公开(公告)号：US4450302A

公开(公告)日：1984-05-22

申请号：US406406

申请日：1982-08-09

Applicant: Chester R. Willis

Inventor： Chester R. Willis

IPC: C08K5/00 ,  C07C67/00 ,  C07C407/00 ,  C07C409/00 ,  C07C409/16 ,  C08K5/14 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L101/00 ,  C07C179/06

CPC classification number: C08K5/14

Abstract: Disclosed are novel blends of peroxides that have melting points of about 5.degree. C. and lower. The blends consist essentially of (1) t-butyl cumyl peroxide, (2) bis(.alpha.-t-butylperoxyisopropyl)benzene, and (3) dicumyl peroxide.

Abstract translation: 公开了具有约5℃和更低熔点的过氧化物的新型共混物。 共混物基本上由（1）叔丁基枯基过氧化物，（2）双（α-叔丁基过氧异丙基）苯和（3）过氧化二异丙苯组成。

公开(公告)号：US4243821A

公开(公告)日：1981-01-06

申请号：US75356

申请日：1979-09-13

Applicant: Ronald E. MacLeay ,  Robert T. Kazmierczak

Inventor： Ronald E. MacLeay ,  Robert T. Kazmierczak

IPC: C07C17/08 ,  C07C67/00 ,  C07C407/00 ,  C07C409/16 ,  C08K5/14 ,  C07C179/06

CPC classification number: C07C17/08 ,  C07C407/00 ,  C07C407/003 ,  C07C409/16 ,  C08K5/14

Abstract: An olefin such as .alpha.-methylstyrene or a substituted .alpha.-methylstyrene, wherein the substituent is on the phenyl ring, a t-cumyl halide corresponding to the hydrohalogenated olefin or a substituted t-cumyl chloride and hydrogen peroxide are reacted under relatively non-aqueous conditions, in the absence of a free acid and in the presence of a phenol, to obtain a symmetrical dicumyl (or substituted dicumyl) peroxide which is useful as cross-linking agents for polyethylene and elastomers.

Abstract translation: 诸如α-甲基苯乙烯或取代的α-甲基苯乙烯的烯烃，其中取代基在苯环上，对应于氢卤化烯烃的叔枯基卤化物或取代的叔枯基氯和过氧化氢在相对非水溶液 条件下，在不存在游离酸的情况下和在苯酚存在下，得到对称的二枯基（或取代的二枯基）过氧化物，其可用作聚乙烯和弹性体的交联剂。

公开(公告)号：US4115455A

公开(公告)日：1978-09-19

申请号：US723415

申请日：1976-09-15

Applicant: Wilbur H. McKellin ,  William A. Swarts

Inventor： Wilbur H. McKellin ,  William A. Swarts

IPC: C07B61/00 ,  B01J25/00 ,  C07C67/00 ,  C07C407/00 ,  C07C409/16 ,  C07C409/18 ,  C07C409/20 ,  C08F299/04 ,  C07C179/06

CPC classification number: C08F299/045 ,  C07C409/16 ,  C07C409/18 ,  C07C2101/14

Abstract: A method of producing hydroxy-containing dialkyl peroxides of the formula ##STR1## by either heterogeneously catalytically reducing or homogeneously, non catalytically chemically reducing carbonyl-containing dialkyl peroxides of the formula ##STR2## R, R.sub.1, R.sub.2 and R.sub.3 are aliphatics. This invention also concerns novel hydroxy-containing dialkyl peroxide compounds having the structure of formula I.

Abstract translation: 通过异构催化还原或均匀地，非催化化学还原式（II）R，R 1，R 2的含羰基的二烷基过氧化物和式（Ⅰ）的羟基含二烷基过氧化物的方法， R3是脂肪族。 本发明还涉及具有式I结构的新型羟基二烷基过氧化物。

公开(公告)号：US4043940A

公开(公告)日：1977-08-23

申请号：US596115

申请日：1975-07-15

Applicant: Jose Sanchez

Inventor： Jose Sanchez

IPC: C08F4/00 ,  C07C67/00 ,  C07C407/00 ,  C07C409/00 ,  C07C409/44 ,  C08F2/00 ,  C08F4/28 ,  C08F4/34 ,  C08K5/14 ,  C07C179/06

CPC classification number: C08K5/14 ,  C07C409/44 ,  C08F4/34

Abstract: Storage stable liquid compositions are prepared from solid acyl alkylsulfonyl peroxides and polar or polarizable solvents or solvent mixtures. The compositions are liquid at 0.degree. to -40.degree. C and are useful as free-radical initiators for polymerizaton of vinyl monomers.

Abstract translation: 储存稳定的液体组合物由固体酰基烷基磺酰基过氧化物和极性或极化溶剂或溶剂混合物制备。 组合物在0℃至-40℃下为液体，可用作乙烯基单体聚合的自由基引发剂。

公开(公告)号：US3945940A

公开(公告)日：1976-03-23

申请号：US43329

申请日：1970-06-04

Applicant: Newton G. Leveskis

Inventor： Newton G. Leveskis

IPC: C07C409/00 ,  C07C409/22 ,  C08F283/01 ,  C07C179/06 ,  A61L13/04

CPC classification number: C07C409/22 ,  C07C407/00 ,  C08F283/01

Abstract: Improved organic aldehyde and ketone peroxide compositions useful for initiating the polymerization of polyesters formed from the concurrent reaction of a beta dione such as 2,4-pentanedione and a different (non-beta dione) ketone or aldehyde, for example methyl ethyl ketone, with aqueous hydrogen peroxide.

