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13 条记录 (耗时 0.017 秒)

    Process for producing trimethylbenzene
    4.
    发明授权
    Process for producing trimethylbenzene 失效
    生产三甲苯的方法

    公开(公告)号：US4899004A

    公开(公告)日：1990-02-06

    申请号：US242110

    申请日：1988-09-09

    申请人： Joe D. Allison ,  Richard M. Tillman

    发明人： Joe D. Allison ,  Richard M. Tillman

    IPC分类号： C07C2/00 ,  C07C2/48 ,  C07C15/02

    CPC分类号： C07C15/02 ,  C07C2/00 ,  C07C2/48 ,  C07C2529/10 ,  C07C2529/16

    摘要： Trimethylbenzene is selectively prepared by contacting a C.sub.1 to C.sub.4 alkane with magnesium under reaction conditions to produce a reaction product. The reaction product thus produced, is contacted with water or a lower alcohol to promote a protonolysis reaction. The reaction mixture or a fraction thereof from the protonolysis reaction is contacted with a metal containing Y zeolite catalyst under reaction conditions to produce trimethylbenzene.

    摘要翻译： 通过在反应条件下使C1至C4烷烃与镁接触以选择性制备三甲基苯以产生反应产物。 由此制得的反应产物与水或低级醇接触以促进质子分解反应。 在反应条件下，使来自质子解反应的反应混合物或其一部分与含金属的Y沸石催化剂接触以产生三甲基苯。

    Process for the disproportionation and transalkylation of toluene and heavy aromatics
    5.
    发明申请
    Process for the disproportionation and transalkylation of toluene and heavy aromatics 有权
    甲苯和重芳烃的歧化和烷基转移的方法

    公开(公告)号：US20040186332A1

    公开(公告)日：2004-09-23

    申请号：US10392457

    申请日：2003-03-19

    申请人： China Petroleum & Chemical Corporation ,  Shanghai Research Institute of Petrochemical Technology Sinopec

    发明人： Dejin Kong ,  Deqin Yang ,  Huaying Li ,  Hongli Guo ,  Tian Ruan

    IPC分类号： C07C005/22

    CPC分类号： C07C6/126 ,  C07C6/123 ,  C07C2523/18 ,  C07C2523/28 ,  C07C2529/10 ,  C07C2529/16 ,  C07C2529/20 ,  C07C2529/26 ,  C07C2529/72 ,  C07C2529/78

    摘要： A process for the disproportionation and transalkylation of toluene and the heavy aromatics comprises subjecting a first stream of toluene, and a stream enriched in aromatics of nine carbon atoms to toluene disproportionation and transalkylation reactions in the presence of hydrogen in a first reaction zone to produce a first product mixture comprising benzene, aromatics of eight carbon atoms and heavy aromatics of ten and more carbon atoms; subjecting a second stream of toluene, and a stream enriched in heavy aromatics of ten and more carbon atoms to transalkylation reaction in the presence of hydrogen in a second reaction zone to produce a second product mixture comprising benzene, aromatics of eight carbon atoms and aromatics of nine carbon atoms; and isolating and recovering benzene and aromatics of eight carbon atoms from the first and second product mixtures.

    摘要翻译： 用于甲苯和重芳烃的歧化和烷基转移的方法包括在第一反应区中在氢存在下使第一甲苯流和富含九个碳原子的芳族化合物的物流进行甲苯歧化和烷基转移反应，以产生 包含苯，八个碳原子的芳烃和十个或更多个碳原子的重芳烃的第一产物混合物; 使第二个甲苯流和富含十个或更多个碳原子的重芳烃的物流在第二反应区的氢气存在下进行烷基转移反应，以产生包含苯，八个碳原子的芳烃和芳烃的第二产物混合物 九个碳原子; 并从第一和第二产物混合物中分离和回收八个碳原子的苯和芳族化合物。

    Process for alkylation-transalkylation of aromatic hydrocarbons by means of methanol
    7.
    发明授权
    Process for alkylation-transalkylation of aromatic hydrocarbons by means of methanol 失效
    通过甲醇烷基化 - 芳烃的烷基转移方法

    公开(公告)号：US4112008A

    公开(公告)日：1978-09-05

    申请号：US782880

    申请日：1977-03-30

    申请人： Christian Marcilly

    发明人： Christian Marcilly

    IPC分类号： C07C2/66 ,  B01J29/00 ,  B01J29/10 ,  C07B61/00 ,  C07C1/00 ,  C07C2/86 ,  C07C6/12 ,  C07C15/02 ,  C07C67/00 ,  C07C3/52 ,  C07C3/62

    CPC分类号： C07C2/864 ,  B01J29/106 ,  C07C6/126 ,  C07C2529/10 ,  C07C2529/14 ,  Y02P20/52

    摘要： Process for alkylating or alkylating-transalkylating a charge containing toluene, methanol and, optionally, polymethylbenzenes, in one or two steps, conducted at a temperature from 100.degree. to 600.degree. C under a pressure from 1 to 150 bars in the presence of hydrogen and of a catalyst having a zeolite base of the faujasite type selected from Y sieves containing less than 2% by weight of sodium and at least 0.5% by weight of nickel, silver, cadmium or a mixture thereof and in which the molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 is from 2 to 6, and also in the presence of sulfur either introduced into the charge or preintroduced into the catalyst or both.

