知搜-全球专利检索

  1. Login
  2. Sign Up

Search Results

28 records (took 0.013 seconds)

    Process for producing olefin polymer
    2.
    发明授权
    Process for producing olefin polymer 失效
    生产烯烃聚合物的方法

    公开(公告)号：US5219960A

    公开(公告)日：1993-06-15

    申请号：US683157

    申请日：1991-04-10

    Applicant: Hideki Tamano ,  Yuzo Saitoh

    Inventor： Hideki Tamano ,  Yuzo Saitoh

    IPC: C08F4/645 ,  C08F4/60 ,  C08F4/647 ,  C08F10/00 ,  C08F210/06 ,  C08F297/08

    CPC classification number: C08F297/083

    Abstract: A process of producing an olefin polymer by polymerizing an olefin in a multi-stage polymerization in the presence of a catalyst composed of a solid catalyst component containing a halogen and titanium, and an organoaluminum compound, while adding, to a reaction vessel for conducting a second-stage or later polymerization or a portion connecting a former part to a latter part, of the multi-stage polymerization reaction vessels,(a) a polyfunctional electron donor compound in an amount, based on the organoaluminum compound, of 0.001 to 50 in terms of the ratio of the total moles of the functional groups to the mole of aluminum, and(b) a compound different from the compound (a) and selected from a compound having a group of the formula M-O-R (wherein M is an element selected from the group consisting of the group IA, IIA, IIB, IIIA, IIIB, IVA, IVB, VA, VB, VIA, VIB, VIIA and VIII elements of the periodic table and R is a hydrogen atom or a hydrocarbyl group), oxygen, carbon monoxide and carbon dioxide, in an amount, based on the organoaluminum compound, of 0.001 to 50 in terms of the ratio of the moles of oxygen atom to the mole of aluminum.

    Abstract translation: 在由含有卤素和钛的固体催化剂组分的催化剂和有机铝化合物组成的催化剂存在下，在多级聚合中使烯烃聚合制备烯烃聚合物的方法，同时加入到用于进行 第二阶段或更后的聚合反应或将前一部分连接到后一部分的部分多级聚合反应容器，（a）多官能电子给体化合物的量为基于有机铝化合物的0.001至50 官能团的总摩尔数与铝的摩尔数的比率的术语，和（b）不同于化合物（a）的化合物，并且选自具有式MOR的基团的化合物（其中M是选择的元素 来自由元素周期表中的IA，IIA，IIB，IIIA，IIIB，IVA，IVB，VA，VB，VIA，VIB，VIIA和VIII族元素组成的组，R是氢原子或烃基），氧 ，一氧化碳和 以氧原子的摩尔数与铝的摩尔数的比例计，基于有机铝化合物的量的二氧化碳为0.001至50。

    Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers
    3.
    发明授权
    Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers 有权
    制备乙烯互聚物和互聚物的方法; 组合物和含有这种互聚物的电子装置

    公开(公告)号：US08263722B2

    公开(公告)日：2012-09-11

    申请号：US11086108

    申请日：2005-03-21

    Applicant: Narayanaswami Raja Dharmarajan ,  Rui Zhao ,  Bruce Allan Harrington ,  George James Pehlert ,  Periagaram S. Ravishankar ,  Kent L. Chasey

    Inventor： Narayanaswami Raja Dharmarajan ,  Rui Zhao ,  Bruce Allan Harrington ,  George James Pehlert ,  Periagaram S. Ravishankar ,  Kent L. Chasey

    IPC: C08F210/16 ,  C08F4/6392 ,  C08F4/647 ,  H01B3/28

    CPC classification number: C08F210/16 ,  C08F2/001 ,  C08F2/06 ,  C08F210/06 ,  C08F2500/25 ,  C08F2500/09 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/05 ,  C08F2500/17 ,  C08F210/08 ,  C08F236/20 ,  C08F210/14

