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公开(公告)号：US12049408B2
公开(公告)日：2024-07-30
申请号：US16571414
申请日：2019-09-16
Applicant: TerraPower, LLC
Inventor： Brian C. Kelleher
Abstract: This document describes a method for reducing the corrosivity of certain magnesium salts. The salt product resulting from the method exhibits reduced corrosion of steels that come into contact with the salt relative to salt compositions that are not so treated. This makes such treated salts more efficient coolant salts as they will require less equipment replacement over time. The method uses magnesium metal to reduce unwanted impurities in the salts the reduced impurities are then removed as either gas or precipitate from the now purified salt. Without being bound to one particular theory, it is believed that the reduction of the level of impurities in the salt results in a salt with substantially reduced corrosiveness to steel.
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2.发明申请
公开(公告)号：US20180327273A1
公开(公告)日：2018-11-15
申请号：US15776810
申请日：2016-12-05
Applicant: NOVA Chemicals (International) S.A.
Inventor： Peter Zoricak , Qinyan Wang , Holly Ann Severin , Mohamed Elamine Aiffa , Kevin Dickinson
IPC: C01F5/30 , B01J27/138 , B01J21/06 , B01J37/02 , B01J19/18 , C08F4/659 , C08F4/655 , C08F10/02 , C08F210/16
CPC classification number: C01F5/30 , B01J19/18 , B01J21/063 , B01J27/138 , B01J37/0207 , B01J2219/00481 , C01P2002/72 , C08F4/655 , C08F4/65916 , C08F10/02 , C08F210/16 , C08F210/14 , C08F2500/03 , C08F4/6555 , C08F4/6546
Abstract: The various embodiments of the invention provide, a magnesium dichloride support and the magnesium titanium polymerization procatalyst made therefrom, and methods for making and using the same.
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公开(公告)号：US09889421B2
公开(公告)日：2018-02-13
申请号：US13579864
申请日：2011-02-04
Applicant: Bryn Harris , Carl White
Inventor： Bryn Harris , Carl White
IPC: B01J14/00 , C01B13/36 , C01F5/30 , C01F7/34 , C01G49/06 , C01G51/08 , C01G53/09 , C01G1/02 , C01G1/06 , C01G3/05 , C01B7/03
CPC classification number: B01J14/00 , B01J2219/00006 , B01J2219/00108 , C01B7/03 , C01B7/035 , C01B13/36 , C01F5/30 , C01F7/34 , C01G1/02 , C01G1/06 , C01G3/05 , C01G49/06 , C01G51/085 , C01G53/09 , C22B3/02 , C22B3/10 , C22B3/44 , C23G1/36 , Y02P10/234
Abstract: A method for recovering hydrochloric acid and metal oxides from a chloride liquor is described. The method uses a chloride liquor including the metal and mixing the liquor and a matrix solution to produce a reaction mixture, wherein the matrix solution assists oxidation/hydrolysis of the metal with HCl production. In a preferred embodiment the matrix solution includes zinc chloride in various stages of hydration and an oxygen containing gas is added to the mix. A method where the improvement is the mixing of a liquor and a matrix solution where the solution assists hydrolysis of the metal with HCl production is also disclosed. The reactor is a column reactor in a preferred embodiment. Further disclosed is the method of using the matrix solution and a reactor for recovering hydrochloric acid and for oxidizing/hydrolysis of a metal.
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公开(公告)号：US20170159190A1
公开(公告)日：2017-06-08
申请号：US15325843
申请日：2015-07-17
Applicant: ALLIANCE MAGNÉSIUM
Inventor： Joël FOURNIER , Laury GAUTHIER
CPC classification number: C25C1/02 , C01F5/30 , C01F5/32 , C01F11/462 , C01G53/003 , C01G53/04 , C21B15/00 , C22B3/10 , C22B3/22 , C22B3/44 , C22B23/0423 , C22B23/0469 , C22B26/22 , C25C3/04 , C25C7/025 , Y02P10/138 , Y02P10/234
Abstract: The present description relates to a process for producing magnesium metal from magnesium-bearing ores using serpentine. The process described herein consists generally in a mineral preparation and classification followed by leaching with dilute hydrochloric acid. The slurry is filtered and the non-leached portion, containing amorphous silica is recovered. The residual solution is neutralized and purified by chemical precipitation with non activated and activated serpentine. The nickel is also recovered by precipitation at higher pH. A final neutralisation and purification step of magnesium chloride solution by precipitation allows eliminating any traces of residual impurities. The purified magnesium chloride solution is evaporated until saturation and the MgCl2.6H2O is recovered by crystallization in an acid media. The salt is dehydrated and subsequent electrolysis of anhydrous magnesium chloride produces pure magnesium metal and hydrochloric acid.
