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公开(公告)号：US4219382A
公开(公告)日：1980-08-26
申请号：US659318
申请日：1976-02-19
Applicant: Carl T. Leffler
Inventor： Carl T. Leffler
Abstract: An acid-fortified rosin is reacted with a water-soluble polyalkylenepolyamine. The product is a modified rosin polyamidopolyamine. The product can be partially or completely neutralized with a rosin, thereby forming a rosin soap of the polyamidopolyamine. The products can be emulsified in water, and are cationic, anionic or non-ionic depending on the pH of the water. The emulsions are sizing agents for paper.
Abstract translation: 酸强化松香与水溶性聚亚烷基多胺反应。 该产品是改性松香多胺多胺。 产物可以用松香部分或完全中和，从而形成聚酰胺多胺的松香皂。 产品可以在水中乳化，并且是阳离子，阴离子或非离子的，这取决于水的pH。 乳液是纸的上浆剂。
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2.发明授权Salt of beta-propiolactone adduct of rosin and sizing compositions made therefrom 失效硫辛酸钠和罗哌糖酸盐的添加量和尺寸组成的盐
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公开(公告)号：US4483744A
公开(公告)日：1984-11-20
申请号：US377398
申请日：1982-05-12
Applicant: Ralph W. Emerson, Sr.
Inventor： Ralph W. Emerson, Sr.
CPC classification number: D21H17/62
Abstract: Improved sizing compositions for cellulosic products, e.g., paper, are provided by combining first and second composition components while at least the second component is finely divided into fine liquid or solid particles. Component combination in this manner serves to provide especially effective sizing compositions.The first component comprises a material which provides both ammonia and ammonium salt when combined with other materials in the composition. Such ammonia-ammonium salt-providing material comprises at least one material selected from the group consisting of ammonia, or a precursor thereof; ammonium salts, or a precursor thereof; a reaction product of urea and at least one selected Lewis acid; and mixtures of these materials.The second component comprises a saponified, partially saponified or unsaponified rosin that is modified with either an .alpha., .beta.-unsaturated aliphatic acid generally containing from about 3 to 10 carbon atoms, an anhydride of such acids, or mixtures thereof.The improved sizing compositions produced comprise ammonia, ammonium salt and modified rosin, which components are present in sizing-effective or sizing-enhancing amounts, such that a total acidity of the composition of at least about 1000 parts per million is realized.
Abstract translation: 通过组合第一和第二组合物组分而提供用于纤维素产品例如纸的改进的施胶组合物，同时至少将第二组分精细地分成细的液体或固体颗粒。 以这种方式的组分组合用于提供特别有效的施胶组合物。 第一组分包括当与组合物中的其它材料组合时提供氨和铵盐的材料。 这种氨 - 铵盐提供材料包括选自氨或其前体中的至少一种材料; 铵盐或其前体; 脲和至少一种选择的路易斯酸的反应产物; 以及这些材料的混合物。 第二组分包括用通常含有约3至10个碳原子的α，β-不饱和脂肪酸，这种酸的酸酐或其混合物改性的皂化，部分皂化或未皂化的松香。 所生产的改进的施胶组合物包括氨，铵盐和改性松香，该成分以施胶效率或施胶增加量存在，使得组合物的总酸度达到至少约1000ppm。
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公开(公告)号：US3540980A
公开(公告)日：1970-11-17
申请号：US3540980D
申请日：1968-10-30
Applicant: INT PAPER CO
Inventor： JONES HAROLD L
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公开(公告)号：US4323425A
公开(公告)日：1982-04-06
申请号：US132505
申请日：1980-03-21
Applicant: Edwin Dowthwaite , Ian R. Hiskens
Inventor： Edwin Dowthwaite , Ian R. Hiskens
CPC classification number: D21H17/62 , D21H17/00 , Y10T428/31848 , Y10T428/31993
Abstract: This invention relates to improved rosin sizes, and to improved methods for preparing sized paper. In one embodiment, sized paper is prepared by adding the improved rosin size and a polyamine retention aid to a pulp slurry before sheet formation, without the use of aluminum sulfate. In another embodiment, paper is surface-sized with the improved rosin size in the absence of both aluminum sulfate and retention aids.
Abstract translation: 本发明涉及改进的松香尺寸，以及用于制备大小纸的改进方法。 在一个实施方案中，通过在不使用硫酸铝的情况下，将改进的松香尺寸和多胺助留剂添加到纸浆形成之前，将其制备成大小的纸。 在另一个实施方案中，在不存在硫酸铝和助留剂的情况下，纸张具有改进的松香尺寸的表面尺寸。
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Patent Agency Ranking
公开(公告)号：US3607621A
公开(公告)日：1971-09-21
申请号：US3607621D
申请日：1968-01-17
Applicant: PATERSON PARCHMENT PAPER CO
Inventor： WASKO WILLIAM R , SHEPPARD MILTON R , SCHULTZ ORSI R , ALBERTSON SOL A
CPC classification number: D21H17/53 , D21H17/62 , Y10T428/277 , Y10T428/3179
Abstract: Process for making erasable paper by forming a paper web, contacting the formed web with a parchmentized solution, removing excess acid, at least partially drying the web, and applying to a surface of the paper one or more sizing agents which are low molecular weight polyesters made by reaction of rosin and maleic anhydride adducts with polyhydric alcohols, and are preferably polyesters of rosin-maleic anhydride adducts with aliphatic polyols, and are applied alone or in combination with certain additives. The invention also includes the product of the foregoing process.
