Interfacial viscosification of aqueous system utilizing sulfonated
ionomers
    1.
    发明授权
    Interfacial viscosification of aqueous system utilizing sulfonated ionomers 失效
    使用磺化离聚物的水性体系的界面粘度

    公开(公告)号:US4465801A

    公开(公告)日:1984-08-14

    申请号:US374197

    申请日:1982-05-03

    摘要: The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 100 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; and admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and neutralized sulfonated polymer transferring from the organic liquid to the water phase, thereby causing the water phase to thicken.

    摘要翻译: 本发明涉及一种水性液体的增稠方法,其包括形成有机液体或油和极性助溶剂的溶剂体系的步骤,极性助溶剂小于溶剂体系的约15重量%, 溶剂体系的粘度小于约100cps; 将中和的磺化聚合物溶解在溶剂体系中以形成溶液,溶液中中和的磺化聚合物的浓度为约0.01至约0.5重量%,溶液的粘度小于约200cps; 并且将所述溶液与约5至约500体积%的水混合或接触,所述水与有机液体和极性助溶剂不混溶,并且中和的磺化聚合物从有机液体转移到水相,从而使水相变稠。

    Silicone-coated article and process for production thereof
    2.
    发明授权
    Silicone-coated article and process for production thereof 失效
    有机硅涂层制品及其生产方法

    公开(公告)号:US4288497A

    公开(公告)日:1981-09-08

    申请号:US111674

    申请日:1980-01-14

    摘要: A silicone-coated article having releasability imparted thereto by the coating of a silicone, wherein that surface of said article on which to coat the silicone is composed of a resin consisting of a polar group-containing olefinic resin comprising (a) 55 to 99% by weight of a unit derived from an olefin and (b) 1 to 45% by weight of a unit derived from a radical-polymerizable monomer containing a polar group selected from the class consisting of ##STR1## in which R.sub.1 represents a hydrogen atom, a metal capable of forming a salt with the carboxyl group, or a monovalent hydrocarbon group, and R.sub.2 represents a monovalent hydrocarbon group; and a method for the production thereof.

    摘要翻译: 一种具有通过涂覆硅氧烷赋予其释放性的硅氧烷涂层制品,其中涂覆有机硅的所述制品的表面由包含(a)含有极性基团的烯烃树脂的树脂组成,所述树脂包含(a)55-99% (b)1〜45重量%的衍生自含有极性基团的自由基聚合性单体的单元,其中R 1表示氢原子,其中R 1表示氢原子, 能够与羧基形成盐的金属或一价烃基,R 2表示一价烃基; 及其制造方法。

    Fibers of ionic thermoplastic polymers
    3.
    发明授权
    Fibers of ionic thermoplastic polymers 失效
    离子热塑性聚合物纤维

    公开(公告)号:US4226751A

    公开(公告)日:1980-10-07

    申请号:US12118

    申请日:1979-02-14

    摘要: The present invention relates to an improved process for forming fibers for fabrics from neutralized sulfonated thermoplastic polymers, and novel ionic polymer fiber compositions derived therefrom, wherein the neutralized sulfonated thermoplastic polymer is dissolved in a solvent, preferably a mixed solvent, consisting of a backbone solvent and a polar cosolvent and spun into fibers. The neutralized sulfonated thermoplastic polymer has about 10 to about 100 meq. SO.sub.3 H per 100 grams of sulfonated thermoplastic polymer, of which at least 95% is neutralized with a cation being selected from the group consisting essentially of antimony, iron, lead, aluminum, or Groups I-A, II-A, I-B or II-B of the Periodic Table of Elements and mixture thereof. The solution of the neutralized sulfonated thermoplastic polymer having a Brookfield viscosity at room temperature at about 6 rpm of about 1,000 to about 200,000 cps is fabricated into fibers by wet or dry spinning through a spinner having a plurality of orifices therein. The resultant fibers exhibit improved dimensional stability and resistance to solvents and temperature when fabricated into a fabric.

