Durable modification of fibrous substrates using a
polyoxyethylene-containing silane and articles therefrom
    2.
    发明授权
    Durable modification of fibrous substrates using a polyoxyethylene-containing silane and articles therefrom 失效
    使用含聚氧乙烯的硅烷及其制品对纤维基材的耐久改性

    公开(公告)号:US4207071A

    公开(公告)日:1980-06-10

    申请号:US8654

    申请日:1979-02-01

    摘要: Fibrous substrates are durably modified by applying a polyoxyethylene-containing silane to the substrate and heating the substrate to cure the silane. Durability of the treatment is achieved by using a silane having the formula R(OCH.sub.2 CH.sub.2).sub.x OR'SR"SiZ.sub.3 where Z denotes a hydroxyl or a hydrolyzable radical, R' and R" are divalent aliphatic radicals of suitable size, R is hydrogen, lower alkyl or lower acyl and x has a value of at least 3. The silane is applied to the fibrous substrate, such as a hydrophobic fabric, as a homogeneous liquid composition comprising the silane, a volatile liquid carrier and a siloxane polymerization catalyst to provide a treated substrate having improved properties, such as hydrophilicity.

    摘要翻译: 通过将基于聚氧化乙烯的硅烷施加到基底上并加热基底以固化硅烷,可持续地改性纤维基材。 通过使用具有式R(OCH 2 CH 2)xOR'SR''SiZ 3的硅烷来实现处理的耐久性,其中Z表示羟基或可水解基团,R'和R“是合适大小的二价脂族基团,R是氢 ,低级烷基或低级酰基,x的值至少为3.将硅烷作为包含硅烷,挥发性液体载体和硅氧烷聚合催化剂的均匀液体组合物施加到纤维基材如疏水性织物上, 提供具有改善的性能如亲水性的处理过的基材。

    Fluorinated condensation polymers and their use as soil release agents
    6.
    发明授权
    Fluorinated condensation polymers and their use as soil release agents 失效
    氟化缩合聚合物及其作为去污剂的用途

    公开(公告)号:US4046944A

    公开(公告)日:1977-09-06

    申请号:US674188

    申请日:1976-04-06

    摘要: Fluorinated condensation polymers which are made up of a combination of Blocks I and II: ##STR1## In these structures R.sub.f is a branched or linear perfluoroalkyl or perfluorooxaalkyl group of 5-18 carbons,R.sup.3 is an aliphatic triradical of 2-50 carbon atoms selected from the group consisting of branched or straight chain alkylene, alkylenethioalkylene, alkyleneoxyalkylene and alkyleneiminoalkylene,R.sup.4 is hydrogen or methyl,D is the organic divalent radial of a diisocyanate,k is 8-100,m is an integer of 1 to 5,n is 1 or 2, andp is an integer of 1 to 5,Wherein Blocks I and II are combined in a ratio of at least about 15% to 70% by weight of Block I to 30% to 85% by weight of Block II.The blocks as defined are connected by urea linkages in the final product condensate. The polymer condensates of this invention are useful as coatings on textiles, glass, linoleum, leather, wood, tile, metals, plastics, and various materials. They are of particular use on textile materials as soil release agents, showing increased durability as compared to urethane-connected condensation block polymers.

    摘要翻译: 由I和II组合组成的氟化缩聚物:块II在这些结构中,Rf是5-18个碳的支链或直链全氟烷基或全氟代烷基, R3是选自支链或直链亚烷基,亚烷硫基亚烷基,亚烷基亚烷基亚烷基亚烷基亚烷基,R 4为氢或甲基的2-50个碳原子的脂族三元素,D为二异氰酸酯的有机二价径向,K IS 8-100 ,M为1至5的整数,N为1或2,P为1至5的整数,由此I和II的组合按至少约15%至70% 至30重量%至85重量%。

    Fabrics treated with hybrid tetracopolymers and process
    7.
    发明授权
    Fabrics treated with hybrid tetracopolymers and process 失效
    用混合四聚物和工艺处理的织物

    公开(公告)号:US3995085A

    公开(公告)日:1976-11-30

    申请号:US637814

    申请日:1975-12-04

    摘要: A new class of hybrid copolymers which confer improved spray rating, resistance to staining, particularly aqueous stains and improved resistance to crocking on surfaces is obtained from (I) fluoroaliphatic radical-containing component in combination with (II) hydrocarbyl radical-containing component together conferring controlled oleophobicity and hydrophobicity in air and (III) a balanced combination of hydrophilic components conferring oleophobicity in water.

    摘要翻译: 从(I)含氟脂族基团的组分与(II)含烃基的组分组合得到一类新的混合共聚物,其赋予改进的喷雾等级,抗污染性,特别是水性污渍和改进的耐表面抗皱性能。 空气中的疏水性和疏水性,(III)赋予水中疏水性的亲水组分的平衡组合。