公开(公告)号：US20140100339A1

公开(公告)日：2014-04-10

申请号：US14101820

申请日：2013-12-10

申请人： JSR CORPORATION ,  BRIDGESTONE CORPORATION

发明人： Yoichi OZAWA ,  H. Jerrold MILLER ,  Koji MASAKI ,  Koichi MORITA ,  Tatsuo FUJIMAKI ,  Tetsuyo OHUMURA ,  Takuo SONE ,  Iwakazu HATTORI

IPC分类号： C08F136/06

CPC分类号： C08F136/14 ,  C08C19/00 ,  C08C19/22 ,  C08C19/44 ,  C08F36/04 ,  C08F136/06 ,  C08K3/04 ,  C08K3/045 ,  C08K3/36 ,  C08L21/00 ,  C08L91/00 ,  C08F4/545 ,  C08L15/00

摘要： In general the present invention provides a functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with a functionalizing agent defined by the formula (I) A-R1—Z  (I) where R1 is a divalent bond or divalent organic group comprising from 0 to about 20 carbon atoms, A is a substituent that will undergo an addition reaction with a pseudo-living polymer, and Z is a substituent that will react or interact with silica or carbon black reinforcing fillers, with the proviso that A, R1, and Z are substituents that will not protonate a pseudo-living polymer.

摘要翻译： 通常本发明提供一种官能化聚合物，该方法包括以下步骤：通过使共轭单体与镧系元素类催化剂聚合制备假活性聚合物，并使假活性聚合物与由式（ I）A-R1-Z（I）其中R1是包含0至约20个碳原子的二价键或二价有机基团，A是将与假活性聚合物进行加成反应的取代基，Z是 将与二氧化硅或炭黑增强填料反应或相互作用的取代基，条件是A，R1和Z是不会使假活性聚合物质子化的取代基。

公开(公告)号：US08362126B2

公开(公告)日：2013-01-29

申请号：US12644382

申请日：2009-12-22

申请人： Yoichi Ozawa ,  H. Jerrold Miller ,  Koji Masaki ,  Koichi Morita ,  Tatsuo Fujimaki ,  Tetsuya Omura ,  Takuo Sone ,  Iwakazu Hattori

发明人： Yoichi Ozawa ,  H. Jerrold Miller ,  Koji Masaki ,  Koichi Morita ,  Tatsuo Fujimaki ,  Tetsuya Omura ,  Takuo Sone ,  Iwakazu Hattori

IPC分类号： C08K5/13 ,  C08F36/00

CPC分类号： C08F136/14 ,  C08C19/00 ,  C08C19/22 ,  C08C19/44 ,  C08F36/04 ,  C08F136/06 ,  C08K3/04 ,  C08K3/045 ,  C08K3/36 ,  C08L21/00 ,  C08L91/00 ,  C08F4/545 ,  C08L15/00

摘要： A method for preparing a functionalized polymer comprising the steps of preparing a polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, wherein the lanthanide-based catalyst comprises (a) a lanthanide compound, (b) an alkylating agent, and (c) a source of halogen, and reacting the pseudo-living polymer with at least one amide-containing functionalizing agent.

摘要翻译： 一种制备官能化聚合物的方法，包括以下步骤：通过使镧系元素基催化剂聚合共轭二烯单体来制备聚合物，其中所述镧系元素基催化剂包含（a）镧系元素化合物，（b）烷基化剂和（c ）卤素源，并使假活性聚合物与至少一种含酰胺官能化试剂反应。

公开(公告)号：US07642322B2

公开(公告)日：2010-01-05

申请号：US11216559

申请日：2005-08-31

申请人： Yoichi Ozawa ,  H. Jerrold Miller ,  Koji Masaki ,  Koichi Morita ,  Tatsuo Fujimaki ,  Tetsuya Omura ,  Takuo Sone ,  Iwakazu Hattori

发明人： Yoichi Ozawa ,  H. Jerrold Miller ,  Koji Masaki ,  Koichi Morita ,  Tatsuo Fujimaki ,  Tetsuya Omura ,  Takuo Sone ,  Iwakazu Hattori

IPC分类号： C08C19/34 ,  C08C19/22

CPC分类号： C08F136/14 ,  C08C19/00 ,  C08C19/22 ,  C08C19/44 ,  C08F36/04 ,  C08F136/06 ,  C08K3/04 ,  C08K3/045 ,  C08K3/36 ,  C08L21/00 ,  C08L91/00 ,  C08F4/545 ,  C08L15/00

摘要： A functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with a functionalizing agent defined by the formula (I) A-R1-Z  (I) where R1 is a divalent bond or divalent organic group comprising from 0 to about 20 carbon atoms, A is a substituent that will undergo an addition reaction with a pseudo-living polymer, and Z is a substituent that will react or interact with silica or carbon black reinforcing fillers, with the proviso that A, R1, and Z are substituents that will not protonate a pseudo-living polymer.