    Abstract: The invention relates to a continuous polymerization process for preparing a random ethylene interpolymer with propylene and/or 1-butene which comprises: (A) polymerizing ethylene, and as an α-olefin comonomer propylene and/or 1-butene under continuous random polymerization conditions in the presence of single site catalyst system employing an ionic activator having cyclic ligands shielding a central charge bearing atom, at a temperature of 140° C. to 250° C. at a conversion of ethylene of 80 to 99% and a comonomer conversion of from at least 30% and (B) devolatilizing the polymer to provide an ethylene copolymer having a density of from 0.85 to 0.92 g/cm3, an MI of from 0.01 to 100 g/10 min, preferably from 0.1 to 20, and an I21/I2 of from 30 to 400. The invention also relates to polymers made by such processes containing as α-olefin comonomer propylene and/or 1-butene, having a density of from 0.85 to 0.92 g/cm3, an MI of from 0.01 to 100 g/10 min and an I21/I2 of from 30 to 400 obtained by solution polymerization using a transition metal complex as a catalyst and a non-coordinating anion to provide a level of NCA derived residue, as determined by boron content, less than 0.5 ppm. as determined by ICP, preferably undetectable by ICP. The polymers may be blended with EP rubber elastomers and be used for electrical cable insulation.

    Abstract translation: 本发明涉及一种用丙烯和/或1-丁烯制备无规乙烯互聚物的连续聚合方法，其包括：（A）在连续无规聚合条件下聚合乙烯和作为α-烯烃共聚单体丙烯和/或1-丁烯 在使用具有屏蔽中心带电荷原子的环状配体的离子活化剂的单中心催化剂体系存在下，在140℃至250℃的温度下，乙烯的转化率为80-99％，共聚单体转化率 至少30％，（B）使该聚合物脱挥发分，得到密度为0.85-0.92g / cm3，MI为0.01-100g / 10min，优选为0.1-20的乙烯共聚物，和I21 / I 2为30至400.本发明还涉及通过这样的方法制备的聚合物，其包含密度为0.85至0.92g / cm 3的α-烯烃共聚单体丙烯和/或1-丁烯，MI为0.01至 100g / 10min，I21 / I2为30〜400 通过使用过渡金属络合物作为催化剂的溶液聚合和非配位阴离子获得，以提供由硼含量确定的NCA衍生残基的水平小于0.5ppm。 由ICP测定，优选不能通过ICP检测。 聚合物可与EP橡胶弹性体共混并用于电缆绝缘。

    Catalyst olefin polymerization and process for olefin polymerization using the same
    5.
    发明授权
    Catalyst olefin polymerization and process for olefin polymerization using the same 失效
    催化剂烯烃聚合和使用该烯烃聚合的烯烃聚合方法

    公开(公告)号：US5703181A

    公开(公告)日：1997-12-30

    申请号：US585812

    申请日：1996-01-16

    Applicant: Takashi Tashiro ,  Takashi Ueda

    Inventor： Takashi Tashiro ,  Takashi Ueda

    IPC: C08F4/64 ,  C08F4/646 ,  C08F4/647 ,  C08F4/649 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/648

    CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65922

    Abstract: Disclosed are a catalyst for olefin polymerization comprising (A) a compound of a transition metal in Group IVB of the periodic table which contains a ligand having a cyclopentadienyl skeleton, (B) an organoaluminum compound and any one of (C1) a Br.o slashed.nsted acid; (C2) a material obtained by contacting (c-1) a magnesium compound with (c-2) an electron donor; and (C3) a material obtained by contacting (c-1) a magnesium compound, (c-2) an electron donor and (c-3) an organometallic compound with each other. Also disclosed are processes for polymerizing an olefin in the presence of the above-mentioned catalysts for olefin polymerization. Such catalysts and processes for olefin polymerization as described above are excellent in olefin polymerization activity and economical efficiency.

    Abstract translation: 公开了一种用于烯烃聚合的催化剂，其包含（A）元素周期表IVB族中的过渡金属化合物，其含有具有环戊二烯基骨架的配体，（B）有机铝化合物和（C1）Br + 526 诺斯特酸 （C2）通过使（c-1）镁化合物与（c-2）电子给体接触而获得的材料; 和（C3）通过使（c-1）镁化合物（c-2）电子给体和（c-3）有机金属化合物彼此接触获得的材料。 还公开了在上述用于烯烃聚合的催化剂存在下使烯烃聚合的方法。 这样的上述烯烃聚合用催化剂和方法在烯烃聚合活性和经济性方面是优异的。

    Preparation of homopolymers of ethene and copolymers of ethene with higher a-monoolefins using a Ziegler catalyst system
    7.
    发明授权
    Preparation of homopolymers of ethene and copolymers of ethene with higher a-monoolefins using a Ziegler catalyst system 失效
    使用齐格勒催化剂体系制备乙烯与乙烯共聚物与高级单环戊二烯的共聚物

