Production of saturated ammonia storage materials
    7.
    发明授权
    Production of saturated ammonia storage materials 有权
    生产饱和氨储存材料

    公开(公告)号:US08084008B2

    公开(公告)日:2011-12-27

    申请号:US12576582

    申请日:2009-10-09

    CPC classification number: C01C1/006 C01F5/30 C01F11/24

    Abstract: A process for saturating a material capable of binding ammonia by ad- or absorption and initially free of ammonia or partially saturated with ammonia comprises treating said material under a pressure and associated temperature located on the vapor pressure curve of ammonia with an amount of liquid ammonia sufficient to saturate said material and an additional amount of a cooling agent selected from liquid ammonia, liquid or solid CO2, hydrocarbons and hydrohalocarbons that have a higher vapor pressure than ammonia, ethyl ether, methyl formate, methyl amine and ethyl amine, such that |Qabs|≦|Qevap|+Qext, wherein Qabs is the amount of heat released from said material when it absorbs ammonia from the liquid phase thereof to the point where it is saturated with ammonia, Qevap is the amount of heat absorbed by said cooling agent when it evaporates, and Qext is the amount of heat exchanged with the surroundings and is positive, if heat is removed from the process by external cooling, and negative, if heat is added to the process from the surroundings.

    Abstract translation: 使能够通过吸收和吸收结合氨并且最初不含氨或部分被氨饱和的材料饱和的材料的方法包括在氨的蒸气压曲线下的压力和相关温度下处理所述材料,其量足够的液氨 使所述材料饱和并加入选自液氨,液态或固体二氧化碳,碳氢化合物和氢卤素的冷却剂,其蒸汽压高于氨,乙醚,甲酸甲酯,甲胺和乙胺,使得| Qabs |≦̸ | Qevap | + Qext,其中Q abs是当从其液相吸收氨到其被氨饱和的点时从所述材料释放的热量,Qevap是由所述冷却剂吸收的热量 当它蒸发时,并且Qext是与周围环境交换的热量并且是正的,如果通过外部冷却从该过程中除去热量,以及 如果从周围环境中加热加热,则为负值。

    Process for the production of calcium bromide by liquid-liquid extraction
    8.
    发明授权
    Process for the production of calcium bromide by liquid-liquid extraction 有权
    通过液 - 液萃取生产溴化钙的方法

    公开(公告)号:US07452520B2

    公开(公告)日:2008-11-18

    申请号:US10469015

    申请日:2002-02-21

    CPC classification number: C01F5/30 C01F5/36 C01F11/24

    Abstract: A process for the production of calcium bromide from feed brines, particularly from Dead Sea End Brine (EB), is described. The process comprises extracting the feed brine in countercurrent with a composite organic solvent; optionally, purifying the extract to increase the ratio Br:Cl by contacting it with a part of the product; and washing the purified extract with water to yield the product, that is an aqueous solution of CaBr2. The composite solvent comprises an anionic extractant, such as an amine or a mixture of amines; a cationic extractant, such as a carboxylic phosphoric or sulphonic acid or a mixtures of said acids; and diluent/modifier, which is an organic solvent. An apparatus for the production of calcium bromide is also described, which comprises: an extraction battery; optionally, a purification battery; and a washing battery, wherein at least one of the batteries comprises a plurality of stages.

    Abstract translation: 描述了从进料盐水,特别是死海盐水(EB)生产溴化钙的方法。 该方法包括将进料盐水与复合有机溶剂逆流萃取; 任选地,纯化提取物以通过使其与一部分产物接触来增加Br:Cl的比例; 并用水洗涤纯化的提取物,得到产物,即CaBr 2水溶液。 复合溶剂包括阴离子萃取剂,例如胺或胺的混合物; 阳离子萃取剂,例如羧酸或磺酸或所述酸的混合物; 和稀释剂/改性剂,它是一种有机溶剂。 还描述了用于生产溴化钙的设备,其包括:提取电池; 任选地,净化电池; 以及洗涤电池,其中所述电池中的至少一个包括多个级。

    Synthetic ocean salt
    9.
    发明申请
    Synthetic ocean salt 审中-公开
    合成海洋盐

    公开(公告)号:US20050193956A1

    公开(公告)日:2005-09-08

    申请号:US11062885

    申请日:2005-02-22

    Abstract: The present invention is directed at a marine salt composition, suitable for simulating the marine environment, which composition comprises sodium chloride, magnesium chloride, anhydrous sodium sulfate, calcium chloride, potassium chloride, sodium bicarbonate and boric acid. The composition is substantially free of nitrate, nitrite, ammonia and phosphate ions. The magnesium chloride is present at 15-40 mesh and the calcium chloride is present at 20-50 mesh.

    Abstract translation: 本发明涉及适用于模拟海洋环境的海盐组合物,该组合物包含氯化钠,氯化镁,无水硫酸钠,氯化钙,氯化钾,碳酸氢钠和硼酸。 该组合物基本上不含硝酸盐,亚硝酸盐,氨和磷酸盐离子。 氯化镁以15-40目存在,氯化钙以20-50目存在。

    Method of recovering fumed silica from spent potliner
    10.
    发明授权
    Method of recovering fumed silica from spent potliner 失效
    从废锅炉回收热解法二氧化硅的方法

    公开(公告)号:US06193944B1

    公开(公告)日:2001-02-27

    申请号:US09298087

    申请日:1999-04-22

    Abstract: Spent potliner from an aluminum reduction cell is subject to an acid digest and the digest may be adjusted to produce a first gas component comprised of at least one material selected from the group consisting of silicon tetrafluoride, hydrogen fluoride, hydrogen cyanide gas and water vapor, and a slurry component comprised of at least one material selected from the group consisting of carbon, silica, alumina, and sodium, iron, calcium and magnesium compounds. The first gas component is removed from the digester and heated to a temperature sufficiently high to convert said silicon tetrafluoride to fumed silica and hydrogen fluoride. Thereafter, the fumed silica is separated from the hydrogen fluoride to recover fumed silica from spent potliner material.

    Abstract translation: 来自铝还原池的废碱浆料经受酸消化,并且可以调节消化物以产生由选自四氟化硅,氟化氢,氰化氢气体和水蒸气中的至少一种材料组成的第一气体组分, 以及由选自碳,二氧化硅,氧化铝和钠,铁,钙和镁化合物中的至少一种材料组成的浆料组分。 将第一气体组分从蒸煮器中取出并加热至足够高的温度,以将所述四氟化硅转化成热解法二氧化硅和氟化氢。 此后,将热解二氧化硅从氟化氢中分离出来,从废弃的废料中回收煅制二氧化硅。

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