摘要翻译： 通过包括以下步骤制备的官能化聚合物的方法，所述方法包括通过使镧系元素类催化剂与共轭单体聚合制备假活性聚合物，并使假活性聚合物与式（I）A-R1- Z（I）其中R1是二价键或包含0至约20个碳原子的二价有机基团，A是将与假活性聚合物进行加成反应的取代基，Z是将反应或相互作用的取代基 具有二氧化硅或炭黑增强填料，条件是A，R 1和Z是不会使假活性聚合物质子化的取代基。

公开(公告)号：US12030965B2

公开(公告)日：2024-07-09

申请号：US17849485

申请日：2022-06-24

申请人： AGENCY FOR DEFENSE DEVELOPMENT

发明人： Byoung Sun Min ,  Jin Hyuk Lee ,  Hong Min Shim ,  Sungjune Kim ,  Minhye Lee

IPC分类号： C08F136/14

CPC分类号： C08F136/14

摘要： Provided are a modified conjugated diene-based polymer comprising a conjugated diene-based monomer-derived repeating unit; and a chain extender-derived part which is linked to both terminals of the conjugated diene based monomer-derived repeating unit, respectively, includes one or more urethane groups in a molecular chain, and has different functional groups at both terminals, wherein one of the functional groups is an alkyne group, wherein a terminal of the chain extender-derived part which is not linked to both terminals of the conjugated diene based monomer-derived repeating unit is an alkyne group, a manufacturing method thereof, a binder composition for a solid propellant comprising the same, a modified conjugated diene based binder for a solid propellant, and a manufacturing method thereof.

公开(公告)号：US20230312784A1

公开(公告)日：2023-10-05

申请号：US18155927

申请日：2023-01-18

申请人： The Goodyear Tire & Rubber Company

发明人： Margaret Flook Vielhaber ,  Thomas Franklin Spilker

IPC分类号： C08F136/14 ,  C08K3/36 ,  B60C1/00

CPC分类号： C08F136/14 ,  C08K3/36 ,  B60C1/0016

摘要： A hydrogenated functionalized polymer obtained by selectively hydrogenating functionalized elastomer double bonds to a predetermined level of saturation, wherein the functionalized elastomer is a reaction product of a living elastomeric polymer and a polymerization terminator of formula I




wherein R1 is C1 to C4 linear alkyl, or C1 to C4 branched alkanediyl; X1, X2, X3 are independently O, S, or a group of formula (II) or (III)




where R2 is C1 to C18 linear or branched alkyl; Z is —R3—X4; R3 is C1 to C18 alkanediyl or dialkyl ether diyl; X4 is a group that is able to react with a pseudo-living chain end.

公开(公告)号：US20230272131A1

公开(公告)日：2023-08-31

申请号：US17849485

申请日：2022-06-24

申请人： AGENCY FOR DEFENSE DEVELOPMENT

发明人： Byoung Sun MIN ,  Jin Hyuk LEE ,  Hong Min SHIM ,  Sungjune KIM ,  Minhye LEE

IPC分类号： C08F136/14

CPC分类号： C08F136/14

摘要： Provided are a modified conjugated diene-based polymer comprising a conjugated diene-based monomer-derived repeating unit; and a chain extender-derived part which is linked to both terminals of the conjugated diene based monomer-derived repeating unit, respectively, includes one or more urethane groups in a molecular chain, and has different functional groups at both terminals, wherein one of the functional groups is an alkyne group, wherein a terminal of the chain extender-derived part which is not linked to both terminals of the conjugated diene based monomer-derived repeating unit is an alkyne group, a manufacturing method thereof, a binder composition for a solid propellant comprising the same, a modified conjugated diene based binder for a solid propellant, and a manufacturing method thereof.

公开(公告)号：US20170043303A1

公开(公告)日：2017-02-16

申请号：US14826338

申请日：2015-08-14

申请人： UT-Battelle, LLC ,  University of Tennessee Research Foundation

发明人： Tao HONG ,  Sabornie CHATTERJEE ,  Shannon Mark MAHURIN ,  Brian Keith LONG ,  De-en JIANG ,  Jimmy Wayne MAYS ,  Alexei P. SOKOLOV ,  Tomonori SAITO

IPC分类号： B01D71/70 ,  C08F136/14 ,  B01D53/22

CPC分类号： B01D71/70 ,  B01D53/22 ,  B01D53/228 ,  B01D67/0006 ,  B01D2256/10 ,  B01D2257/504 ,  B01D2323/30 ,  C08F136/14 ,  C08F2500/25 ,  C08G77/28 ,  C09D183/08 ,  Y02C10/10 ,  Y02P20/152

摘要： A membrane useful in gas separation, the membrane comprising a cross-linked polysiloxane structure having a cross-link density of about 0.1×10−5 mol/cm3 to about 6×10−5 mol/cm3, where, in particular embodiments, the cross-linked polysiloxane structure has the following general structure: wherein R1, R2, R3, R4, R5, and R6 are independently selected from hydrocarbon groups having at least 1 and up to 6 carbon atoms; A1 and A2 are independently selected from cyclic hydrocarbon groups; L1 and L2 are linking groups or covalent bonds; n is an integer of at least 1; r and s are independently selected from integers of at least 1; and p is an integer of at least 10. The invention also includes methods for making and using the above-described membranes for gas separation.

