公开(公告)号：US10017590B2

公开(公告)日：2018-07-10

申请号：US15557011

申请日：2016-03-07

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Alessandro Mignogna ,  Giampiero Morini ,  Reynald Chevalier

IPC: C08F4/649 ,  C08F4/651 ,  C08F4/654 ,  C08F4/655 ,  C08F110/06 ,  C08F4/645

CPC classification number: C08F110/06 ,  C08F4/6455 ,  C08F4/6457 ,  C08F4/649 ,  C08F4/6495 ,  C08F4/6498 ,  C08F2410/01 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6543

Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti, halogen and an electron donor of formula (I) or (II) When activated with an aluminum alkyl and optionally an external electron donor, solid catalyst component can give high activity and stereospecificity in the polymerization of olefins.

公开(公告)号：US20180066089A1

公开(公告)日：2018-03-08

申请号：US15807665

申请日：2017-11-09

Applicant: Chevron Phillips Chemical Company LP

Inventor： Kensha Marie Clark ,  Qing Yang ,  Gary L. Glass

IPC: C08F210/16 ,  C08F4/649

CPC classification number: C08F210/16 ,  C08F4/649 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F110/02 ,  C08F10/02 ,  C08F2/06 ,  C08F210/14 ,  C08F2500/15 ,  C08F2500/26

Abstract: Methods for preparing metallocene-based catalyst systems containing an activator-support are disclosed. These methods are directed to contacting an activator-support, an organoaluminum compound, and a mixture containing a metallocene compound and cyclohexene or a mixture of cyclohexane and 1-hexene, resulting in catalyst systems with increased catalytic activity for the polymerization of olefins. The olefin polymers can be used to produce film products with high haze values.

公开(公告)号：US09670293B2

公开(公告)日：2017-06-06

申请号：US14914501

申请日：2014-10-22

Applicant: BOREALIS AG

Inventor： Alexander Reznichenko ,  Noureddine Ajellal ,  Pascal Castro ,  Irfan Saeed

IPC: C08F4/649 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/659

CPC classification number: C08F10/00 ,  C08F4/649 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F2410/01 ,  C08F10/06 ,  C08F110/06 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/14 ,  C08F110/02 ,  C08F2500/01

Abstract: Process for the preparation of a solid catalyst system comprising the steps of preparing a liquid clathrate comprising a mixing of an aluminoxane, an aromatic compound and an organo-silicon compound, wherein the mol-ratio between the organo-silicon compound and aluminum of the aluminoxane is below 0.1, mixing said liquid clathrate with an organometallic compound obtaining a liquid mixture, and precipitating the solid catalyst system out of said liquid mixture by adding a saturated aliphatic compound to said mixture liquid.

公开(公告)号：US09481749B1

公开(公告)日：2016-11-01

申请号：US14751226

申请日：2015-06-26

Applicant: Chevron Phillips Chemical Company LP

Inventor： Kensha Marie Clark ,  Qing Yang ,  Gary L. Glass

IPC: C08F4/6592 ,  C08F210/16 ,  C08F4/659

CPC classification number: C08F210/16 ,  C08F4/649 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F110/02 ,  C08F4/65925 ,  C08F4/65927

Abstract: Methods for preparing metallocene-based catalyst systems containing an activator-support are disclosed. These methods are directed to contacting an activator-support, an organoaluminum compound, and a mixture containing a metallocene compound and cyclohexene or a mixture of cyclohexane and 1-hexene, resulting in catalyst systems with increased catalytic activity for the polymerization of olefins.

Abstract translation: 公开了制备含有活化剂 - 载体的茂金属系催化剂体系的方法。 这些方法涉及使活化剂 - 载体，有机铝化合物和含有茂金属化合物和环己烯或环己烷和1-己烯的混合物的混合物接触，导致催化剂体系具有增加的烯烃聚合催化活性。

公开(公告)号：US3081287A

公开(公告)日：1963-03-12

申请号：US72491658

申请日：1958-03-31

Applicant: EASTMAN KODAK CO

Inventor： HARRY WESLEY JR COOVER ,  NEWTON HENRY SHEARER

IPC: C08F4/16 ,  C08F4/629 ,  C08F4/64 ,  C08F10/00 ,  C08F12/08 ,  C08F36/04 ,  C08F110/06 ,  C08F110/14 ,  C08G79/14

CPC classification number: C08G79/14 ,  C08F10/00 ,  C08F12/08 ,  C08F36/04 ,  C08F110/06 ,  C08F110/14 ,  C08F4/629 ,  C08F4/6498 ,  C08F4/6495 ,  C08F4/6297 ,  C08F4/6497 ,  C08F4/6295 ,  C08F2500/26 ,  C08F4/68 ,  C08F4/69 ,  C08F4/695 ,  C08F4/649

公开(公告)号：US3018278A

公开(公告)日：1962-01-23

申请号：US72491958

申请日：1958-03-31

Applicant: EASTMAN KODAK CO

Inventor： SHEARER JR NEWTON H ,  COOVER JR HARRY W

IPC: C08F4/16 ,  C08F4/629 ,  C08F4/64 ,  C08F10/00 ,  C08F12/08 ,  C08F36/04 ,  C08F110/06 ,  C08F110/14 ,  C08G79/14

CPC classification number: C08G79/14 ,  C08F10/00 ,  C08F12/08 ,  C08F36/04 ,  C08F110/06 ,  C08F110/14 ,  C08F4/629 ,  C08F4/6498 ,  C08F4/6495 ,  C08F4/6297 ,  C08F4/6497 ,  C08F4/6295 ,  C08F2500/26 ,  C08F4/68 ,  C08F4/69 ,  C08F4/695 ,  C08F4/649