    公开(公告)号：US5210160A

    公开(公告)日：1993-05-11

    申请号：US410047

    申请日：1989-09-19

    Applicant: Roland Saive ,  Guido Funk ,  Rainer Hemmerich

    Inventor： Roland Saive ,  Guido Funk ,  Rainer Hemmerich

    IPC: C08F4/607 ,  C08F4/642 ,  C08F4/647 ,  C08F4/65 ,  C08F4/685 ,  C08F10/02

    CPC classification number: C08F10/02

    Abstract: Homopolymerization and copolymerization of ethene is carried out using a Ziegler catalyst system consisting of (1) a transition metal catalyst component, (2) an organoaluminum catalyst component and (3) an organohalogen catalyst component. The component (1) used is the solid-phase product (VI) which has been obtained by a method in which (1.1) first (1.1.1) an inorganic oxidic substance (I) as a carrier and (1.1.2) a solution (II) of (IIa) a certain oxahydrocarbon and (IIb) a mixture of (IIb1) a vanadium trichloride/alcohol complex and (IIb2) a titanium trihalide or titanium trihalide/alcohol complex and (IIc) a silicon or boron compound are combined with formation of a suspension (III) and the latter is evaporated to form a solid-phase intermediate (IV) and (1.2) then (1.2.1) the intermediate (IV) obtained in (1.1) and (1.2.2) a dissolved organoaluminum compound (V) are combined with formation of a suspension, the solid-phase product (VI) formed as the suspended substance being the transition metal catalyst component (1).

    Abstract translation: 使用由（1）过渡金属催化剂组分，（2）有机铝催化剂组分和（3）有机卤化物催化剂组分组成的齐格勒催化剂体系进行乙烯的均聚和共聚。 所使用的组分（1）是通过以下方法获得的固相产物（VI）：（1.1）第一（1.1.1）作为载体的无机氧化物质（I）和（1.1.2）a （IIa）的某些氧杂烃的溶液（II）和（IIb）（IIb1）三氯化钒/醇络合物和（IIb2）三卤化钛或三卤化钛/醇络合物和（IIc）硅或硼化合物的混合物 （IV）和（1.2）然后（1.2.1）（1.1）和（1.2.2）中得到的中间体（Ⅳ），然后蒸发形成悬浮液（III） 将溶解的有机铝化合物（V）与形成悬浮液组合，形成为作为过渡金属催化剂组分（1）的悬浮物质的固相产物（VI）。

    Catalyst for polymerization of olefins and method for polymerization of olefins
    9.
    发明授权
    Catalyst for polymerization of olefins and method for polymerization of olefins 有权
    烯烃聚合催化剂和烯烃聚合方法

    公开(公告)号：US07704910B2

    公开(公告)日：2010-04-27

    申请号：US11569229

    申请日：2005-05-17

    Applicant: Motoki Hosaka ,  Takefumi Yano ,  Hiroyuki Kono

    Inventor： Motoki Hosaka ,  Takefumi Yano ,  Hiroyuki Kono

    IPC: C08F4/64 ,  C08F4/642 ,  C08F4/647 ,  C08F4/649 ,  B01J31/14

    CPC classification number: C08F10/00 ,  C08F4/6548 ,  C08F4/651 ,  C08F4/6465 ,  C08F2500/04

    Abstract: A catalyst for olefin polymerization comprising (A) a solid catalyst component prepared by causing (a) a magnesium compound, (b) a tetravalent titanium halide compound, and (c) an electron donor compound to come in contact with each other, (B) an organoaluminum compound of the general formula R1pAlQ3-p, and (C) an oligomer of an organosilicon compound of the following chemical formula; R4—(R2R3SiO)m—R5 can produce olefin polymers having higher stereoregularity and a broader molecular weight distribution in a higher yield than conventional catalysts.

    Abstract translation: 一种用于烯烃聚合的催化剂，包括（A）通过使（a）镁化合物，（b）四价卤化钛化合物和（c）电子给体化合物彼此接触而制备的固体催化剂组分，（B ）通式为R1pAlQ3-p的有机铝化合物，（C）下列化学式的有机硅化合物的低聚物; R4-（R2R3SiO）m-R5可以以比常规催化剂更高的产率生产具有较高立构规整性和较宽分子量分布的烯烃聚合物。

Patent Agency Ranking