摘要翻译： 其中R1，R2，R3，R4，R5和R6独立地选自具有至少1个和至多6个碳原子的烃基; A1和A2独立地选自环状烃基; L1和L2是连接基团或共价键; n为至少1的整数; r和s独立地选自至少1的整数; p为至少10的整数。本发明还包括制备和使用上述用于气体分离的膜的方法。

公开(公告)号：US08921502B2

公开(公告)日：2014-12-30

申请号：US13517151

申请日：2010-12-20

申请人： Sven Thiele ,  Sascha Rulhoff ,  Susanne Knoll

发明人： Sven Thiele ,  Sascha Rulhoff ,  Susanne Knoll

IPC分类号： C08F36/04 ,  C08C19/44 ,  C08F236/14 ,  C08F4/48 ,  C08L9/00 ,  C08L9/06 ,  C08F136/14 ,  B60C1/00

CPC分类号： C08F236/14 ,  B60C1/00 ,  C08C19/44 ,  C08F4/48 ,  C08F36/04 ,  C08F136/14 ,  C08L9/00 ,  C08L9/06 ,  C08L2205/02 ,  C08L2314/00 ,  Y10T428/139

摘要： The invention provides a first composition comprising at least the following: i) a modified polymer comprising at least one branched modified polymer macromolecule (b1) and at least one linear modified polymer macromolecule (a1), and wherein the at least one branched modified polymer macromolecule and the at least one linear modified polymer macromolecule each, independently, comprises at least one amine group selected from the group consisting of formulas (1A-1F), each as described above: and combinations thereof; and wherein the at least one branched modified polymer macromolecule further comprises one of the structures (ib1-ib4) as described above, and the at least one linear modified polymer macromolecule further comprises one of the structures (iib1) as described above (see Formula 3A).

摘要翻译： 本发明提供了至少包含以下的第一组合物：i）包含至少一种支化改性聚合物高分子（b1）和至少一种线性改性聚合物高分子（a1）的改性聚合物，其中所述至少一种支化改性聚合物高分子 并且所述至少一种线性改性聚合物高分子各自独立地包含至少一种选自如上所述的式（1A-1F）的胺基团及其组合; 并且其中所述至少一种支化改性聚合物高分子还包含如上所述的结构（ib1-ib4）之一，并且所述至少一种线性改性聚合物高分子还包含如上所述的结构（iib1）之一（参见式3A ）。

公开(公告)号：US20130102736A1

公开(公告)日：2013-04-25

申请号：US13711701

申请日：2012-12-12

申请人： Yoichi OZAWA ,  H. Jerrold MILLER ,  Koji MASAKI ,  Koichi MORITA ,  Tatsuo FUJIMAKI ,  Tetsuyo OHUMURA ,  Takuo SONE ,  Iwakazu HATTORI

发明人： Yoichi OZAWA ,  H. Jerrold MILLER ,  Koji MASAKI ,  Koichi MORITA ,  Tatsuo FUJIMAKI ,  Tetsuyo OHUMURA ,  Takuo SONE ,  Iwakazu HATTORI

IPC分类号： C08C19/22

CPC分类号： C08F136/14 ,  C08C19/00 ,  C08C19/22 ,  C08C19/44 ,  C08F36/04 ,  C08F136/06 ,  C08K3/04 ,  C08K3/045 ,  C08K3/36 ,  C08L21/00 ,  C08L91/00 ,  C08F4/545 ,  C08L15/00

摘要： A method for preparing a functionalized polymer comprising the steps of preparing a polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, wherein the lanthanide-based catalyst comprises (a) a lanthanide compound, (b) an alkylating agent, and (c) a source of halogen, and reacting the pseudo-living polymer with at least one amide-containing functionalizing agent.

摘要翻译： 一种制备官能化聚合物的方法，包括以下步骤：通过使镧系元素基催化剂聚合共轭二烯单体来制备聚合物，其中所述镧系元素基催化剂包含（a）镧系元素化合物，（b）烷基化剂和（c ）卤素源，并使假活性聚合物与至少一种含酰胺官能化试剂反应。

公开(公告)号：US3277067A

公开(公告)日：1966-10-04

申请号：US10147561

申请日：1961-04-07

申请人： MONTEDISON SPA

发明人： GIULIO NATTA ,  MARIO FARINA ,  MARIO DONATI

IPC分类号： C08F36/00 ,  C08F36/04 ,  C08F136/14 ,  C08F236/04

CPC分类号： C08F36/04 ,  C08F36/00 ,  C08F136/14 ,  C08F236/04