    摘要翻译: 本发明涉及一种用于从中和磺化热塑性聚合物形成织物纤维的改进方法和由其衍生的新型离子聚合物纤维组合物,其中中和的磺化热塑性聚合物溶解在溶剂中,优选由主要溶剂组成的混合溶剂 和极性助溶剂并纺成纤维。 中和的磺化热塑性聚合物具有约10至约100meq。 SO 3 H / 100克磺化热塑性聚合物,其中至少95%被阳离子中和,阳离子主要由锑,铁,铅,铝或IA,II-A,IB或II-B族组成 元素周期表及其混合物。 通过湿法或干纺法通过其中具有多个孔的旋转器将具有Brookfield粘度的Brookfield粘度的中和磺化热塑性聚合物溶液在大约6rpm的约1000至约200,000cps下制成纤维。 当制成织物时,所得纤维表现出改进的尺寸稳定性和耐溶剂性和耐温度。

    Interfacial viscosification of aqueous acid systems utilizing sulfonated
ionomers
    7.
    发明授权
    Interfacial viscosification of aqueous acid systems utilizing sulfonated ionomers 失效
    使用磺化离聚物的含水酸性体系的界面粘度

    公开(公告)号:US4426473A

    公开(公告)日:1984-01-17

    申请号:US374198

    申请日:1982-05-03

    摘要: The present invention relates to a process for the gelation (i.e. thickening) of an aqueous acid solution which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 100 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; and admixing or contacting said solution with about 5 to about 500 volume percent of the aqueous acid solution, the aqueous acid solution being immiscible with the organic liquid and the polar cosolvent and neutralized sulfonated polymer transferring from the organic liquid to the aqueous acid phase, thereby causing the aqueous acid phase to thicken (i.e. interfacial viscosification).

    摘要翻译: 本发明涉及一种酸性水溶液凝胶化(即增稠)的方法,其包括形成有机液体或油和极性助溶剂的溶剂体系的步骤,极性助溶剂小于约15重量% 溶剂系统,溶剂体系的粘度小于约100cps; 将中和的磺化聚合物溶解在溶剂体系中以形成溶液,溶液中中和的磺化聚合物的浓度为约0.01至约0.5重量%,溶液的粘度小于约200cps; 并将所述溶液与约5至约500体积%的酸水溶液混合或接触,酸性水溶液与有机液体和极性助溶剂不混溶,并将中和的磺化聚合物从有机液体转移到含水酸相,由此 导致含水酸相增稠(即界面粘稠化)。

    Interfacial viscosification of salt water systems utilizing sulfonated
ionomers
    10.
    发明授权
    Interfacial viscosification of salt water systems utilizing sulfonated ionomers 失效
    使用磺化离聚物的盐水系统的界面粘度

    公开(公告)号:US4427812A

    公开(公告)日:1984-01-24

    申请号:US374251

    申请日:1982-05-03

    摘要: The present invention relates to a process for the gelation (i.e. thickening) of salt water which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 100 cps; dissolving a nonionic surfactant and water insoluble, neutralized or unneutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized, or unneutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, the concentration of the nonionic surfactant in the solvent system being about 0.0001 to about 1.0 weight percent, a viscosity of the solution being less than about 2,000 cps; and admixing or contacting said solution with about 5 to about 500 volume precent of salt water, the salt water being immiscible with the organic liquid and the polar cosolvent, nonionic surfactant and the water insoluble, neutralized or unneutralized sulfonated polymer transferring from the organic liquid to the salt water phase, thereby causing the salt water phase to gel.

    摘要翻译: 本发明涉及一种盐水凝胶化(即增稠)的方法,其包括形成有机液体或油和极性助溶剂的溶剂体系的步骤,极性助溶剂小于溶剂的约15重量% 系统,溶剂系统的粘度小于约100cps; 将非离子表面活性剂和水不溶性,中和或未中和的磺化聚合物溶解在溶剂体系中以形成溶液,溶液中的中和或未中和的磺化聚合物的浓度为约0.01至约0.5重量%,非离子表面活性剂 在溶剂体系中为约0.0001至约1.0重量%,溶液的粘度小于约2,000cps; 并且将所述溶液与约5至约500体积的盐水混合或接触,所述盐水与有机液体和极性助溶剂,非离子表面活性剂和水不溶性,中和或未中和磺化聚合物不混溶,从有机液体转移到 盐水相,从而使盐水相凝胶化。