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公开(公告)号：US11406958B2
公开(公告)日：2022-08-09
申请号：US17095173
申请日：2020-11-11
申请人： PHILLIPS 66 COMPANY
发明人： Jianhua Yao , Neal D. McDaniel , Bruce B. Randolph , Robert M. Walston , Anthony O. Baldridge , James A. Suttil , Soumen Kundu , Hong Xie , Steven E. Lusk
摘要： The present disclosure relates generally processes and systems for converting a C2-C7 light alkanes feed to liquid transportation fuels or value-added chemicals. The feed is contacted with an aromatization catalyst at a temperature and pressure that selectively converts C4 and larger alkanes to an intermediate product comprising monocyclic aromatics and olefins. Following separation of the aromatics and C5+ hydrocarbons from the intermediate product, unconverted C2-C3 alkanes are thermally-cracked to produce olefins that are subsequently oligomerized to produce a liquid transportation fuel blend stock or value-added chemicals.
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公开(公告)号：US11306042B2
公开(公告)日：2022-04-19
申请号：US17157142
申请日：2021-01-25
申请人： Swift Fuels, LLC
发明人： Chris D'Acosta , Jeffery Miller , Robert Hoch
摘要： Methods for making higher-octane fuel components from a feed stream of C8+ paraffins, including catalytically cracking the C8+ paraffins using a Zeolite catalyst to produce a reaction product of mid-chain paraffins and olefins and short-chain paraffins and olefins. The reaction product comprises liquid phase paraffins having an increased Octane Value over the feed stream paraffins. The reaction product further comprises a gas phase of short-chain paraffins which are separated from the liquid phase. In embodiments, the short chain olefins are hydrogenated to form mid-chain paraffins and a gas phase containing short-chain paraffins.
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公开(公告)号：US20210189256A1
公开(公告)日：2021-06-24
申请号：US17045883
申请日：2019-04-08
申请人： Neste Oyj
发明人： Virpi RÄMÖ , Antti OJALA , Risto VAPOLA
摘要： A method for producing a mixture hydrocarbons; a blend for producing a mixture of hydrocarbons; a mixture of hydrocarbons; and use of the mixture of hydrocarbons for producing chemicals and/or polymers.
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公开(公告)号：US20210138429A1
公开(公告)日：2021-05-13
申请号：US17095173
申请日：2020-11-11
申请人： PHILLIPS 66 COMPANY
发明人： Jianhua Yao , Neal D. McDaniel , Bruce B. Randolph , Robert M. Walston , Anthony O. Baldridge , James A. Suttil , Soumen Kundu , Hong Xie , Steven E. Lusk
摘要： The present disclosure relates generally processes and systems for converting a C2-C7 light alkanes feed to liquid transportation fuels or value-added chemicals. The feed is contacted with an aromatization catalyst at a temperature and pressure that selectively converts C4 and larger alkanes to an intermediate product comprising monocyclic aromatics and olefins. Following separation of the aromatics and C5+ hydrocarbons from the intermediate product, unconverted C2-C3 alkanes are thermally-cracked to produce olefins that are subsequently oligomerized to produce a liquid transportation fuel blend stock or value-added chemicals.
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公开(公告)号：US10981847B2
公开(公告)日：2021-04-20
申请号：US16593238
申请日：2019-10-04
申请人： PHILLIPS 66 COMPANY
发明人： Anthony O. Baldridge , Neal D. McDaniel , James A. Suttil , Edward C. Weintrob , Jianhua Yao , Bruce B. Randolph , Maziar Sardashti , Robert M. Walston , Steven E. Lusk
摘要： The present disclosure relates to processes that catalytically convert a hydrocarbon feed stream predominantly comprising both isopentane and n-pentane to yield upgraded hydrocarbon products that are suitable for use either as a blend component of liquid transportation fuels or as an intermediate in the production of other value-added chemicals. The hydrocarbon feed stream is isomerized in a first reaction zone to convert at least a portion of the n-pentane to isopentane, followed by catalytic-activation of the isomerization effluent in a second reaction zone with an activation catalyst to produce an activation effluent. The process increases the conversion of the hydrocarbon feed stream to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. Certain embodiments provide for further upgrading of at least a portion of the activation effluent by either oligomerization or alkylation.