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公开(公告)号：US20170152160A1
公开(公告)日：2017-06-01
申请号：US15128603
申请日：2015-01-04
Inventor： Panmin CAI
CPC classification number: C02F1/441 , B01D61/025 , B01D2311/08 , C01B7/096 , C01B35/121 , C01D3/06 , C01D3/10 , C01F5/30 , C02F2103/08 , Y02A20/131 , Y02W10/37 , B01D2311/26 , B01D2311/2669
Abstract: A process produces salt by way of strong brine concentration after sea water desalination by using a two-way circulation method and bromine extraction. The process includes the following steps: A, preparing fresh water and strong brine from sea water in a high-pressure reverse osmosis unit by using a reverse osmosis method, wherein the concentration of the prepared strong brine is 70000 to 80000 PPM; and B, performing fresh and concentrated separation on the strong brine with the concentration of 70000 to 80000 PPM in a two-way circulation manner by using a concentration difference method till the strong brine is crystallized.
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公开(公告)号：US20160318837A1
公开(公告)日：2016-11-03
申请号：US15210586
申请日：2016-07-14
Applicant: PURAC BIOCHEM BV
Inventor： Adriaan Dirk KON , André Banier DE HAAN , Paulus Loduvicus Johannes VAN DER WEIDE , Tanja ÐEKIC ZIVKOVIC , Lucien Henri Leander Jozef DE KONINCK
CPC classification number: C07C51/02 , B01J39/05 , B01J49/53 , C01B7/035 , C01F5/02 , C01F5/10 , C01F5/16 , C01F5/30 , C07C55/10 , C07C59/08 , C07C53/122 , C07C59/01 , C07C59/265 , C07C55/14 , C07C57/15 , C07C57/145 , C07C63/26 , C07C57/04
Abstract: The invention is directed to a method for recovering carboyxlic acid from an magnesium carboxylate containing aqueous mixture, including the steps of: contacting the aqueous mixture with an acidic ion exchanger, thereby forming a carboxylic acid mixture and an ion exchanger loaded with magnesium ions; contacting the ion exchanger loaded with magnesium ions with a hydrochloric acid solution, thereby forming a magnesium chloride solution; and thermally decomposing the magnesium chloride solution at a temperature of at least 300° C., thereby forming magnesium oxide (MgO) and hydrogen chloride (HCl).
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公开(公告)号：US09181603B2
公开(公告)日：2015-11-10
申请号：US14388285
申请日：2013-03-11
Applicant: ORBITE ALUMINAE INC.
Inventor： Richard Boudreault , Joël Fournier , Denis Primeau
IPC: A62D3/36 , C22B3/10 , C22B7/02 , C22B21/00 , C01F7/30 , A62D3/40 , C01F7/56 , C01F5/10 , C01F5/30 , C01F7/22 , C01F17/00 , C01D1/04 , C01B33/12 , C01G49/06 , C01G49/10 , A62D101/08
CPC classification number: C22B21/0023 , A62D3/36 , A62D3/40 , A62D2101/08 , A62D2203/02 , C01B33/126 , C01D1/04 , C01F5/10 , C01F5/30 , C01F7/22 , C01F7/306 , C01F7/56 , C01F17/0043 , C01G49/06 , C01G49/10 , C22B3/10 , C22B7/02 , C22B21/0007 , C22B26/10 , C22B26/22 , C22B59/00 , Y02C20/20 , Y02P10/146 , Y02P10/212 , Y02P20/129 , Y02W30/54
Abstract: There are provided processes for treating fly ash. For example, the processes can comprise leaching fly ash with HCl so as to obtain a leachate comprising aluminum ions and a solid, and separating the solid from the leachate; reacting the leachate with HCl so as to obtain a liquid and a precipitate comprising the aluminum ions in the form of AlCl3, and separating the precipitate from the liquid; and heating the precipitate under conditions effective for converting AlCl3 into Al2O3 and optionally recovering gaseous HCl so-produced.
