摘要:
Provided are an aqueous bicomponent baking type automobile finishing varnish with improved acid etching resistance and preparation method thereof, the aqueous bicomponent baking type automobile finishing varnish consisting of component A and component B; component A and component B both consist of a methylacrylate monomer, an acrylate monomer, a non-acrylate monomer, an acrylic monomer, a hydroxyl-containing acrylate monomer, and a chain transfer agent. The preparation method comprises: mixing component A and component B respectively with all the starting materials to prepare a solute, adding a solvent, uniformly mixing to obtain a solution, then adding an initiator to cause a solution polymerization reaction, lastly adding a neutralizer and adjusting to a desired level of neutralization, giving an aqueous acrylic resin A and an aqueous acrylic resin B respectively, lastly mixing the two given substances, adding a crosslinking agent and then water to adjust to the desired viscosity, thus obtaining the product. The product has excellent overall performance, especially good acid etching resistance, and lower raw material prices, and is an environmentally-friendly aqueous finishing varnish.
摘要:
Provided are an aqueous bicomponent baking type automobile finishing varnish with improved acid etching resistance and preparation method thereof, the aqueous bicomponent baking type automobile finishing varnish consisting of component A and component B; component A and component B both consist of a methylacrylate monomer, an acrylate monomer, a non-acrylate monomer, an acrylic monomer, a hydroxyl-containing acrylate monomer, and a chain transfer agent. The preparation method comprises: mixing component A and component B respectively with all the starting materials to prepare a solute, adding a solvent, uniformly mixing to obtain a solution, then adding an initiator to cause a solution polymerization reaction, lastly adding a neutralizer and adjusting to a desired level of neutralization, giving an aqueous acrylic resin A and an aqueous acrylic resin B respectively, lastly mixing the two given substances, adding a crosslinking agent and then water to adjust to the desired viscosity, thus obtaining the product. The product has excellent overall performance, especially good acid etching resistance, and lower raw material prices, and is an environmentally-friendly aqueous finishing varnish.
摘要:
A free-radical polymerization process for making macromonomers having the structure: comprising contacting: (a) CH2═CHY; (b) optionally, CH2═CXB; and (c) free-radicals, produced from a free-radical source; in which B, U, X, Y, Z, m, n and p are defined in the text; macromonomer quality being controlled by adjusting one or more of the following variables: molar ratios of a, b and c; temperature; monomer concentration; and conversion.
摘要:
AQUEOUS DISPERSIONS OF VINYL ESTER POLYMERS HAVING A VISCOSITY INDEX OF NOT GREATER THAN ABOUT 1.8, AND A PROCESS FOR MAKING THEM, ARE PROVIDED. FILMS CAST FROM THESE DISPERSIONS POSSES GOOD WATER RESISTANCE AND STABILITY. THE DISPERSIONS CONTIN AS A PROTECTIVE COLLOID PARTIALLY HYDROLYZED POLYVINYL ALCOHOL, DERIVED FROM POLYVINYL ACETATE, HAVING AN AVERAGE VINYL ACETATE CONTENT OF 5 TO 7 MOLE PERCENT AND CONSISTING ESSENTIALLY OF PPOLYVINYL ALCOHOL MOLECULES ESSENTIALLY NONE OF WHICH CONTAINS MORE THAN ABOUT 16 MOLE PERCENT VINYL ACETATE. THE POLYVINYL ALCOHOL MAY CONSIST OF A BLEND OF TWO OR MORE POLYVINYL ALCOHOLS EACH OF WHICH HAS AN EVERAGE POLYVINYL ACETATE CONTENT DIFFERENT FROM THE AVERAGE OF THE BLEND; HOWEVER, THE AVERAGE POLYVINYL ACETATE CONTENT OF ANY POLYVINYL ALCOHOL BLENDED SHOULD NOT EXCEED ABOUT 16 MOLE PERCENT.
摘要:
There are provided an active energy ray-curable composition containing a polymerizable compound represented by General Formula (1), a polymerizable compound represented by General Formula (2), and a photopolymerization initiator, and an ink composition for inkjet recording use. CH2═CR1—CO—O—R2—O—CH═CH—R3 (1) (In Formula (1), R1 represents a hydrogen atom or a methyl group, R2 represents an organic residue having 2 to 20 carbon atoms, and R3 represents a hydrogen atom or an organic residue having 1 to 11 carbon atoms.) (In Formula (2), each of R4 and R5 independently represents a hydrogen atom or a methyl group, each of R6a, R6b, and R6c independently represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms, and m+n represents an integer of 0 to 4.).