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公开(公告)号：US10851313B2
公开(公告)日：2020-12-01
申请号：US16318539
申请日：2017-07-12
发明人： Ryoji Ida , Yasuyuki Iwasa , Masahide Kobayashi , Yukihiro Yoshiwara , Shinichiro Yanagawa , Yasuhiro Watanabe , Takashi Aozasa , Shinji Hyodo
摘要： A method of producing a lower olefin and BTX from stock oils selected from at least two kinds of oils is provided. The method includes a first catalytic cracking step of bringing one stock oil A into contact with a catalytic cracking catalyst; a second catalytic cracking step of bringing one stock oil B, having an aromatic component content smaller than that of the stock oil A, into contact with the catalytic cracking catalyst; and a separation and collection step of collecting the lower olefins and BTX from a product generated in the first and second catalytic cracking steps. A contact time A during which the stock oil A is in contact with the catalytic cracking catalyst in the first catalytic cracking step is longer than a contact time B during which the stock oil B is in contact with the catalytic cracking catalyst in the second catalytic cracking step.
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公开(公告)号：US20200308497A1
公开(公告)日：2020-10-01
申请号：US16815056
申请日：2020-03-11
摘要： A novel process/system for flexibly producing chemicals and fuels from a petroleum feed such as crude comprise a flashing drum, a first cracker (e.g., a fluidized bed pyrolysis cracker or an oxidative cracker), and an olefin-to-gasoline reaction zone. The process/system can also include a steam cracker and a hydrotreater. The process/system can convert crude oil into hydrogen, C2-C4 olefins, gas oil and distillates with various amounts by adjusting the cut point of the bottoms effluent exiting the flashing drum.
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公开(公告)号：US20200248079A1
公开(公告)日：2020-08-06
申请号：US16263026
申请日：2019-01-31
发明人： Arsam Behkish , Brian A. Cunningham , Anjaneya S. Kovvali , Brenda A. Raich , Christopher G. Smalley
IPC分类号： C10G63/04
摘要： Systems and methods are provided for conversion of light paraffinic gases to form liquid products in a two-stage reaction system. In a first stage, the light paraffinic gas is exposed to heat transfer particles in a side riser, where the heat transfer particles correspond to particles used in a separate process. Examples of a separate process include fluidized coking and fluid catalytic cracking. The conditions in the side riser can be selected to allow for conversion of at least a portion of the paraffins to olefins. After conversion, the converted olefin stream is passed to the second reaction stage while the heat transfer particles are returned to the separate process. The converted olefin stream is then exposed to a conversion catalyst under conditions for forming aromatics from the converted olefin stream in a second reaction stage. By performing the initial alkane conversion to olefins in the first reaction stage, the amount of coke formed during the aromatics formation process is reduced or minimized.
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公开(公告)号：US10173950B2
公开(公告)日：2019-01-08
申请号：US15826117
申请日：2017-11-29
发明人： Raed H. Abudawoud , Zhonglin Zhang
IPC分类号： C07C4/18 , C07C5/10 , C07C13/271 , C07C15/08 , C07C15/04 , C07C15/06 , C07C15/24 , C07C6/12 , C10G63/04 , B01D53/047
摘要： Systems and processes for maximizing the production of benzene and para-xylene from heavy reformate are provided. An integrated process and system may include a C9 dealkylation reactor, a transalkylation reactor, and a C10+ dealkylation reactor. The integrated process and system for producing benzene and para-xylene may be configured to additionally produce alkanes in the presence of hydrogen or olefins in the absence of hydrogen. The transalkylation reactor may perform transalkylation of product from the C9 dealkylation reactor and xylene isomerization.
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10.发明申请公开(公告)号：US20180334623A1
公开(公告)日：2018-11-22
申请号：US16051208
申请日：2018-07-31
申请人： UOP LLC
CPC分类号： C10G63/08 , C10G35/04 , C10G35/065 , C10G63/04 , C10G2300/104 , C10G2300/1044 , C10G2300/302 , C10G2300/305 , C10G2400/02
摘要： A process is presented for recovering the hydrocarbon components from a naphtha feed to pass to a gasoline blending pool or to change the operations to increase the production of light olefins. The process includes the separation of the naphtha feedstock into a light naphtha stream and a heavy naphtha stream. The process further includes separating the light naphtha stream to recovery high quality non-normal hydrocarbons, and to separate normal hydrocarbons to the feed to the cracking unit.
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