公开(公告)号：US2973348A

公开(公告)日：1961-02-28

申请号：US72492158

申请日：1958-03-31

Applicant: EASTMAN KODAK CO

Inventor： COOVER JR HARRY W ,  JOYNER FREDERICK B

IPC: C08F4/16 ,  C08F4/629 ,  C08F4/64 ,  C08F10/00 ,  C08F12/08 ,  C08F36/04 ,  C08F110/06 ,  C08F110/14 ,  C08G79/14

CPC classification number: C08G79/14 ,  C08F10/00 ,  C08F12/08 ,  C08F36/04 ,  C08F110/06 ,  C08F110/14 ,  C08F4/629 ,  C08F4/6498 ,  C08F4/6495 ,  C08F4/6297 ,  C08F4/6497 ,  C08F4/6295 ,  C08F2500/26 ,  C08F4/68 ,  C08F4/69 ,  C08F4/695 ,  C08F4/649

公开(公告)号：US20190211116A1

公开(公告)日：2019-07-11

申请号：US16335910

申请日：2017-10-25

Applicant: Yingkou Xiangyang Catalyst Co., Ltd. ,  Dalian University of Technology

Inventor： Licai Wang ,  Zhanxian Gao ,  Qinghai Sun ,  Limei Yu ,  Huan Wang ,  Wei Li ,  Guotong Zheng ,  Qingxin Dong ,  Yongqiang Wang ,  Wenwei Wang ,  Zhe Yuan ,  Yang Li

IPC: C08F4/642 ,  C08F2/38 ,  C08F210/02 ,  C08F210/06 ,  C08F210/08 ,  C08F4/649 ,  C08F4/659 ,  C08F2/34

CPC classification number: C08F4/6421 ,  C08F2/34 ,  C08F2/38 ,  C08F4/642 ,  C08F4/649 ,  C08F4/6494 ,  C08F4/654 ,  C08F4/65916 ,  C08F10/06 ,  C08F10/08 ,  C08F210/02 ,  C08F210/06 ,  C08F210/08

Abstract: Disclosed are a Z-N catalyst for α-olefin polymerization and an application thereof, specifically, an industrial production catalyst consisting of (A) a solid catalyst component, (B) a cocatalyst organoaluminum compound and (C) an external electron donor compound and used for α-olefin polymerization or copolymerization processes. The catalyst component is prepared from a transition metal such as titanium and magnesium and a composite aromatic diacid diester/1,3-diether as an internal electron donor. One or more organoaluminum compounds or a mixture thereof serve as the cocatalyst. One or more structure control agent hydrocarbyl alkoxysilicons are compounded with one or more activity regulator organic acid esters as the external electron donor capable of automatically adjusting the polymerization rate. The Z-N catalyst is used for α-olefin polymerization/copolymerization, and can automatically adjust the polymerization rate at a higher polymerization temperature so as to maintain stable operation of a reactor.

公开(公告)号：US09914793B2

公开(公告)日：2018-03-13

申请号：US14967704

申请日：2015-12-14

Applicant: NOVA Chemicals (International) S.A.

Inventor： Qinyan Wang ,  Tyler Craig ,  Savina Udara Suduweli Kondage ,  Bradley Wade Funk

IPC: C08F4/02 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/649 ,  C08F4/659

CPC classification number: C08F210/16 ,  C08F4/022 ,  C08F4/649 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F2420/04 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/06

Abstract: A solid, spheroidal polymerization catalyst having a particle size distribution characterized by a Dm*/Dn of less than 3.0, the catalyst comprising a phosphinimine catalyst, a cocatalyst and a magnesium chloride support. A process for the polymerization of ethylene with one or more alpha olefin catalyzed by a solid, spheroidal polymerization catalyst having a particle size distribution characterized by a Dm*/Dn of less than 3.0, the catalyst comprising a phosphinimine catalyst, a cocatalyst and a magnesium chloride support.

公开(公告)号：US20180037676A1

公开(公告)日：2018-02-08

申请号：US15552658

申请日：2016-06-10

Applicant: LG CHEM, LTD.

Inventor： Eun Kyoung SONG ,  Yong Ho LEE ,  Kyung Jin CHO ,  Yi Young CHOI ,  Ki Soo LEE ,  Heon Yong KWON ,  Young Suk YOU

IPC: C08F4/6192 ,  C08F4/659 ,  C08F4/649 ,  C08F10/00 ,  C08F4/02

CPC classification number: C08F4/61922 ,  C08F4/02 ,  C08F4/649 ,  C08F4/659 ,  C08F4/65912 ,  C08F10/00 ,  C08F2410/01 ,  C08F2410/03 ,  C08F2420/02 ,  C08F2500/04 ,  C08F210/16 ,  C08F4/65925 ,  C08F4/65916 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/01 ,  C08F2500/05 ,  C08F2500/02 ,  C08F4/65904 ,  C08F2/06

Abstract: The present invention provides a method for preparing a polyolefin having a broad molecular weight distribution. More specifically, the present invention provides a method for preparing a polyolefin having a broad molecular weight distribution and an ultra-high molecular weight in which an organometallic complex containing a specific Ti—Al complex structure is used as a molecular weight controller (i.e., molecular weight enhance) in the polymerization of an olefin monomer, thereby enabling both solution polymerization and slurry polymerization, particularly enabling the molecular weight distribution to be more readily and effectively controlled.