摘要:
The invention relates to a process for the production of cellulosic moulded bodies in the form of flat or tubular films and cellulosic membranes in the form of flat or tubular films whereby a solution of cellulose in an aqueous tertiary amine oxide is extruded using an extrusion nozzle whereby the solution can as the case may be also contain additives such as stabilizing and softening agents, pore formers and so on whereby a moulded solution results which has two surfaces and the extruded moulded solution is led over a gap into a precipitation bath and drawn off from the precipitation bath. The process in accordance with the invention is characterized in that the two surfaces of the moulded solution in the gap are each exposed to at least one gaseous medium whereby the medium to which the first surface is exposed differs from the medium to which the second surface is exposed in composition, properties and/or the state of motion.
摘要:
This invention relates to a process for forming a single-layer, durably wettable polymeric web having a plurality of apertures. This process comprises melting a mixture of at least one thermoplastic polymer and at least one migratable surfactant and extruding the mixture to form a single-layer, substantially continuous polymeric film. The film is then apertured using high pressure fluid flows. Aperture formation is conducted when the single-layer polymeric film has a contact angle of at least about 30.degree., to minimize wash-off of the surfactant impregnated in the polymer web. The invention also relates to durably-wettable apertured webs.
摘要:
A synthetic hydrophilic membrane, and method for manufacturing thereof, in the form of hollow fibers or flat membranes for dialysis and/or ultrafiltration, containing a mixture of polysulfone and sulfonated polysulfone, the mixture containing 65 to 95 wt.% sulfonated polysulfone, possibly as a salt of sulfonic acid, and 35 to 5 wt.% unsulfonated polysulfone. Preferably, up to 12 wt.% water-soluble polymers, based on the total mixture, are added to the mixture of polysulfone and sulfonated polysulfone before formation of the membrane.
摘要:
Halogen-substitutable hydrogen atoms are linked to nitrogen atoms of a polymer, with ethylenically-unsaturated monomers. By using inorganic or organic hypohalogenites and/or organic N-halogen derivatives as halogenation means, hydrogen atoms on the nitrogen atoms of the polymer membranes or polymer formed materials are replaced by halogen atoms and part of these are removed by reducing agents in the presence of ethylenically unsaturated monomers, with radical grafting of these on to the nitrogen atoms, after which the remaining halogen atoms are removed by reducing agents in the absence of monomers.
摘要:
A composite structure, particularly a filter structure, is provided comprising a support having a surface and a porous membrane formed integrally to the surface of the support. The support preferably includes means for directing a fluid away from the surface of the support. The support surface is at least slightly soluble in a solvent. The porous membrane comprises a resin soluble in the solvent and precipitated while the casting solution is in contact with a porous substrate and the surface of the support. The membrane is formed and integrally secured to the surface of the support contemporaneously.
摘要:
A composite membrane and process utilizing the membrane which is capable of selectively removing particles such as viral particles from a solution such as a protein solution is provided. The membrane comprises a porous membrane substrate, a surface skin having ultrafiltration separation properties and an intermediate porous zone between the substrate and the skin which intermediate zone has an average pore size smaller than that of the substrate. The intermediate zone is free of voids which break the skin and which directly fluid communicate with the substrate. The composite is capable of a log reduction value of at least 3 (99.9% removal) of particles selectively from solution.
摘要:
A method of manufacturing an integral asymmetrical membrane for the separation of liquid or gaseous mixtures. A membrane-forming agent in the form of a polyetherimide is mixed with a solvent that is miscible with water. The resulting mixture is introduced into or accommodated in a geometrical form. The form is then brought into contact with a precipitating agent.
摘要:
A filter for separating solid particles, whose diameters are generally smaller than 5 .mu.m, from flowing gases or liquids. A covering layer with columnar and/or platelet-shaped oxides is formed on a body consisting of porous steel foil at least in and around the pores.
摘要:
An anisotropic elastomeric membrane preferably made from polyurea/urethane has been prepared. These anisotropic membranes are made from the corresponding polymeric material by preparing the polymeric material in a good solvent containing less than 5 vol % non-solvent, producing a film of the polymer solution on a support with a maximum pore size less than 20 microns, subjecting the film to conditions such that the solvent vapor pressure-time factor is 1000 mm Hg-min. or less, preferably 200 mm Hg-min or less, most preferably approaching 0 mm Hg-min and quenching the membrane film in a non-solvent yielding a three-layered anisotropic membrane.
摘要:
An expandable vinyl chloride resin composition for foaming under atmospheric pressure which comprises a resin ingredient comprising (A) a vinyl chloride homopolymer or copolymer having substantially no active hydrogens, (B) a vinyl chloride copolymer having active hydrogens and (C) a thermoplastic polyurethane resin, and a crosslinking agent, a foaming agent, a thermal stabilizer and a plasticizer, the ratio of the components (A), (B) and (C) being 30 to 90:5 to 40:5 to 40 by weight. The composition is expanded under atmospheric pressure to give a foam of a high expansion ratio which has uniform and fine cells and shows an excellent rubber-like elasticity.