Circular economy for plastic waste to polypropylene via oil refinery with filtering and metal oxide treatment of pyrolysis oil

    公开(公告)号:US11359147B2

    公开(公告)日:2022-06-14

    申请号:US17237633

    申请日:2021-04-22

    Inventor: Hye-Kyung Timken

    Abstract: Provided in one embodiment is a continuous process for converting waste plastic comprising polyethylene and/or polypropylene into recycle for polypropylene polymerization. The process comprises selecting waste plastics containing polyethylene, polypropylene, or a mixture thereof, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil comprising a naphtha, diesel and heavy fractions, and char. The pyrolysis oil, or at least a fraction, is passed to a filtration/metal oxide treatment, with the treated product passed to a refinery FCC unit. A liquid petroleum gas C3 olefin/paraffin mixture fraction is recovered from the FCC unit, as well as a C4 olefin/paraffin mixture fraction. The C3 olefin fraction can be passed to a propylene polymerization reactor, and the C3 paraffin passed to a dehydrogenation unit to produce propylene for further polymerization.

    Integrated hydrothermal process to upgrade heavy oil

    公开(公告)号:US11149216B2

    公开(公告)日:2021-10-19

    申请号:US16928212

    申请日:2020-07-14

    Abstract: An integrated hydrothermal process for upgrading heavy oil includes the steps of mixing a heated water stream and a heated feed in a mixer to produce a mixed fluid, introducing the mixed stream to a reactor unit to produce a reactor effluent that includes light fractions, heavy fractions, and water, cooling the reactor effluent in a cooling device to produce a cooled fluid, depressurizing the cooled fluid in a depressurizing device to produce a depressurized fluid, introducing the depressurized fluid to a flash drum configured to separate the depressurized fluid into a light fraction stream and a heavy fraction stream. The light fraction stream includes the light fractions and water and the heavy fraction stream includes the heavy fractions and water. The process further includes the step of introducing the heavy fraction stream to an aqueous reforming unit that includes a catalyst to produce an aqueous reforming outlet.

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