公开(公告)号：US20240034855A1

公开(公告)日：2024-02-01

申请号：US18245796

申请日：2021-08-11

Applicant: Evonik Operations GmbH

Inventor： Verena BREUERS ,  Daniel Neß ,  Stephan Wieber ,  Valeri Leich ,  Jonas Hönig ,  Michael Gerhard Hagemann ,  Willibald Wombacher ,  Christian Däschlein

IPC: C08K3/04 ,  C08F267/06 ,  C08F279/06 ,  C08F220/14 ,  C08F220/34 ,  C08F220/18 ,  C08F220/56 ,  C08F212/08 ,  C08K5/5419 ,  C08K5/544 ,  C08K5/5435 ,  C10M125/02 ,  C10M139/04 ,  C10M145/14 ,  C10M143/12 ,  C10M169/04

CPC classification number: C08K3/042 ,  C08F267/06 ,  C08F279/06 ,  C08F220/14 ,  C08F220/34 ,  C08F220/1804 ,  C08F220/56 ,  C08F220/1812 ,  C08F212/08 ,  C08K5/5419 ,  C08K5/544 ,  C08K5/5435 ,  C10M125/02 ,  C10M139/04 ,  C10M145/14 ,  C10M143/12 ,  C10M169/04 ,  C08K2201/011 ,  C08K2201/006 ,  C10M2201/041 ,  C10M2227/04 ,  C10M2209/084 ,  C10M2205/06 ,  C10N2020/04

Abstract: Nanoparticle compositions contain a graphene-based material. A preparation process involves providing several components and milling a mixture. The nanoparticle compositions can be used as a lubricant additive to improve tribological performance, in particular to improve anti-friction and anti-wear performance on metal parts. A corresponding lubricant composition contains these nanoparticle compositions.

公开(公告)号：US11746173B2

公开(公告)日：2023-09-05

申请号：US17423360

申请日：2020-08-18

Applicant: LG Chem, Ltd.

Inventor： Sang Il Nam ,  Ki Hyun Yoo ,  Yoon Ho Kim

IPC: C08L51/04 ,  C08F236/10 ,  C08F279/06 ,  C08L27/06

CPC classification number: C08F236/10 ,  C08F279/06 ,  C08L27/06 ,  C08L2207/53

Abstract: Provided is a core-shell copolymer, and in particular, a core-shell copolymer including a core and a shell surrounding the core, wherein the core includes a conjugated diene monomer-derived repeating unit, an aromatic vinyl monomer-derived repeating unit, and an aromatic (meth)acrylate monomer-derived repeating unit, the shell includes an alkyl (meth)acrylate monomer-derived repeating unit, an aromatic vinyl monomer-derived repeating unit, and an aromatic (meth)acrylate monomer-derived repeating unit, the core has a particle size of 800 Å to 900 Å, the core-shell copolymer has a particle size of 900 Å to 1000 Å, the core has a refractive index of 1.5355 to 1.5425, and the core-shell copolymer has a refractive index of 1.5415 to 1.5440.

公开(公告)号：US20180187003A1

公开(公告)日：2018-07-05

申请号：US15833335

申请日：2017-12-06

Applicant: Lotte Advanced Materials Co., Ltd.

Inventor： HyukJin Jung ,  Myeonghwan Kim ,  Seungshik Shin

IPC: C08L69/00 ,  C08L55/02 ,  C08L51/04 ,  C08L27/12 ,  C08K5/00 ,  C08K5/521 ,  C08F257/02 ,  C08F279/04 ,  C08F279/06

CPC classification number: C08L69/00 ,  C08F257/02 ,  C08F279/04 ,  C08F279/06 ,  C08F2800/20 ,  C08K5/0066 ,  C08K5/521 ,  C08L27/12 ,  C08L51/04 ,  C08L55/02 ,  C08L2201/02 ,  C08L2205/03 ,  C08L2666/84 ,  C08K5/523 ,  C08L25/12

Abstract: A resin composition that can exhibit good heat resistance and/or insulation properties includes (A) a polycarbonate resin, (B) a vinyl-based copolymer, (C) a fluorinated polyolefin and (D) a phosphorus-based flame retardant represented by Chemical Formula 1: wherein, in Chemical Formula 1, R6, R7, R9 and R10 are the same or different and are each independently a C6 to C20 aryl group or C1 to C14 alkyl-substituted C6 to C20 aryl group, R8 is biphenyl, and n is an integer ranging from 1 to 5.

