Abstract:
The invention relates to a process for the production of polypropylene with a propane-dehydrogenation stage and a polymerization stage, whereby a degassing stream is obtained, characterized in that the degassing stream is used as a feedstock stream for the propane-dehydrogenation stage.
Abstract:
A single-site olefin polymerization catalyst is described. The catalyst comprises an activator and an organometallic compound that includes an amine derivative ligand. The catalyst is highly productive, incorporates comonomers well, and gives polymers with narrow molecular weight distributions.
Abstract:
The invention relates to a process for the polymerization and co-polymerization of olefins, which comprises polymerizing/copolymerizing olefins in presence of a solvent, a supported metallocene catalyst and an aluminoxane as cocatalyst in a hydrocarbon medium, at a temperature in the range of 50 to 150.degree. C., at a pressure ranging between 1 to 20 bar, for a period of 10 minutes to 10 hours, scavenging the reaction mixture by addition of an organoaluminum compound to remove the last traces of impurities of solvent, separating the polymer by conventional method like, washing the polymer with an organic solvent and drying the polymer to remove the solvent to obtain the product.
Abstract:
Olefin polymerization is performed in the presence of a catalyst comprising a compound of the formula wherein M is a Group 3-10 transition metal; A is O, S, N—R″, or P—R″; L is an anionic ligand; X is hydride, halide, C1-C20 alkoxy, siloxy, hydrocarbyl, or dialkylamido; R, R′, and R″, which are the same or different, are selected from the group consisting of hydrogen and C1-C20 hydrocarbyl; and m+n equals the valency of M minus 1; and an activator.
Abstract:
A PROCESS FOR PREPARING AN ALTERNATING COPOLYMER OF BUTADIENE AND A-OLEFINE HAVING THE FORMULA O CH2=CHR, WHEREIN R REPRESENTS PHENYL OR A NORMAL OR BRANCHED CHAIN LOWER ALKYL RADICAL, WHICH COMPRISES CONTACTING BUTADIENE AND THE A-OLEFINE IN LIQUID PHASE WITH A CATALYST SYSTEM OF AN ORGANOALUMINUM COMPOUND, A VANADIUM COMPOUND HAVING V-X LINKAGE (X IS HALOGEN) AND A COMPOUND HAVING M-OR LINKAGE (M IS AN ATOM WHOSE ELECTRO NEGATIVITY (H. O. PRITCHARD, CHEM, REV., 55, 745 (1955)) IS LOWER THAN 2.2 AND R IS A HYDROCARBON RADICAL O ALKYL, ARYL, CYCLOALKYL KOR HALOGENATED ETHER RADICAL) OR A COMPOUND HAVING (O-M)X-(0-M'')Y-OR LINKAGE (M IS DEFINED AS ABOVE AND M'' CAN BE DEFINED BY THE SAME DEFINITION GIVEN IN M). OPTIONALLY A HALOGEN ATOM, A HALOGEN CONTAINING COMPOUND, A METAL OXIDE OR A METALLOID OXIDE CAN BE ADDED TO THE ABOVE MENTIONED THREE COMPONENT CATAYAST SYSTEM AS THE FOURTH COMPONENT TO FURTHER IMPROVE THE CATALYTIC PROPERTIES. THE ALTERNATING COPOLYMERS OBTAINED BY THIS INVENTION ARE RUBBER-LIKE IN CHARACTER AND CAN BE USED AS POLYMERIC PLASTICIZERS IN ADHESIVES AND CAN BE VULCANIZED WITH SULFUR OR A SULFUR COMPOUND TO PRODUCE VULCANIZED ELASTOMERS.
Abstract:
THIS INVENTION IS CONCERNED WITH THE POLYMERIZATION OF BUTADIENCE IN AN INERT LIQUID HYDROCARBON IN THE PRESENCE OF 0.5 TO 20% BY WEIGHT OF BUTADIECE OF A CATALYST COMPRISING TICL4 AND ALR''R"R"''.
Abstract:
The present invention relates to a catalyst composition containing: one or more selected from the group consisting of a transition metal compound represented by Formula 1 and a transition metal compound represented by Formula 3, and dialkyl L-tartrate; a cleaning liquid composition containing the catalyst composition; and a method of cleaning a polymerization apparatus using the cleaning liquid composition,
Abstract:
Methods for producing aluminum hydride are provided herein. Exemplary methods may include combining an amount of aluminum with an amount of a metal in such a way that a eutectic mixture is formed and treating the eutectic mixture with hydrogen gas to produce aluminum hydride. Various methods and processes are conducted under anhydrous conditions or within anhydrous systems.