摘要:
The present disclosure relates to a method and an apparatus for treating, sorting and recycling an oil-containing discharged catalyst. There is provided a method for treating, sorting and recycling an oil-containing discharged catalyst, wherein the method comprises the following steps: (A) cyclonic washing and on-line activation of a discharged catalyst; (B) cyclonic spinning solvent stripping of the catalyst; (C) gas stream acceleration sorting of a high activity catalyst; (D) cyclonic restriping and particle capture of the high activity catalyst; and (E) cooling of the gas and condensation removal of the solvent. There is further provided an apparatus for treating, sorting and recycling an oil-containing discharged catalyst.
摘要:
In an ebullated bed process reactor effluent is subjected to high pressure followed by intermediate flash separation. An ebullation liquid is formed by educting high pressure flash separation liquid into an intermediate flash separation liquid. The ebullation liquid is recycled to the reactor to expand the catalyst bed to 110 vol % to 200 vol % of a settled catalyst bed volume. As a result of recycle pressure balance is advantageously maintained. Carry over catalyst and catalyst fines are recycled to the reactor and kept out of downstream equipment.
摘要:
An improved air distribution device for distributing fluidizing gas to a bed of fluidized solids. The distribution device is arranged to maintain a bed of fluidized particles above a planar region of air injection and allow withdrawal of solids from below the region of air injection. The fluidizing gas is distributed to a bed of fluidized particles by a central dome and a series of horizontally extending branch pipes arranged about the periphery of the dome. In order to improve the structural integrity of the apparatus and the operation of the device, the horizontal branch pipes are attached to a knuckle region of the central dome by a series of extruded outlets that minimize stress concentrations in the branch pipe connection and locate outlet holes in the branch pipes at an elevation close to the outlet holes in the dome.
摘要:
The hydrotreatment of hydrocarbons in the liquid phase is effected in a column containing a catalyst bed supported by a grid, wherethrough passes an ascending stream of the charge admixed with hydrogen which expands the catalyst bed, the perforations of the grid being small enough to prevent passage of the catalyst particles but large enough to permit passage of the hydrogen-charge mixture, the reaction effluent being withdrawn from the top of the column.
摘要:
A process and apparatus are shown for the improved utilization of catalysts in a hydrocracking system. The method comprises passing a hydrocarbon oil feedstock, preferably a heavy hydrocarbon residuum, upwardly through a particulate catalyst bed in a reaction zone maintained at high temperature and high pressure, together with hydrogen-containing gas; recycling a portion of the upwardly flowing oil together with a portion of the particulate catalyst to the bottom of the reaction zone while simultaneously pulverizing the minor proportion of the particulate catalyst to a fine powdered catalyst; and passing the recycled oil and finely powdered catalyst upwardly through the particulate catalyst bed in the reaction zone, with at least a portion of the powdered catalyst leaving the reactor with the treated effluent. Apparatus for practicing this process comprises a reactor vessel having a vertically mounted recycle conduit mounted therein, and pulverizing means, preferably a modified axial turbine high-shear mixer communicatingly connected to the bottom of the recycle conduit, for pulverizing recycled particulate catalyst to a fine powdery catalyst. Additionally, a pump is mounted to the outlet of the high-shear turbine mixer to provide positive fluid flow.
摘要:
A hydroconversion process of a heavy oil feedstock including (a) preparing a first conditioned feedstock (103) by blending heavy oil feedstock (101) with an organic chemical compound (102) containing at least one carboxylic acid function and/or at least one ester function and/or an acid anhydride function; (b) preparing a second conditioned feedstock (105) by mixing a catalyst precursor composition (104) with the first conditioned feedstock in a manner such that a colloidal or molecular catalyst is formed when it reacts with sulfur; (c) heating the second conditioned feedstock in at least a preheating device; (d) introducing the heated second conditioned feedstock (106) into at least one hybrid ebullated-entrained bed reactor containing a hydroconversion porous supported catalyst and operating the reactor in the presence of hydrogen and at hydroconversion conditions to produce an upgraded material (107), the colloidal or molecular catalyst being formed during step (c) and/or (d).
摘要:
A catalyst structure includes a porous support structure, where the support structure includes an aluminosilicate material and any two or more metals loaded in the porous support structure selected from Ga, Ag, Mo, Zn, Co and Ce. The catalyst structure is used in a hydrocarbon upgrading process that is conducted in the presence of methane, nitrogen or hydrogen.
摘要:
Processes and systems for upgrading resid hydrocarbon feeds are disclosed. The process system may operate in two different operating modes, maximum conversion and maximum quality effluent. The process system may be reversibly transitioned between the different operating modes. The system has the ability to reversibly transition between the two modes without shutting down the system or losing production.