摘要:
The present invention relates to organic solvent soluble dyes. In particular, the invention relates to an organic solvent soluble metal complex azo dyes containing chelated metal atoms.
摘要:
The invention relates to a process for the preparation of a metal complex dye under production conditions, which comprises reacting at least one dye with a metal donor, adding said metal donor or said dye discontinuously before the end point of the metallizing is reached, and determining the end of the metallizing voltametrically.The process makes it possible to prepare metal complex dyes in good yield and purity.
摘要:
A method of directly producing copperized azo-dyestuffs of predetermined inorganic salt content is disclosed wherein an ortho, ortho'-dihydroxyazo-dyestuff is reacted with about one molar equivalent of a copper (II) compound consisting of from 1.0 to 0.1 molar equivalent of a non-salt-forming copper compound selected from CuCO.sub.3.Cu(OH).sub.2, 2CuCO.sub.3.Cu(OH).sub.2, Cu(OH).sub.2, CuO and mixtures thereof, and correspondingly from 0 to 0.9 molar equivalent of a salt-forming copper (II) compound selected from CuSO.sub.4, CuCl.sub.2 and Cu(NO.sub.3).sub.2. The disclosed method provides standard strength copperized dyestuff compositions at increased yields and without the need to precipitate the product from the reaction solution.
摘要:
Dyestuffs are provided which contain one or more 1,3-dicyanobenzene radicals linked to the dyestuff at the 2-, 4- or 6-position, with halogen substituents in both of the remaining two of these positions and an electron-attracting substituent in the 5-position. These dyestuffs reactively dye cellulose at low temperatures and are less prone to "acid-bleeding" than some known reactive dyes. More particularly, those dyestuffs have the formula: ##STR1## where D is a chromophoric groupn is 1 or 2, ##STR2## where R is H, C.sub.1-4 alkyl, C.sub.1-4 alkyl substituted by OH, OSO.sub.3 H, CN or SO.sub.3 H or is phenyl.Each hal independently represents a chlorine or fluorine atom occupying one of the remaining 2-, 4- and 6-positions of the benzene nucleus, and Y is H, F, Cl, CN, NO.sub.2 or SO.sub.3 H.
摘要翻译:提供了含有一个或多个在2-,4-或6-位上与染料连接的1,3-二氰基苯基的染料,其中两个位置中的两个卤素取代基和 5位。 这些染料在低温下反应性地染色纤维素,并且比一些已知的活性染料更不容易发生“酸性渗色”。 更具体地说,那些染料具有下式:其中D是发色团n是1或2,其中R是H,C 1-4烷基,被OH,OSO 3 H,CN取代的C 1-4烷基或 SO 3 H或是苯基。 每个卤素独立地表示占据苯核的剩余的2-,4-和6-位中的一个的氯或氟原子,Y是H,F,Cl,CN,NO 2或SO 3 H.
摘要:
Novel azo compounds of the general formula(E).sub.n.sbsb.1 (A).sub.n.sbsb.2 --(R.sub.1).sub.n.sbsb.3 --N.dbd.N--BALare provided, wherein A is a charged group which may be positively or negatively charged, E is a counter ion which carries a charge of opposite sign to that carried by A, BAL represents a ballasting group attached to the azo group via an aromatic or heterocyclic ring which may be further substituted, and R.sub.1 is an optionally substituted aromatic or heterocyclic ring which is present unless A is a charged heterocylic group, and n.sub.1 and n.sub.2 are each 1 or 2, and n.sub.3 is 0 or 1.The compounds are useful in the photographic field, especially in the photographic dye diffusion transfer process for the production of photographic images.
摘要:
A process for the photochemical stabilization of fibre materials made of synthetic polyamides, which comprises treating the fibre material with at least one water-soluble copper complex dye or with a mixture of copper complex compounds containing at least one copper complex dye, or containing at least one copper complex dye in combination with a water-soluble 1:2 cobalt complex dye, 1:2 chromium complex dye, or an azo, anthraquinone, nitroaryl or dioxazine dye.The fibre materials treated (dyed) by the process of the invention are distinguished by very high tear strength and elongation values after exposure to light or exposure to hot light.
摘要:
A tri- or tetra-dentate metal complex having the formula ##STR1## wherein A is an aryl or heterocyclic residue, B is an aliphatic, aryl or heterocyclic residue, R is an alkyl, cycloalkyl, aryl, aralkyl or heterocyclic residue or R is the atoms required to complete, together with A and Y, a heterocyclic residue, Y is O, S or N--R" wherein R" is the atoms required to complete, together with A and Y, a heterocyclic residue, X is O, S, CO.sub.2 or N--R wherein R has its previous significance, and when X is CO.sub.2, R' is a methylene residue and when X is O, S or N--R, R' is a carbon chain, which may form part of an aromatic or heterocyclic ring, and having 2 or 3 carbon atoms between the nitrogen atom and the X substituent, M is a Zn, Cu or Ni atom, n and m are the same or different and each is 0 or 1 and P is 1 or 2, and when p is 1, C is a hydrogen atom attached to one of the residues A, B, R or R' and when p is 2, C is either a direct bond linking two residues, A, B, R or R' or is an alkylene, arylene or aralkylene residue linking two residues A, B, R or R', which is useful for coloring organic material preferably a lacquer, paint or printing ink.