公开(公告)号：US06569969B2

公开(公告)日：2003-05-27

申请号：US09963172

申请日：2001-09-25

申请人： Dominique Charmot ,  Han Ting Chang

发明人： Dominique Charmot ,  Han Ting Chang

IPC分类号： C08F404

CPC分类号： C08F2/38

摘要： Control agents that have a nitrogen—nitrogen bond covalently bonded to a thiocarbonyl moiety are provided for living-type free radical polymerization of a wide variety of monomers. These control agents provide superior properties for control of the polymerization and/or the properties of the polymers obtained and/or the monomers that may be polymerized. In some embodiments, a bulky group is pendant off the activated thiocarbonyl portion of the control agents. Multifunctional control agents provide the opportunity for a variety of structurally unique polymers, including block copolymers, stars and hyper-branched polymers.

公开(公告)号：US06723811B1

公开(公告)日：2004-04-20

申请号：US09561847

申请日：2000-04-28

申请人： Andrew Bruce Holmes ,  Xiao-Chang Li ,  Stephen Carl Moratti ,  Kenneth Andrew Murray ,  Richard Henry Friend

发明人： Andrew Bruce Holmes ,  Xiao-Chang Li ,  Stephen Carl Moratti ,  Kenneth Andrew Murray ,  Richard Henry Friend

IPC分类号： C08F404

CPC分类号： H05B33/14 ,  C08F128/06 ,  C08F220/18 ,  C08F220/30 ,  C08F220/36 ,  C08F228/06 ,  C08G61/00 ,  C08G61/02 ,  C08G61/12 ,  C08G61/126 ,  C09K11/06 ,  H01L51/0003 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0038 ,  H01L51/004 ,  H01L51/0043 ,  H01L51/007 ,  H01L51/5012 ,  H01L51/5048 ,  H05B33/10

摘要： Optical devices fabricated from solvent processible polymers suffer from susceptibility to solvents and morphological changes. A semiconductive polymer capable of luminescence in an optical device is provided. The polymer comprises a luminescent film-forming solvent processible polymer which contains cross-linking so as to increase its molar mass and to resist solvent dissolution, the cross-linking being such that the polymer retains semiconductive and luminescent properties.

摘要翻译： 由溶剂可加工聚合物制成的光学器件易受溶剂和形态的影响。 提供了能够在光学装置中发光的半导体聚合物。 该聚合物包含含有交联以增加其摩尔质量和抵抗溶剂溶解的发光成膜溶剂可加工聚合物，交联使得聚合物保持半导体和发光性质。

公开(公告)号：US06573347B1

公开(公告)日：2003-06-03

申请号：US09461927

申请日：1999-12-15

申请人： Wiebke Wunderlich ,  Rudolf Pfaendner ,  Raymond Seltzer ,  James Peter Galbo

发明人： Wiebke Wunderlich ,  Rudolf Pfaendner ,  Raymond Seltzer ,  James Peter Galbo

IPC分类号： C08F404

CPC分类号： C08F2/38 ,  C08F4/00 ,  C08K5/34926

摘要： The present invention relates to a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b1) at least one multifunctional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyl and a free radical initiator or b2) at least one multifunctional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyl-ether. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, the (co)polymers obtainable by this process and the use of multifunctional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyls in combination with a free radical initiator, or a multifunctional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyl-ethers for controlled polymerization. In a particularly preferred embodiment at least one additional heating step at a temperature from 140 to 280° C. is applied after polymerization is completed.

摘要翻译： 本发明涉及一种可聚合组合物，其包含a）至少一种烯属不饱和单体和b1）至少一种多官能三嗪基2,2,6,6四甲基哌啶-1-氧基和自由基引发剂或b2）至少一种多官能 三嗪基2,2,6,6四甲基哌啶-1-氧基醚。 本发明的其它方面是聚合烯键式不饱和单体的方法，可通过该方法获得的（共）聚合物和使用多官能三嗪基基2,2,6,6四甲基哌啶-1-氧基与自由基引发剂 ，或用于受控聚合的多官能三嗪基2,2,6,6四甲基哌啶-1-氧基醚。 在特别优选的实施方案中，在聚合完成后，施加140-180℃温度下的至少一个另外的加热步骤。

公开(公告)号：US06423799B1

公开(公告)日：2002-07-23

申请号：US09180851

申请日：1998-11-17

申请人： Horst Berneth ,  Uwe Claussen ,  Serguei Kostromine ,  Ralf Neigl ,  Hans-Joachim Vedder

