Treatment for virgin phosphorous/vanadium oxidation catalysts
    91.
    发明授权
    Treatment for virgin phosphorous/vanadium oxidation catalysts 失效
    处理原始磷/钒氧化催化剂

    公开(公告)号:US5446000A

    公开(公告)日:1995-08-29

    申请号:US209407

    申请日:1994-03-14

    Applicant: Arie Bortinger

    Inventor: Arie Bortinger

    Abstract: A method of removing chloride from phosphorus/vanadium/oxygen mixed oxide oxidation catalysts comprising treating a chloride containing catalyst comprising phosphorus, vanadium and oxygen with a stream of gas comprising oxygen, steam and an inert gas at flow rate and temperature and for a period of time to substantially reduce the amount of chloride in the catalyst.

    Abstract translation: 一种从磷/钒/氧混合氧化物氧化催化剂中除去氯化物的方法,包括以包含氧,蒸汽和惰性气体的气流在流速和温度下处理包含磷,钒和氧的含氯化物的催化剂和一段时间 时间来显着减少催化剂中的氯化物的量。

    Phosphorous/vanadium oxidation catalyst
    92.
    发明授权
    Phosphorous/vanadium oxidation catalyst 失效
    磷/钒氧化催化剂

    公开(公告)号:US5262548A

    公开(公告)日:1993-11-16

    申请号:US923508

    申请日:1992-08-03

    Inventor: Bruno J. Barone

    CPC classification number: C07C51/215 B01J23/002 B01J27/199 B01J2523/00

    Abstract: An improvement in the oxidation catalyst used for the partial oxidation of n-butane and containing vanadium and phosphorus, zinc and lithium mixed oxides which comprises adding a molybdenum compound modifier in an amount of from about 0.005 to 0.025/1 Mo/V to the catalyst during the digestion of the reduced vanadium compound by concentrated phosphoric acid. The addition of Mo produces a catalyst which is very stable more active system and longer lived than the unmodified catalyst.

    Abstract translation: 用于正丁烷部分氧化并含有钒和磷,锌和锂混合氧化物的氧化催化剂的改进包括向催化剂中加入量为约0.005至0.025 / 1Mo / V的钼化合物改性剂 在通过浓磷酸消化还原的钒化合物的过程中。 Mo的添加产生的催化剂比非改性催化剂非常稳定,活性更强,寿命更长。

    TUBE TO TUBE SHEET WELDING FOR FABRICATION OF VERTICAL BOILING REACTOR WITH REDUCED TUBE PITCH

    公开(公告)号:US20220226937A1

    公开(公告)日:2022-07-21

    申请号:US17575023

    申请日:2022-01-13

    Inventor: Mohammad Ganjvar

    Abstract: Reduced tube pitch within a shell-and-tube heat exchange reactor such as, for example, an EO reactor, is provided by utilizing a welding material that has a high tensile (i.e., a tensile strength of greater than 600 MPa). Reduced tube pitch allows for more elongated tubes (the tubes are filled with a catalyst) to be present in a reactor, and thus a smaller reactor can be manufactured. Notably, the use of a high tensile strength welding material allows the implementation of a small welding groove located between a beveled sidewall of a beveled upper portion of an opening provided in a tube sheet overlay material (that is located atop a tube sheet) and an outermost sidewall of the elongated tube passing through the opening in the tube sheet overlay material.

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