Efficient method of producing lubricant detergent additives
    1.
    发明授权
    Efficient method of producing lubricant detergent additives 失效
    生产润滑剂洗涤剂添加剂的高效方法

    公开(公告)号:US5370803A

    公开(公告)日:1994-12-06

    申请号:US115840

    申请日:1993-09-03

    CPC classification number: C10M159/24 C10M159/22

    Abstract: A method of preparing a lubricant detergent additive at a significantly enhanced filtration rate comprising the steps of:(a) mixing a neutral calcium sulfonate with sulfur, diluent oil, (C.sub.5 -C.sub.40) alkylphenol, ethylene glycol, and calcium hydroxide to form a mixture;(b) agitating said mixture at a temperature of about 150.degree. C. to about 200.degree. C. for a period of about four hours;(c) bubbling CO.sub.2 into said agitated mixture to provide an intermediate product; and(d) filtering said intermediate product at a rate of about 50 ml per 3 to 6 minutes to provide the lubricant detergent additive.

    Abstract translation: 一种以显着增强的过滤速率制备润滑剂洗涤剂添加剂的方法,包括以下步骤:(a)将中性磺酸钙与硫,稀释油,(C 5 -C 40)烷基酚,乙二醇和氢氧化钙混合以形成混合物 ; (b)在约150℃至约200℃的温度下搅拌所述混合物约4小时; (c)将CO 2鼓泡到所述搅拌的混合物中以提供中间产物; 和(d)以每50ml至约3分钟6分钟的速率过滤所述中间产物以提供润滑剂洗涤剂添加剂。

    Aqueous lubricant
    2.
    发明授权
    Aqueous lubricant 失效
    水性润滑剂

    公开(公告)号:US4419252A

    公开(公告)日:1983-12-06

    申请号:US436157

    申请日:1982-10-22

    Applicant: Joosup Shim

    Inventor: Joosup Shim

    Abstract: A lubricant concentrate is provided for forming stable, translucent oil-in-water emulsions upon dilution with a major part of water. The concentrate comprises a suitable base oil blended with polyisobutylene and an emulsifier/dispersant and antiwear/antirust inhibitor system. Typical emulsifier/dispersants include the metal soaps of rosin acids, the alkylene oxide condensation products of a fatty amine or the reaction product thereof with a polyalkenylsuccinic acid or anhydride. Zinc dialkyldithiophosphates and metal dialkylnaphthalene sulfonates are useful antiwear and antirust inhibitors.

    Abstract translation: 提供润滑剂浓缩物以在用大部分水稀释时形成稳定的,半透明的水包油乳液。 浓缩物包括与聚异丁烯和乳化剂/分散剂和抗磨/防锈剂抑制剂体系混合的合适的基础油。 典型的乳化剂/分散剂包括松香酸的金属皂,脂肪胺的烯化氧缩合产物或其与多烯基琥珀酸或酸酐的反应产物。 二烷基二硫代磷酸锌和二烷基萘磺酸金属盐是有用的抗磨和防锈剂。

    Process for preparing overbased magnesium sulfonates
    3.
    发明授权
    Process for preparing overbased magnesium sulfonates 失效
    制备高碱性磺酸镁的方法