公开(公告)号：US09068036B2

公开(公告)日：2015-06-30

申请号：US13325762

申请日：2011-12-14

Applicant: Christophe Navarro ,  Stephane Girois ,  Elisabeth Bay ,  Jean-Claude Saint-Martin

Inventor： Christophe Navarro ,  Stephane Girois ,  Elisabeth Bay ,  Jean-Claude Saint-Martin

IPC: C08L51/00 ,  C08F285/00 ,  C08F2/22 ,  C08F6/00 ,  C08F6/22 ,  C08F279/06 ,  C08L67/02 ,  C08L69/00

CPC classification number: C08F285/00 ,  C08F2/22 ,  C08F6/006 ,  C08F6/22 ,  C08F279/06 ,  C08L51/003 ,  C08L67/02 ,  C08L69/00 ,  C08F212/36 ,  C08F212/08 ,  C08F220/12

Abstract: The present invention relates to a process for producing impact modifiers, impact modified thermoplastic molding compositions and in particular impact modified polycarbonate or polycarbonate/polyester blends having improved resistance to degradation. More particularly the present invention relates to a process for producing polymeric impact modifiers with a core-shell structure made by a multistage process comprising a control and adjustment if necessary of the pH value before and during the recovery step.

Abstract translation: 本发明涉及一种生产抗冲改性剂，抗冲改性热塑性成型组合物的方法，特别涉及具有改进的降解抗性的抗冲改性聚碳酸酯或聚碳酸酯/聚酯共混物。 更具体地说，本发明涉及一种制备具有由多级方法制成的核 - 壳结构的聚合物抗冲改性剂的方法，包括在恢复步骤之前和期间必要时控制和调节pH值。

公开(公告)号：US20150065651A1

公开(公告)日：2015-03-05

申请号：US14394703

申请日：2013-03-17

Applicant: KANEKA CORPORATION

Inventor： Seigo Takamido ,  Toyohisa Fujimoto

IPC: C08F279/06 ,  C08L69/00

CPC classification number: C08F279/06 ,  C08F6/22 ,  C08F279/02 ,  C08L67/02 ,  C08L69/00 ,  C08L2205/03 ,  C08L2207/53 ,  C08L51/04 ,  C08F212/08 ,  C08F220/14 ,  C08F220/32 ,  C08F220/18

Abstract: The present invention relates to a thermoplastic resin composition comprising a rubber graft copolymer comprising a core layer containing a rubber copolymer and a shell layer grafted on the core layer and a thermoplastic resin comprising a polycarbonate resin and an aliphatic polyester resin in the mass ratio of the rubber graft copolymer/the thermoplastic resin of 3/100 or more, wherein the shell layer is obtained by polymerizing or copolymerizing a (meth)acrylate monomer having an epoxy group, and the amount of the (meth)acrylate monomer having an epoxy group is 3 parts by mass or more and less than 29 parts by mass based on 100 parts by mass of the rubber graft copolymer. The thermoplastic resin composition of the present invention can be utilized in various applications.

Abstract translation: 本发明涉及一种热塑性树脂组合物，其包含橡胶接枝共聚物，该橡胶接枝共聚物包含含有橡胶共聚物的芯层和接枝在芯层上的壳层，以及包含聚碳酸酯树脂和脂族聚酯树脂的热塑性树脂，其质量比为 橡胶接枝共聚物/ 3/100以上的热塑性树脂，其中壳层通过聚合或共聚具有环氧基的（甲基）丙烯酸酯单体而得到，并且具有环氧基的（甲基）丙烯酸酯单体的量为 相对于100质量份橡胶接枝共聚物，为3质量份以上且小于29质量份。 本发明的热塑性树脂组合物可用于各种应用。

公开(公告)号：US20080249214A1

公开(公告)日：2008-10-09

申请号：US10570474

申请日：2004-09-01

Applicant: Alex Wegmann ,  Pascal Xanthopoulos

Inventor： Alex Wegmann ,  Pascal Xanthopoulos

IPC: C08K5/3492 ,  C08K5/05 ,  C08K5/36

CPC classification number: C08K5/372 ,  C08F257/02 ,  C08F279/02 ,  C08F279/06 ,  C08K5/13 ,  C08K5/34924 ,  C08K5/375 ,  C08L51/04 ,  C08L55/02 ,  C08L2201/06 ,  C08L2666/02

Abstract: The instant invention relates to a stabilized composition of methylmethacrylate-butadiene-styrene graft copolymers with selected sterically hindered phenolic antioxidants and thioethers. Further subjects of the invention are a process for the stabilization of methylmethacrylate-butadiene-styrene graft copolymers and the use of selected sterically hindered phenolic antioxidants together with a thioether for the thermal stabilization of said graft copolymer.

