摘要:
The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 100 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; and admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and neutralized sulfonated polymer transferring from the organic liquid to the water phase, thereby causing the water phase to thicken.
摘要:
A silicone-coated article having releasability imparted thereto by the coating of a silicone, wherein that surface of said article on which to coat the silicone is composed of a resin consisting of a polar group-containing olefinic resin comprising (a) 55 to 99% by weight of a unit derived from an olefin and (b) 1 to 45% by weight of a unit derived from a radical-polymerizable monomer containing a polar group selected from the class consisting of ##STR1## in which R.sub.1 represents a hydrogen atom, a metal capable of forming a salt with the carboxyl group, or a monovalent hydrocarbon group, and R.sub.2 represents a monovalent hydrocarbon group; and a method for the production thereof.
摘要:
The present invention relates to an improved process for forming fibers for fabrics from neutralized sulfonated thermoplastic polymers, and novel ionic polymer fiber compositions derived therefrom, wherein the neutralized sulfonated thermoplastic polymer is dissolved in a solvent, preferably a mixed solvent, consisting of a backbone solvent and a polar cosolvent and spun into fibers. The neutralized sulfonated thermoplastic polymer has about 10 to about 100 meq. SO.sub.3 H per 100 grams of sulfonated thermoplastic polymer, of which at least 95% is neutralized with a cation being selected from the group consisting essentially of antimony, iron, lead, aluminum, or Groups I-A, II-A, I-B or II-B of the Periodic Table of Elements and mixture thereof. The solution of the neutralized sulfonated thermoplastic polymer having a Brookfield viscosity at room temperature at about 6 rpm of about 1,000 to about 200,000 cps is fabricated into fibers by wet or dry spinning through a spinner having a plurality of orifices therein. The resultant fibers exhibit improved dimensional stability and resistance to solvents and temperature when fabricated into a fabric.
摘要翻译:本发明涉及一种用于从中和磺化热塑性聚合物形成织物纤维的改进方法和由其衍生的新型离子聚合物纤维组合物,其中中和的磺化热塑性聚合物溶解在溶剂中,优选由主要溶剂组成的混合溶剂 和极性助溶剂并纺成纤维。 中和的磺化热塑性聚合物具有约10至约100meq。 SO 3 H / 100克磺化热塑性聚合物,其中至少95%被阳离子中和,阳离子主要由锑,铁,铅,铝或IA,II-A,IB或II-B族组成 元素周期表及其混合物。 通过湿法或干纺法通过其中具有多个孔的旋转器将具有Brookfield粘度的Brookfield粘度的中和磺化热塑性聚合物溶液在大约6rpm的约1000至约200,000cps下制成纤维。 当制成织物时,所得纤维表现出改进的尺寸稳定性和耐溶剂性和耐温度。
摘要:
This invention relates to a polymeric composition suitable for greenhouse film applications, and greenhouse films made therefrom. The polymeric composition suitable for greenhouse film applications according to the present invention comprises a) 50 to 99 percent by weight of a continuous polymeric phase comprising a polymer selected from the group consisting of a polyolefin, a polyolefin copolymer, an ethylene propylene copolymer with an acrylic ester, an ethylene or propylene copolymer with a vinyl acetate, and combinations thereof; and b) 1 to 50 percent by weight of polymeric particles having an average particle diameter of 0.5 to 10 μm; a refractive index from 1.474 to 1.545; an average particle hardness from 1.2367E+10 N/m2 to 8.4617E+10 N/m2; and at least 60% polymerized acrylic monomer units.
摘要:
An example starch-based material for forming a biodegradable component includes a mixture of a starch and an expansion additive. The starch has an amylose content of less than about 70% by weight. The expansion additive enhances the expansion and physical properties of the starch. A method of preparing a starch-based material is also disclosed and an alternate starch-based material for forming a biodegradable component is also disclosed.
摘要:
The present invention relates to a process for the gelation (i.e. thickening) of an aqueous acid solution which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 100 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; and admixing or contacting said solution with about 5 to about 500 volume percent of the aqueous acid solution, the aqueous acid solution being immiscible with the organic liquid and the polar cosolvent and neutralized sulfonated polymer transferring from the organic liquid to the aqueous acid phase, thereby causing the aqueous acid phase to thicken (i.e. interfacial viscosification).
摘要:
The instant invention relates to a process for controlling the viscosity of organic liquids by incorporating in said liquid a minor amount of an ionic polymer, and a cosolvent for the ionic groups of said polymer. The ionic polymer comprises a backbone which is substantially soluble in said organic liquid, and pendant ionic groups which are substantially insoluble in said organic liquid. A cosolvent is selected which will solubilize the pendant ionomeric groups and provide a reasonably homogeneous mixture of solvent, cosolvent and ionomeric polymer. The preferred compositions prepared by the method of the instant invention comprise an organic liquid having a solubility parameter of from 6 to 10.5 in combination with a sulfonated polymer containing from 0.2 up to 10.0 mole % ionic groups which has been neutralized by a basic material selected from Groups IA and IIA, IB and IIB of the Periodic Table of the Elements (and also lead, tin and antimony) and a nonvolatile alcohol or amine cosolvent.
摘要:
The present invention relates to a process for the gelation (i.e. thickening) of salt water which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 100 cps; dissolving a nonionic surfactant and water insoluble, neutralized or unneutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized, or unneutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, the concentration of the nonionic surfactant in the solvent system being about 0.0001 to about 1.0 weight percent, a viscosity of the solution being less than about 2,000 cps; and admixing or contacting said solution with about 5 to about 500 volume precent of salt water, the salt water being immiscible with the organic liquid and the polar cosolvent, nonionic surfactant and the water insoluble, neutralized or unneutralized sulfonated polymer transferring from the organic liquid to the salt water phase, thereby causing the salt water phase to gel.