    公开(公告)号:US4347147A

    公开(公告)日:1982-08-31

    申请号:US213323

    申请日:1980-12-05

    CPC classification number: C07C309/00 C10M159/24

    Abstract: A method of preparing superbased magnesium sulfonates by dispersing MgO in the preformed low viscosity overbased magnesium sulfonates. The low viscosity overbased magnesium sulfonates is prepared by sulfonating an alkyl benzene with a material containing SO.sub.3, preferably oleum, and reacting the alkyl benzene sulfonate with magnesium oxide in the presence of a low viscosity diluent, such as No. 2 oil or LOPS (low odor paraffin solvent), together with water, alcohol, and CO.sub.2. The newness of the method lies in the steps of preferably positively utilizing oleum which contains a minor amount of sulfuric acid as a promoter and utilizing also a surfactant couple of a C.sub.12 -C.sub.18 fatty acid such as oleic acid and an ethanol amide such as a lauryl diethanol amide, which may be Witcamide 5138; where a ready made sulfonate is used, such as SA697 (Conoco), H.sub.2 SO.sub.4 is utilized. In certain instances the amide may be omitted with satisfactory results occurring by using the acid alone.Of particular interest is the preparation of a concentrated magnesium sulfonate wherein the water and alcohol are removed by distillation and a diluent such as LOPS or No. 2 oil is added to produce a slurry.An important feature of this process lies in the reduction in size of the magnesium oxide particles. CO.sub.2 is preferentially bubbled through the mixture after introduction of the magnesium oxide and at a temperature range of 30.degree.-80.degree. C. with stirring. A typical zone of particle size is 40-50% of about 200 A and 50-60% of 0.1-1.0 microns. This is quite advantageous where an emulsion is formulated and the percentage of magnesium is in the area of 14-23% and preferably 20% or over.

    Abstract translation: 通过将MgO分散在预制的低粘度高碱性磺酸镁中制备高碱性磺酸镁的方法。 低粘度高碱性磺酸镁通过用含有SO 3,优选发烟硫酸的材料磺化烷基苯,并在低粘度稀释剂如2号油或LOPS(低)下使烷基苯磺酸盐与氧化镁反应制备 气味石蜡溶剂),以及水,酒精和二氧化碳。 该方法的新颖性在于优选积极利用含有少量硫酸作为助催化剂的发烟硫酸的步骤,还利用C 12 -C 18脂肪酸如油酸和乙醇酰胺的表面活性剂对,例如月桂基 二乙醇酰胺,其可以是Witcamide 5138; 其中使用现成的磺酸盐,例如SA697(Conoco),使用H 2 SO 4。 在某些情况下,可以省略酰胺,并通过单独使用酸而发生令人满意的结果。 特别令人感兴趣的是制备浓缩的磺酸镁,其中通过蒸馏除去水和醇,并加入稀释剂如LOPS或NO 2油以产生浆料。 该方法的一个重要特征在于氧化镁颗粒的尺寸减小。 在引入氧化镁后,在搅拌下,在30〜80℃的温度范围内,CO 2优先鼓泡通过混合物。 典型的粒度区域是约200A的40-50%和0.1-1.0微米的50-60%。 当配制乳液并且镁的百分比在14-23%,优选20%或更高的范围内时,这是非常有利的。

    Process for preparing overbased magnesium sulfonates
    5.
    发明授权
    Process for preparing overbased magnesium sulfonates 失效
    制备高碱性磺酸镁的方法

    公开(公告)号:US4306983A

    公开(公告)日:1981-12-22

    申请号:US184156

    申请日:1980-09-04

    CPC classification number: C07C309/00 C10M159/24

    Abstract: A method of preparing overbased or superbased magnesium sulfonates by sulfonating an alkyl benzene with a material containing SO.sub.3, preferably oleum, and reacting the alkyl benzene sulfonate with magnesium oxide in the presence of a low viscosity diluent, such as No. 2 oil or LOPS (low odor paraffin solvent), together with water, alcohol, and CO.sub.2. The newness of the method lies in the steps of preferably positively utilizing oleum which contains a minor amount of sulfuric acid as a promoter and utilizing also a surfactant couple of a C.sub.12 -C.sub.18 fatty acid such as oleic acid and an ethanol amide such as a lauryl diethanol amide, which may be Witcamide 5138; where a ready made sulfonate is used, such as SA697 (Conoco), H.sub.2 SO.sub.4 is utilized. In certain instances the amide may be omitted with satisfactory results occurring by using the acid alone.Of particular interest is the preparation of a concentrated magnesium sulfonate wherein the water and alcohol are removed by distillation and a diluent such as LOPS or No. 2 oil is added to produce a slurry.An important feature of this process lies in the reduction in size of the magnesium oxide particles. CO.sub.2 is preferentially bubbled through the mixture after introduction of the magnesium oxide and at a temperature range of 30.degree.-80.degree. C. with stirring.