发明人： Horst Berneth ,  Uwe Claussen ,  Serguei Kostromine ,  Ralf Neigl ,  Hans-Joachim Vedder

IPC分类号： C08F404

CPC分类号： G03F7/001 ,  C08F8/00 ,  C08F246/00 ,  C09B69/106 ,  G03H1/02 ,  G03H2001/026 ,  G03H2001/0264 ,  G03H2240/52 ,  G11B7/245 ,  C08F20/00

摘要： Disclosed is an extremely rapidly photo-addressable storage media from inherently slow photo-addressable polymers by irradiating a substrate over a large area with a light source suitable for conventional inscription so that an optical anisotropy, i.e. a double refraction with a preferential direction in the plane of the substrate occurs. If the substrates so prepared are briefly intensively irradiated, the pattern is inscribed extremely rapidly and permanently. The invention also relates to novel side-chain polymers in which high optical anisotropy can be generated by irradiation. This optical anisotropy is very heat stable.

摘要翻译： 公开了通过用适合于常规铭文的光源在大面积上照射基底的基本上缓慢的光寻址聚合物的非常快速的光寻址存储介质，使得光学各向异性即在平面中具有优先方向的双折射 的基板发生。 如果这样制备的基材被短暂地照射，则图案被非常快速地永久地刻印。 本发明还涉及其中可以通过照射产生高光学各向异性的新型侧链聚合物。 该光学各向异性非常热稳定。

公开(公告)号：US06172170B2

公开(公告)日：2001-01-09

申请号：US09472200

申请日：1999-12-27

申请人： Rainer Königer ,  Reinhold Schwalm ,  Roman Benedikt Raether

发明人： Rainer Königer ,  Reinhold Schwalm ,  Roman Benedikt Raether

IPC分类号： C08F404

CPC分类号： C08F4/04 ,  C07D231/54 ,  C07D271/12 ,  C07D487/08 ,  C07F7/0814

摘要： Initiators for free-radical addition polymerization comprising as structural feature the Diels-Alder adduct of an azo group (—N═N—) with a conjugated double bond (diene).

摘要翻译： 包括具有偶合基团（-N = N-）与共轭双键（二烯）的狄尔斯 - 阿尔德加合物的结构特征的自由基加聚的引发剂。

公开(公告)号：US06710146B2

公开(公告)日：2004-03-23

申请号：US10406374

申请日：2003-04-03

申请人： Wiebke Wunderlich ,  Rudolf Pfaendner ,  Raymond Seltzer ,  James Peter Galbo

发明人： Wiebke Wunderlich ,  Rudolf Pfaendner ,  Raymond Seltzer ,  James Peter Galbo

IPC分类号： C08F404

CPC分类号： C08F2/38 ,  C08F4/00 ,  C08K5/34926

摘要： The present invention relates to a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b1) at least one multifunctional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyl and a free radical initiator or b2) at least one multifunctional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyl-ether. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, the (co)polymers obtainable by this process and the use of multifunctional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyls in combination with a free radical initiator, or a multi-functional triazinyl based 2,2,6,6 tetramethylpiperidine-1-oxyl-ethers for controlled polymerization. In a particularly preferred embodiment at least one additional heating step at a temperature from 140 to 280° C. is applied after polymerization is completed.

摘要翻译： 本发明涉及一种可聚合组合物，其包含a）至少一种烯属不饱和单体和b1）至少一种多官能三嗪基2,2,6,6四甲基哌啶-1-氧基和自由基引发剂或b2）至少一种多官能 三嗪基2,2,6,6四甲基哌啶-1-氧基醚。 本发明的其它方面是聚合烯键式不饱和单体的方法，可通过该方法获得的（共）聚合物和使用多官能三嗪基基2,2,6,6四甲基哌啶-1-氧基与自由基引发剂 ，或用于受控聚合的多官能三嗪基2,2,6,6四甲基哌啶-1-氧基醚。 在特别优选的实施方案中，在聚合完成后，施加140-180℃温度下的至少一个另外的加热步骤。

公开(公告)号：US06602967B1

公开(公告)日：2003-08-05

申请号：US09615250

申请日：2000-07-13

申请人： Ron W. Darbeau ,  Mark S. Delaney ,  Ulku Ramelow

发明人： Ron W. Darbeau ,  Mark S. Delaney ,  Ulku Ramelow

IPC分类号： C08F404

CPC分类号： C08F4/00 ,  C08F136/08

摘要： Deaminatively generated carbocations to initiate addition polymerization are disclosed. The high reactivity of the carbocation allows initiation of polymerization with virtually all alkenes, alkynes, alicyclic and aromatic monomers, regardless whether multisubstituted or conjugated. In addition, the carbocation initiates a polymerization reaction that generates an extremely high molecular weight polymer. In particular polystyrene of viscosity average molecular weight of approximately 106 was obtained.

