a gate dielectric layer using an atomic layer deposition process. The atomic layer deposition process comprises depositing one or more first nitride monolayers; and depositing one or more carbide monolayers over the one or more first nitride monolayers. The method further includes depositing an adhesion layer of the first work function tuning layer; and depositing a conductive material over the adhesion layer.

公开(公告)号：US20220384440A1

公开(公告)日：2022-12-01

申请号：US17884052

申请日：2022-08-09

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Hsin-Yi Lee ,  Weng Chang ,  Chi On Chui

IPC: H01L27/092 ,  H01L29/06 ,  H01L21/02 ,  H01L29/78 ,  H01L29/66

Abstract: In an embodiment, a device includes: a channel region; a gate dielectric layer on the channel region; a first work function tuning layer on the gate dielectric layer, the first work function tuning layer including a n-type work function metal; a barrier layer on the first work function tuning layer; a second work function tuning layer on the barrier layer, the second work function tuning layer including a p-type work function metal, the p-type work function metal different from the n-type work function metal; and a fill layer on the second work function tuning layer.

公开(公告)号：US20220359703A1

公开(公告)日：2022-11-10

申请号：US17814743

申请日：2022-07-25

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd

Inventor： Hsin-Yi Lee ,  Cheng-Lung Hung ,  Chi On Chui

IPC: H01L29/49 ,  H01L21/285 ,  H01L21/8234 ,  H01L29/40 ,  H01L29/78

Abstract: A method includes forming a gate dielectric layer on a semiconductor region, and depositing a first aluminum-containing work function layer using a first aluminum-containing precursor. The first aluminum-containing work function layer is over the gate dielectric layer. A second aluminum-containing work function layer is deposited using a second aluminum-containing precursor, which is different from the first aluminum-containing precursor. The second aluminum-containing work function layer is deposited over the first aluminum-containing work function layer. A conductive region is formed over the second aluminum-containing work function layer.

公开(公告)号：US11495661B2

公开(公告)日：2022-11-08

申请号：US16842066

申请日：2020-04-07

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Hsin-Yi Lee ,  Ji-Cheng Chen ,  Cheng-Lung Hung ,  Weng Chang ,  Chi On Chui

IPC: H01L29/06 ,  H01L21/02 ,  H01L29/423 ,  H01L29/49

Abstract: A semiconductor device including a barrier layer surrounding a work function metal layer and methods of forming the same are disclosed. In an embodiment, a semiconductor device includes a semiconductor substrate; a first channel region over the semiconductor substrate; a second channel region over the first channel region; gate dielectric layers surrounding the first channel region and the second channel region; work function metal layers surrounding the gate dielectric layers; and barrier layers surrounding the work function metal layers, a first barrier layer surrounding the first channel region being merged with a second barrier layer surrounding the second channel region.

公开(公告)号：US11488873B2

公开(公告)日：2022-11-01

申请号：US17018084

申请日：2020-09-11

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Hsin-Yi Lee ,  Cheng-Lung Hung ,  Chi On Chui

IPC: H01L21/8238 ,  H01L27/092 ,  H01L29/49 ,  H01L21/285

Abstract: A method includes depositing a first conductive layer over a gate dielectric layer; depositing a first work function tuning layer over the first conductive layer; selectively removing the first work function tuning layer from over a first region of the first conductive layer; doping the first work function tuning layer with a dopant; and after doping the first work function tuning layer performing a first treatment process to etch the first region of the first conductive layer and a second region of the first work function tuning layer. The first treatment process etches the first conductive layer at a greater rate than the first work function tuning layer.

公开(公告)号：US20220328319A1

公开(公告)日：2022-10-13

申请号：US17854175

申请日：2022-06-30

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Hsin-Yi Lee ,  Cheng-Lung Hung ,  Chi On Chui

IPC: H01L21/285 ,  H01L29/786 ,  H01L29/06 ,  H01L27/092 ,  H01L29/40 ,  H01L21/8238 ,  H01L29/423

Abstract: A device includes a first nanostructure; a second nanostructure over the first nanostructure; a high-k gate dielectric around the first nanostructure and the second nanostructure, the high-k gate dielectric having a first portion on a top surface of the first nano structure and a second portion on a bottom surface of the second nanostructure; and a gate electrode over the high-k gate dielectric. The gate electrode comprises: a first work function metal around the first nanostructure and the second nanostructure, the first work function metal filling a region between the first portion of the high-k gate dielectric and the second portion of the high-k gate dielectric; and a tungsten layer over the first work function metal, the tungsten layer being free of fluorine.