    Abstract translation: 通过用含有SO 3的材料(优选发烟硫酸)磺化烷基苯,并在低粘度稀释剂(如2号油或LOPS)存在下使烷基苯磺酸盐与氧化镁反应来制备高碱性或高碱性磺酸镁的方法 低气味石蜡溶剂),以及水,酒精和二氧化碳。 该方法的新颖性在于优选积极利用含有少量硫酸作为助催化剂的发烟硫酸的步骤,还利用C 12 -C 18脂肪酸如油酸和乙醇酰胺的表面活性剂对,例如月桂基 二乙醇酰胺,其可以是Witcamide 5138; 其中使用现成的磺酸盐,例如SA697(Conoco),使用H 2 SO 4。 在某些情况下,可以省略酰胺,并通过单独使用酸而发生令人满意的结果。 特别令人感兴趣的是制备浓缩的磺酸镁,其中通过蒸馏除去水和醇,并加入稀释剂如LOPS或NO 2油以产生浆料。 该方法的一个重要特征在于氧化镁颗粒的尺寸减小。 在引入氧化镁后,在搅拌下,在30〜80℃的温度范围内,CO 2优先鼓泡通过混合物。

    Process for the production of overbased manganese salts of organic acids
    7.
    发明授权
    Process for the production of overbased manganese salts of organic acids 失效
    生产高碱性有机酸锰盐的方法

    公开(公告)号:US4252659A

    公开(公告)日:1981-02-24

    申请号:US84259

    申请日:1979-10-12

    Applicant: Asghar Ali

    Inventor: Asghar Ali

    CPC classification number: C07C51/414 C07G17/008 C10M159/20

    Abstract: Solutions of overbased manganese salts of organic acids that contain at least 13% by weight of manganese are prepared by carbonating a reaction mixture that contains excess manganous oxide, an oil-soluble organic acid, a solvent system, a promoter, a copromoter, and a third promoter that is an alkanoic acid having 1 to 3 carbon atoms at 70.degree.-120.degree. C. at a pressure of 1 atmosphere to 10 atmospheres.

    Abstract translation: 含有至少13重量%锰的有机酸的高碱性锰盐溶液通过碳酸化含有过量的氧化锰,油溶性有机酸,溶剂体系,助催化剂,共发酵剂和 第三助催化剂,其是在70-120℃下在1个大气压至10个大气压的压力下具有1至3个碳原子的链烷酸。

    Stabilized hydraulic fluid
    9.
    发明授权
    Stabilized hydraulic fluid 失效
    稳定液压油

    公开(公告)号:US4179389A

    公开(公告)日:1979-12-18

    申请号:US957654

    申请日:1978-11-03

    Applicant: James T. Mann

    Inventor: James T. Mann

    Abstract: Mineral oil or synthetic hydrocarbon base hydraulic fluids containing a zinc bis(dialkyldithiophosphate) as an antiwear agent are stabilized against degradation at elevated operating temperatures by the incorporation in the hydraulic fluid of an appropriate Group I or Group II metal dialkylnaphthalene sulfonate. For example, a hydraulic fluid containing a zinc bis(dialkyldithiophosphate) is stabilized by the presence of a minor amount of zinc dinonylnaphthalene sulfonate.

    Abstract translation: 含有双(二烷基二硫代磷酸锌)作为抗磨剂的矿物油或合成烃基液压油通过掺入适当的第I族或第II族金属二烷基萘磺酸盐的液压油中而在升高的操作温度下稳定而不会降解。 例如,含有二(二烷基二硫代磷酸锌)的液压油通过少量的二壬基萘磺酸锌的存在来稳定。

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