摘要翻译： 公开了脱氨基生成的引发加成聚合的碳阳离子。 碳阳离子的高反应性允许几乎所有烯烃，炔烃，脂环族和芳族单体的聚合开始，无论多取代或共轭。 另外，碳阳离子开始产生极高分子量聚合物的聚合反应。 特别是得到粘均分子量约为106的聚苯乙烯。

公开(公告)号：US06288185B1

公开(公告)日：2001-09-11

申请号：US09677889

申请日：2000-10-03

申请人： Rainer Königer ,  Reinhold Schwalm ,  Roman Benedikt Raether

发明人： Rainer Königer ,  Reinhold Schwalm ,  Roman Benedikt Raether

IPC分类号： C08F404

CPC分类号： C08F4/04 ,  C07D231/54 ,  C07D271/12 ,  C07D487/08 ,  C07F7/0814

摘要： Initiators for free-radical addition polymerization comprising as structural feature the Diels-Alder adduct of an azo group (—N═N—) with a conjugated double bond (diene).

公开(公告)号：US06262205B1

公开(公告)日：2001-07-17

申请号：US07890604

申请日：1992-07-13

申请人： Thomas Huver ,  Thomas Moeller ,  Wolfgang Klauck ,  Christian Nicolaisen

发明人： Thomas Huver ,  Thomas Moeller ,  Wolfgang Klauck ,  Christian Nicolaisen

IPC分类号： C08F404

CPC分类号： C08F4/00 ,  C08F4/40

摘要： The process of curing a radical-polymerizable multicomponent mixture containing an olefinically-unsaturated compound with ambient air by adding to the mixture an alkyl, cycloalkyl or aryl hydrazone of an aliphatic, cycloaliphatic or aromatic aldehyde or ketone which forms a hydroperoxide as an initiator for curing the mixture.

摘要翻译： 将含有烯属不饱和化合物的自由基聚合性多组分混合物与环境空气固化的方法，通过向混合物中加入形成氢过氧化物作为固化剂的引发剂的脂族，脂环族或芳族醛或酮的烷基，环烷基或芳基腙 混合物。

公开(公告)号：US06653418B1

公开(公告)日：2003-11-25

申请号：US10219262

申请日：2002-08-16

申请人： Katsuhiro Maruyama ,  Satoru Yoshida ,  Satoru Kitano ,  Hitoshi Mashio

发明人： Katsuhiro Maruyama ,  Satoru Yoshida ,  Satoru Kitano ,  Hitoshi Mashio

IPC分类号： C08F404

CPC分类号： C08F12/22

摘要： There is provided a process for preparing a polymer compound for a resist, which can improve the performance, such as the heat resistance, sensitivity and resolution of the resist, without causing film loss of the resist, line width reduction of the resist or deterioration of the dry etching resistance of the polymer. This process comprises dissolving a styrene-based monomer containing at least a 4-acetoxystyrene monomer, and a dimethyl-2,2′-azobiscarboxylate ester in a solvent, thereby to polymerize the styrene-based monomer; adding an alkali catalyst to the resulting polymer solution, thereby to hydrolyze the polymer solution; and washing the resulting polymer compound with water.

摘要翻译： 提供了制备抗蚀剂用高分子化合物的方法，其可以提高抗蚀剂的耐热性，灵敏度和分辨率等性能，而不会导致抗蚀剂的膜损失，抗蚀剂的线宽减小或抗蚀剂的劣化 聚合物的耐干蚀刻性。 该方法包括将至少含有4-乙酰氧基苯乙烯单体的苯乙烯基单体和二甲基-2,2'-偶氮二羧酸酯溶解在溶剂中，从而聚合苯乙烯类单体; 向所得聚合物溶液中加入碱催化剂，从而水解聚合物溶液; 并用水洗涤所得高分子化合物。