Abstract translation: 改进的有机醛和酮过氧化物组合物可用于引发由β-二酮如2,4-戊二酮和不同的（非β-二酮）酮或醛（例如甲基乙基酮）的同时反应形成的聚酯聚合， 过氧化氢水溶液。

公开(公告)号：US4413148A

公开(公告)日：1983-11-01

申请号：US349413

申请日：1982-02-16

Applicant: Mitsukuni Kato ,  Takuya Demachi ,  Hidehiko Hagii ,  Takeshi Arai

Inventor： Mitsukuni Kato ,  Takuya Demachi ,  Hidehiko Hagii ,  Takeshi Arai

IPC: C07C67/00 ,  C07C407/00 ,  C07C409/16 ,  C07C179/035 ,  C07C179/06

CPC classification number: C07C409/16 ,  C07C407/00

Abstract: In a process for producing a dicumyl peroxide comprising reacting a cumene hydroperoxide and an .alpha.,.alpha.-dimethylbenzyl alcohol in the presence of an acid catalyst, when a polar solvent exists in the reaction system, the cumene hydroperoxide of the starting material and the dicumyl peroxide of the resulting product are scarcely decomposed.

Abstract translation: 在生产二异丙苯过氧化物的方法中，包括在酸催化剂存在下使氢过氧化枯烯和α，α-二甲基苄醇反应，当反应体系中存在极性溶剂时，起始原料的氢过氧化枯烯和过氧化二异丙苯 所得产物几乎不分解。

公开(公告)号：US4288379A

公开(公告)日：1981-09-08

申请号：US802216

申请日：1977-05-31

Applicant: Duane B. Priddy

Inventor： Duane B. Priddy

IPC: C07C409/22 ,  C08F4/36 ,  C07C179/06

CPC classification number: C07C409/22 ,  C08F4/36

Abstract: The title compounds are useful vinyl polymerization initiators of high thermal stability and correspond to the formula: ##STR1## wherein R is an x-valent hydrocarbon whose chain length can be interrupted by one or more ether linkages, R' is an aliphatic moiety of 1 to about 10 carbon atoms, R" is a tertiary hydrocarbon, and x is an integer of at least 2.

Abstract translation: 标题化合物是具有高热稳定性的有用的乙烯基聚合引发剂，对应于下式：其中R是一个x价烃，其链长可以被一个或多个醚键间隔，R'是1的脂族部分 至约10个碳原子，R“为叔烃，x为至少2的整数。

公开(公告)号：US4198528A

公开(公告)日：1980-04-15

申请号：US872179

申请日：1978-01-25

Applicant: Donald R. Kelsey

Inventor： Donald R. Kelsey

IPC: C07C409/16 ,  C07C179/06

CPC classification number: C07C409/16 ,  C07C407/00

Abstract: The reaction rates for the interaction of tertiary hydroperoxides with tertiary alcohols to afford di-tertiary peroxides are increased by carrying out the reaction in the presence of a carboxylic acid anhydride.

Abstract translation: 通过在羧酸酐存在下进行反应，使叔氢过氧化物与叔醇相互作用产生二叔过氧化物的反应速率增加。

公开(公告)号：US4052464A

公开(公告)日：1977-10-04

申请号：US597792

申请日：1975-07-21

Applicant: Duane B. Priddy

Inventor： Duane B. Priddy

IPC: C07C409/00 ,  C07C409/22 ,  C07C179/06

CPC classification number: C07C407/00 ,  C07C407/003 ,  C07C2101/14

Abstract: Di-t-butylperoxy ketals are prepared from t-butyl hydroperoxide and the appropriate ketone in the presence of from 1 to 10 times the weight of ketone of ethylbenzene employing an acidic catalyst. Water is removed by azeotropic distillation with ethylbenzene and excess t-butyl hydroperoxide is subsequently removed by azeotropic distillation of additional ethylbenzene to provide a solution of the di-t-butylperoxide ketal in ethylbenzene which is particularly desirable as an initiator for styrene polymerization.

公开(公告)号：US3953521A

公开(公告)日：1976-04-27

申请号：US590930

申请日：1975-06-27

Applicant: Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

Inventor： Hideaki Suda ,  Iwao Dohgane ,  Takashi Chinuki ,  Kenji Tanimoto ,  Hirokazu Hosaka ,  Yukimichi Nakao ,  Yuji Ueda ,  Seiya Imada ,  Hideki Yanagihara ,  Kunihiko Tanaka

IPC: C07C409/12 ,  C07C179/06

CPC classification number: C07C409/12 ,  C07C407/00 ,  C07C407/003

Abstract: Meta-and/or paradiisopropylbenzene dihydroperoxides are continuously produced by oxidizing meta-and/or paradiisopropylbenzenes in liquid phase through contact with oxygen or a gas containing oxygen, while keeping the concentration of meta-and/or paradiisopropylbenzene monohydroperoxides of the oxidation product solution in a range of 20 to 40% by weight.

Abstract translation: 通过在与氧气或含氧气体接触的情况下液相氧化间位和/或对二异丙基苯，同时将氧化产物溶液的间 - 和/或对二甲基异丙基苯单氢过氧化物的浓度保持在一定范围内，从而连续制备元和/或对二异丙基苯二氢过氧化物 范围为20〜40重量％。