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7.发明授权
公开(公告)号：US3526524A
公开(公告)日：1970-09-01
申请号：US3526524D
申请日：1967-07-14
Applicant: AMERICAN CYANAMID CO
Inventor： KULICK RUSSELL JOSEPH
IPC: C08G69/48 , C08L77/00 , C08L79/02 , C08L93/00 , C08L93/04 , D21H17/56 , D21H17/62 , C08H11/04 , C08H11/06 , D21H3/34
CPC classification number: D21H17/62 , C08G69/48 , C08L79/02 , C08L93/00 , C08L93/04 , D21H17/56 , C08L2666/26 , C08L2666/14
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公开(公告)号：US4606791A
公开(公告)日：1986-08-19
申请号：US667726
申请日：1984-11-02
Applicant: Ralph W. Emerson, Sr.
Inventor： Ralph W. Emerson, Sr.
CPC classification number: D21H17/62
Abstract: Improved sizing compositions for cellulosic products, e.g., paper, are provided by combining first and second composition components while at least the second component is finely divided into fine liquid or solid particles. Component combination in this manner serves to provide especially effective sizing compositions.The first component comprises a material which provides both ammonia and ammonium salt when combined with other materials in the composition. Such ammonia-ammonium salt-providing material comprises at least one material selected from the group consisting of ammonia, or a precursor thereof; ammonium salts, or a precursor thereof; a reaction product of urea and at least one selected Lewis acid; and mixtures of these materials.The second component comprises a saponified, partially saponified or unsaponified rosin that is modified with either an .alpha., .beta.-unsaturated aliphatic acid generally containing from about 3 to 10 carbon atoms, an anhydride of such acids, or mixtures thereof.The improved sizing compositions produced comprise ammonia, ammonium salt and modified rosin, which components are present in sizing-effective or sizing-enhancing amounts, such that a total acidity of the composition of at least about 1000 parts per million is realized.
Abstract translation: 通过组合第一和第二组合物组分而提供用于纤维素产品例如纸的改进的施胶组合物，同时至少将第二组分精细地分成细的液体或固体颗粒。 以这种方式的组分组合用于提供特别有效的施胶组合物。 第一组分包括当与组合物中的其它材料组合时提供氨和铵盐的材料。 这种氨 - 铵盐提供材料包括选自氨或其前体中的至少一种材料; 铵盐或其前体; 脲和至少一种选择的路易斯酸的反应产物; 以及这些材料的混合物。 第二组分包括用通常含有约3至10个碳原子的α，β-不饱和脂肪酸，这种酸的酸酐或其混合物改性的皂化，部分皂化或未皂化的松香。 所生产的改进的施胶组合物包括氨，铵盐和改性松香，该成分以施胶效率或施胶增加量存在，使得组合物的总酸度达到至少约1000ppm。
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公开(公告)号：US4522686A
公开(公告)日：1985-06-11
申请号：US511445
申请日：1983-07-07
Applicant: David H. Dumas
Inventor： David H. Dumas
Abstract: Described are sizing compositions in the form of aqueous dispersions comprising a hydrophobic cellulose-reactive sizing agent such as a ketene dimer, fortified rosin and a water-soluble, nitrogen-containing cationic dispersing agent. The compositions are highly efficient internal or surface sizing agents for paper and maximize the advantages of each sizing component while minimizing the disadvantages.
Abstract translation: 描述了包含疏水性纤维素反应性施胶剂如乙烯酮二聚体，强化松香和水溶性含氮阳离子分散剂的水性分散体形式的上浆组合物。 组合物是用于纸的高效内部或表面施胶剂，并最大化每种施胶组分的优点，同时最小化缺点。
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10.发明授权
公开(公告)号：US4333795A
公开(公告)日：1982-06-08
申请号：US137677
申请日：1980-04-07
Applicant: Peter C. Street
Inventor： Peter C. Street
CPC classification number: D21H17/62
Abstract: Stable aqueous dispersions which are useful as one-shot sizing agents for paper, i.e. which do not require the separate addition of a flocculating agent, are prepared by combining a rosin dispersion, aluminum sulfate, and an alkali in a prescribed manner. The dispersions may also contain an added stabilizer such as a starch derivative, hydroxyethyl cellulose, or polyvinyl pyrrolidone if desired. These compositions can be used for either internal or external sizing.
Abstract translation: 通过以规定的方式组合松香分散体，硫酸铝和碱来制备可用作纸的单次施胶剂即不需要单独加入絮凝剂的稳定的水性分散体。 如果需要，分散体还可以含有添加的稳定剂如淀粉衍生物，羟乙基纤维素或聚乙烯吡咯烷酮。 这些组合物可用于内部或外部施胶。
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