Abstract translation: 本发明涉及一种稳定的甲基丙烯酸甲酯 - 丁二烯 - 苯乙烯接枝共聚物与选定的空间位阻酚类抗氧化剂和硫醚的组合物。 本发明的其它主题是使甲基丙烯酸甲酯 - 丁二烯 - 苯乙烯接枝共聚物稳定化的方法，以及选择的空间位阻酚类抗氧化剂与硫醚一起用于所述接枝共聚物的热稳定化。

公开(公告)号：US07393896B2

公开(公告)日：2008-07-01

申请号：US10407362

申请日：2003-04-04

Applicant: James L. DeRudder ,  Robert R. Gallucci

Inventor： James L. DeRudder ,  Robert R. Gallucci

IPC: C08G63/48 ,  C08K3/04

CPC classification number: C08L67/02 ,  C08F279/02 ,  C08F279/04 ,  C08F279/06 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  Y10S525/902 ,  C08L2666/14 ,  C08L2666/02 ,  C08L51/00 ,  C08L2666/24

Abstract: An aromatic carbonate polymer composition having improved thermal stability consisting of an aromatic carbonate polymer such as a polycarbonate or polycarbonate/polyester blend and an impact modifier which is free of alkali materials which catalytically degrade a polycarbonate. Also an impact modifier which is preferably of a shell-core structure prepared by the emulsion polymerization process and has a pH of about 3 to about 8. A preferred emulsifier is an alkyl sulfonate having an alkyl group of C6-C18 carbons.

Abstract translation: 具有由芳族碳酸酯聚合物如聚碳酸酯或聚碳酸酯/聚酯共混物组成的具有改进的热稳定性的芳族碳酸酯聚合物组合物和不含催化降解聚碳酸酯的碱性材料的抗冲改性剂。 还有一种抗冲改性剂，其优选是通过乳液聚合方法制备并具有约3至约8的pH的壳芯结构。优选的乳化剂是具有C6-C18碳烷基的烷基磺酸盐。

公开(公告)号：US20030203990A1

公开(公告)日：2003-10-30

申请号：US10407362

申请日：2003-04-04

Applicant: General Electric Co.

Inventor： James L. DeRudder ,  Robert R. Gallucci

IPC: C08L051/08

CPC classification number: C08L67/02 ,  C08F279/02 ,  C08F279/04 ,  C08F279/06 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  Y10S525/902 ,  C08L2666/14 ,  C08L2666/02 ,  C08L51/00 ,  C08L2666/24

Abstract: An aromatic carbonate polymer composition having improved thermal stability consisting of an aromatic carbonate polymer such as a polycarbonate or polycarbonate/polyester blend and an impact modifier which is free of alkali materials which catalytically degrade a polycarbonate. Also an impact modifier which is preferably of a shell-core structure prepared by the emulsion polymerization process and has a pH of about 3 to about 8. A preferred emulsifier is an alkyl sulfonate having an alkyl group of C6-C18 carbons.

Abstract translation: 具有由芳族碳酸酯聚合物如聚碳酸酯或聚碳酸酯/聚酯共混物组成的改进的热稳定性的芳族碳酸酯聚合物组合物和不含催化降解聚碳酸酯的碱性材料的抗冲改性剂。 还有一种抗冲改性剂，其优选是通过乳液聚合方法制备并具有约3至约8的pH的壳芯结构。优选的乳化剂是具有C6-C18碳烷基的烷基磺酸盐。

公开(公告)号：US20020099236A1

公开(公告)日：2002-07-25

申请号：US09915065

申请日：2001-07-25

Inventor： Jose M. Rego ,  Ludo Aerts ,  Duane B Priddy ,  Mehmet Demirors

IPC: C07C055/00 ,  C07C069/34

CPC classification number: C08F212/04 ,  C08F279/02 ,  C08F279/06 ,  C08L51/04 ,  C08F212/00

Abstract: The present invention relates to a polymer produced by polymerizing a vinyl aromatic monomer in the presence of a small amount of furfuryl (alkyl)acrylate.

Abstract translation: 本发明涉及通过在少量糠基（烷基）丙烯酸酯存在下使乙烯基芳族单体聚合而制备的聚合物。

公开(公告)号：US5268430A

公开(公告)日：1993-12-07

申请号：US760721

申请日：1991-09-16

Applicant: I-Chung W. Wang

Inventor： I-Chung W. Wang

IPC: C08F279/00 ,  C08F279/06 ,  C08F285/00 ,  C08L27/06 ,  C08L51/04 ,  C08F279/02

CPC classification number: C08F285/00 ,  C08F279/06 ,  C08L27/06 ,  C08L51/04 ,  Y10S525/902

Abstract: Multi-stage rubber-based MBS resin compositions are provided which include a polymeric substrate stage of a conjugated diolefin-based polymer or copolymer and optional units derived from a cross-linking agent or agents, and at least one polymeric graft stage graft polymerized in the presence of the substrate stage which include monomers of an acrylate, a vinyl aromatic, or a mixture of those monomers and optional units derived from a cross-linking agent or agents and/or units which serve as a graft-linking agent or agents wherein the weight ratio of acrylate in all graft stages combined to vinyl aromatic in all graft stages combined is at least 1.2:1. Additionally, modified vinyl chloride polymer compositions which include a vinyl chloride polymer or copolymer in combination with an impact modifying, yellowness index improving amount of the multi-stage rubber-based resin compositions above are provided. These modified vinyl chloride polymer compositions have a low yellowness index, good clarity, and desirable impact properties. Finally, processes for the production of the above compositions are provided.