摘要:
A method for preparing a main chain scission-type polysilyl (meth)acrylate resin and application thereof. The method comprises: a cyclic monomer, vinyl monomer and vinyl silyl ester monomer are mixed in a solvent at a formulation ratio, then added a composite initiator in a mass percentage of 0.01-5% based on the total amount of the monomers, and reacted at a temperature of 25-150° C., and under the protection of argon or nitrogen gas, so as to prepare the main chain scission-type polysilyl (meth)acrylate resin, wherein the monomers are consisted of 5-95% by mass of cyclic monomer, 0-90% by mass of vinyl monomer and 5-95% by mass of vinyl silyl ester monomer. The resulting resin can not only be hydrolyzed on the side chain silyl ester segment under the effect of the sea water, but also occur chain scission on the main chain polyester segment under the effect of the seawater, so as to solve the dependency of the traditional self-polishing material on the sailing speed, effectively control the release of the antifouling agent at a constant rate, ensure the active substance preserved on the coating surface of the ships, and properly meet the antifouling requirements on the low sailing speed ships, submarines and off-shore oil platform facilities.
摘要:
An alkaline soluble resin, a process for preparing the same, and a photoresist composition containing the same. The alkaline soluble resin is a polyether chain-containing acrylate alkaline soluble resin. A photoresist composition comprising said alkaline soluble resin can reduce the slope angle of the film layer and prevent gaps which cause light leakage from forming in the junction between the colored film layer and the black matrix. Moreover, the coating and the rubbing effect of the orientation layer can be improved.
摘要:
Dental cement composition comprising a polymerizable polyacidic polymer having repeating units in the polymer backbone, which are represented by the following formula (I)1 (II), and/or (III): wherein X represents O, S, or NR′, whereby R′ represents a hydrogen atom or a straight or branched C1-C6 alkyl group, C3-C6 cycloalkyl group, or C4-C8 cycloalkylalkyl group, Y a group of the following formula (IV), wherein each of L1, L2, L3 and L4, which are independent from each other represents a single bond, a straight or branched C1-C6 alkylene group, a straight or branched C1-C6 alkenylene, or a straight or branched C1-C20 alkylene group which includes 1 to 8 atoms selected from oxygen and sulfur atoms, X′ represents O, S, or NR″, whereby R″ represents a hydrogen atom or a straight or branched C1-C6 alkyl group, C3-C6 cycloalkyl group, or C4-C8 cycloalkylalkyl group, m is 0 to 3, and n is 1 to 3.
摘要:
An object of the present invention is to provide a dispersion stabilizer for suspension polymerization which satisfies various performance requirements for suspension polymerization of a vinyl-based compound such as vinyl chloride. The present invention relates a modified vinyl alcohol-based polymer having at least one monomer unit represented by a following general formula (I) and a modification rate of from 0.01 mol % to 10 mol %:general formula (1): in which BO represents an oxybutylene unit; EO represents an oxyethylene unit; and each of m and n is a number of repeating unit of the respective oxyalkylene units; 1≤m≤10; and 1≤n≥60.
摘要:
A modified PVA that enables formation of a film superior in cold water solubility, mechanical strength, and chemical resistance is provided. The modified PVA comprises a monomer unit represented by formula (I), and a structural unit represented by formula (II): wherein: a content of the monomer unit (I) is from 0.05 mol % to 10 mol %, and a content of the structural unit (II) is from 0.001 mol % to 0.5 mol % with respect to the total monomer units in the modified PVA; a viscosity average degree of polymerization is from 300 to 3,000; and a degree of saponification is from 82 mol % to 99.5 mol %. In the formula (I): R1 represents a hydrogen atom, or a methyl group; and R2 represents —R3—SO3−X+, —R3—N+(R4)3Cl−, or a hydrogen atom, R3 representing an alkanediyl group, X+ representing a hydrogen atom, a metal atom, or an ammonium group, and R4 representing an alkyl group.