    摘要翻译： 在一个或两个步骤中，在100℃至600℃的温度下，在氢气存在下，在1至150巴的压力下，对含有甲苯，甲醇和任选的聚甲基苯的电荷进行烷基化或烷基化 - 烷基化 - 具有选自含有小于2重量％的钠和至少0.5重量％的镍，银，镉或其混合物的Y筛的八面沸石沸石基质的催化剂，其中SiO 2 / Al 2 O 3的摩尔比 为2〜6，也可在硫的存在下引入电荷或预先引入催化剂或两者。

    Isoparaffin-olefin alkylation utilizing crystalline aluminosilicate catalyst in an adsorption zone
    8.
    发明授权
    Isoparaffin-olefin alkylation utilizing crystalline aluminosilicate catalyst in an adsorption zone 失效
    在吸附区使用结晶硅铝酸盐催化剂的异链烷烃烯烃烷基化

    公开(公告)号：US3917738A

    公开(公告)日：1975-11-04

    申请号：US47041374

    申请日：1974-05-16

    申请人： UNIVERSAL OIL PROD CO

    发明人： FENSKE ELLSWORTH R ,  ANDERSON ROBERT F

    IPC分类号： C07C2/58 ,  C07C3/52

    CPC分类号： C07C2/58 ,  C07C2529/10

    摘要： A process for alkylating an isoparaffin with an olefin using a solid, particulate catalyst capable of adsorbing the olefin. The isoparaffin and the olefin are admixed to form a reactants stream in contact with catalyst particles at the upstream end of an adsorption zone; the reactants stream and catalyst particles are passed cocurrently through the adsorption zone without back mixing, at controlled relative velocities, so that a controlled amount of olefin is adsorbed onto the catalyst and removed from the reactants stream as the catalyst and hydrocarbons are passed cocurrently through the adsorption zone; reactants stream and catalyst particles having olefin adsorbed thereon are withdrawn from the downstream end of the adsorption zone and contacted in an alkylation reaction zone to alkylate the isoparaffin with previously adsorbed olefin; and the alkylation reaction product is recovered from the hydrocarbon effluent from the alkylation zone.

    摘要翻译： 使用能够吸附烯烃的固体颗粒催化剂用烯烃烷基化异链烷烃的方法。 将异链烷烃和烯烃混合以在吸附区的上游端形成与催化剂颗粒接触的反应物流; 反应物流和催化剂颗粒在受控的相对速度下并流通过吸附区，而不受反相混合的影响，使得受控量的烯烃吸附到催化剂上并从反应物流中除去，因为催化剂和烃通过并流通过 吸附区; 从吸附区的下游端排出具有吸附有烯烃的反应物料流和催化剂颗粒，并在烷基化反应区中与预先吸附的烯烃烷基化异构烷烃; 并从烷基化区的烃流出物回收烷基化反应产物。

    Process for the disproportionation and transalkylation of toluene and heavy aromatics
    10.
    发明授权
    Process for the disproportionation and transalkylation of toluene and heavy aromatics 有权
    甲苯和重芳烃的歧化和烷基转移的方法

    公开(公告)号：US07109389B2

    公开(公告)日：2006-09-19

    申请号：US10392457

    申请日：2003-03-19

    申请人： Dejin Kong ,  Deqin Yang ,  Huaying Li ,  Hongli Guo ,  Tian Ruan

    发明人： Dejin Kong ,  Deqin Yang ,  Huaying Li ,  Hongli Guo ,  Tian Ruan

    IPC分类号： C07C5/22

    CPC分类号： C07C6/126 ,  C07C6/123 ,  C07C2523/18 ,  C07C2523/28 ,  C07C2529/10 ,  C07C2529/16 ,  C07C2529/20 ,  C07C2529/26 ,  C07C2529/72 ,  C07C2529/78

    摘要： A process for the disproportionation and transalkylation of toluene and the heavy aromatics comprises: subjecting a first stream of toluene, and a stream enriched in aromatics of nine carbon atoms to toluene disproportionation and transalkylation reactions in the presence of hydrogen in a first reaction zone to produce a first product mixture comprising benzene, aromatics of eight carbon atoms and heavy aromatics of ten and more carbon atoms; subjecting a second stream of toluene, and a stream enriched in heavy aromatics of ten and more carbon atoms to transalkylation reaction in the presence of hydrogen in a second reaction zone to produce a second product mixture comprising benzene, aromatics of eight carbon atoms and aromatics of nine carbon atoms; and isolating and recovering benzene and aromatics of eight carbon atoms from the first and second product mixtures.

    摘要翻译： 用于甲苯和重芳族化合物的歧化和烷基转移的方法包括：在第一反应区中使氢气的第一甲苯流和富含九个碳原子的芳烃的物流进行甲苯歧化和烷基转移反应以产生 包含苯，八个碳原子的芳烃和十个或更多个碳原子的重芳烃的第一产物混合物; 使第二个甲苯流和富含十个或更多个碳原子的重芳烃的物流在第二反应区的氢气存在下进行烷基转移反应，以产生包含苯，八个碳原子的芳烃和芳烃的第二产物混合物 九个碳原子; 并从第一和第二产物混合物中分离和回收八个碳原子的苯和芳族化合物。