摘要:
Disclosed are a method of solidifying a low-boiling-point hydrocarbon, wherein the low-boiling-point hydrocarbon (including hydrocarbons which are gaseous at ordinary temperature) is brought into contact with a metal salt of an aliphatic carboxylic acid, and if necessary a high-boiling-point hydrocarbon, suspended in water, to form a solid aggregate substance, a method of handling the low-boiling-point hydrocarbon, wherein the solid aggregate substance is stored or transported, and a method of regenerating the low-boiling-point hydrocarbon, wherein the solid aggregate substance is decomposed by opening or heating, to obtain the low-boiling-point hydrocarbon. According to the methods, a wide variety of gaseous and highly volatile liquid hydrocarbons can be safely and easily solidified without using harmful reagent, and during storage, transportation, etc., the gaseous hydrocarbons and highly volatile liquids can be handled as a solid material. Further, by releasing under atmospheric pressure at room temperature or by heating if necessary, the original hydrocarbons can be easily obtained, and the metal salt of a carboxylic acid can also be repeatedly used.
摘要:
Disclosed are a method of solidifying a low-boiling-point hydrocarbon, wherein the low-boiling-point hydrocarbon (including hydrocarbons which are gaseous at ordinary temperature) is brought into contact with a metal salt of an aliphatic carboxylic acid, and if necessary a high-boiling-point hydrocarbon, suspended in water, to form a solid aggregate substance, a method of handling the low-boiling-point hydrocarbon, wherein the solid aggregate substance is stored or transported, and a method of regenerating the low-boiling-point hydrocarbon, wherein the solid aggregate substance is decomposed by opening or heating, to obtain the low-boiling-point hydrocarbon. According to the methods, a wide variety of gaseous and highly volatile liquid hydrocarbons can be safely and easily solidified without using harmful reagent, and during storage, transportation, etc., the gaseous hydrocarbons and highly volatile liquids can be handled as a solid material. Further, by releasing under atmospheric pressure at room temperature or by heating if necessary, the original hydrocarbons can be easily obtained.
摘要:
Multifunctional liquid phase carriers (LPCs) and methods of using LPCs for the preparation of biopolymers are provided. The LPCs are highly symmetrical compounds that possess more than two points of attachment for biopolymer synthesis. The LPCs have the formula Sp(X1)n, where Sp is a highly symmetrical moiety such that all X1 groups are equivalent. X1 is a functional group that is suitable for biopolymer synthesis, including OH, SH, NH2, COOH and the like. Biopolymers that may be produced using the methods provided include oligonucleotides, peptides, protein nucleic acids (PNAs) and oligosaccharides. Analogs of the biopolymers may also be prepared using the methods.
摘要:
A method for making platform molecules comprising: reacting 4-alkoxy benzoyl chloride with R2-hydroquinone under first conditions effective to produce bis 1,4[4-alkoxy-benzoyloxy]-R2-phenylene comprising bis terminal alkoxy groups wherein R2 is a bulky organic group; and, subjecting the bis 1,4[4-alkoxy-benzoyloxy]-R2-phenylene to second conditions effective to selectively cleave the bis terminal alkoxy groups to produce a solution comprising complexes comprising diphenolic platform molecules comprising bis terminal hydroxyl groups, the second conditions also being effective to precipitate the complexes out of the solution.
摘要:
A crystal substance formed by precipitating as fibrous aggregates by making a metal aliphatic carboxylate dissolve completely in pure water, stirring, and gradually cooling the resulting solution. A method of preparing the fibrous crystal aggregates. A material for recovering flowing oil and method of recovering flowing oil by using the fibrous crystal aggregates. A material for solidifying liquid hydrocarbon, waste tempura oil and edible oil and method of solidifying liquid hydrocarbon, waste tempura oil and edible oil by using the fibrous crystal aggregates. A method of preparing the solidifying material.
摘要:
Process for preparing unsaturated esters by reacting an olefin having an allylic hydrogen atom with an ester forming material in the presence of oxygen and a catalyst selected from the group consisting of mercury, selenium or tellurium. The unsaturated ester may be converted to a polyunsaturated compound by pyrolysis.
摘要:
AROMATIC HYDROCARBONS ARE SEPARATED FROM A MIXTURE OF LIQUID HYDROCARBONS. THE MIXTURE OF LIQUID HYDROCARBONS IS EXTRACTED IN THE LIQUID PHASE IN AN EXTRACTION ZONE AT A TEMPERATURE FROM ABOUT 40*C. TO AOUT 80*C. WITH ETHYLENEDIAINE SOLVENT HAVING A WATER CONTENT OF FROM 00% TO 20% BY WEIGHT TO FORM AN EXTRACTED PHASE AND A RAFFINATE PHASE. THE EXTRACTED PHASE COMPRISES PREDOMINANTLY AROMATIC HYDROCARBONS, SOLVENT AND A MINOR AMOUNT OF NON-AROMATIC HYDROCARBONS. THE RAFFINATE PHASE COMPRISES PREDOMINANTLY NON-AROMATIC HYDROCARBONS. THE EXTRACTED PHASE AND THE RAFFINATE PHASE ARE SEPARATELY COLLECTED. THE EXTRACTED PHASE IS COLLED TO A TEMPERATURE AT LEAST 300*C. LOWER THAN THE TEMPERATURE OF THE EXTRACTION STEP AND THEN SEPARATED INTO A HEAVIER SOLVENT CONTAINING PHASE AND ALIGHTER HYDROCARONS CONTAINING PHASE. THE NON-AROMATIC HYDROCARBONS IN THE LIGHTER HYDROCARBONS CONTAINING PHASE ARE SEPARATED A OVERHEAD PRODUCT BY MEANS OF EXTRACTIVE STRIPPING AT ATMOSPHERIC PRESSURE. THE AROMATIC HYDROCARBONS REMAIN IN THE RESIDUE OF THE EXTRACTIVE STRIPPING WHICH IS THEN SCRUBBED WITH WATER TO THEREBY OBTAIN AN AROMATIC HYDROCARBONS PHASE AND AN AQUEOUS ETHYLENEDIAMINE CONTAINING PHASE. THE AROMATIC HYDROCARBONS PHASE IS THEN RECTIFIED.