Abstract translation: 提供了处理飞灰的方法。 例如，该方法可以包括用HCl浸出飞灰，以获得包含铝离子和固体的渗滤液，并将固体与渗滤液分离; 使渗滤液与HCl反应，以获得液体和包含AlCl 3形式的铝离子的沉淀物，并将沉淀物与液体分离; 并在有效将AlCl 3转化为Al 2 O 3的条件下加热沉淀物，并任选地回收如此生产的气态HCl。
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公开(公告)号：US20150075328A1
公开(公告)日：2015-03-19
申请号：US14388285
申请日：2013-03-11
Applicant: ORBITE ALUMINAE INC.
Inventor： Richard Boudreault , Joël Fournier , Denis Primeau
CPC classification number: C22B21/0023 , A62D3/36 , A62D3/40 , A62D2101/08 , A62D2203/02 , C01B33/126 , C01D1/04 , C01F5/10 , C01F5/30 , C01F7/22 , C01F7/306 , C01F7/56 , C01F17/0043 , C01G49/06 , C01G49/10 , C22B3/10 , C22B7/02 , C22B21/0007 , C22B26/10 , C22B26/22 , C22B59/00 , Y02C20/20 , Y02P10/146 , Y02P10/212 , Y02P20/129 , Y02W30/54
Abstract: There are provided processes for treating fly ash. For example, the processes can comprise leaching fly ash with HCl so as to obtain a leachate comprising aluminum ions and a solid, and separating the solid from the leachate; reacting the leachate with HCl so as to obtain a liquid and a precipitate comprising the aluminum ions in the form of AlCl3, and separating the precipitate from the liquid; and heating the precipitate under conditions effective for converting AlCl3 into Al2O3 and optionally recovering gaseous HCl so-produced.
Abstract translation: 提供了处理飞灰的方法。 例如，该方法可以包括用HCl浸出飞灰，以获得包含铝离子和固体的渗滤液，并将固体与渗滤液分离; 使渗滤液与HCl反应，以获得液体和包含AlCl 3形式的铝离子的沉淀物，并将沉淀物与液体分离; 并在有效将AlCl 3转化为Al 2 O 3的条件下加热沉淀物，并任选地回收如此生产的气态HCl。
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公开(公告)号：US20140357877A1
公开(公告)日：2014-12-04
申请号：US14238633
申请日：2012-08-16
Applicant: André Banier De Haan , Jan Van Breugel , Paulus Loduvicus Johannes Van Der Weide , Peter Paul Jansen , José María Vidal Lancis , Agustín Cerdà Baró
Inventor： André Banier De Haan , Jan Van Breugel , Paulus Loduvicus Johannes Van Der Weide , Peter Paul Jansen , José María Vidal Lancis , Agustín Cerdà Baró
IPC: C07C51/02 , C07C51/43 , C07D307/68
CPC classification number: C07C51/02 , C01B7/03 , C01B7/035 , C01F5/10 , C01F5/30 , C07C51/43 , C07D307/68 , C07C55/10
Abstract: A method for preparing a carboxylic acid, includes the steps of: providing magnesium carboxylate, wherein the carboxylic acid corresponding with the carboxylate is selected from the group made of 2,5-furandicarboxylic acid, fumaric acid, adipic acid, itaconic acid, citric acid, glutaric acid, maleic acid, malonic acid, oxalic acid and fatty acids having more than 10 carbon atoms; acidifying the magnesium carboxylate with hydrogen chloride (HCl), thereby obtaining a solution including carboxylic acid and magnesium chloride (MgCl2); optionally a concentration step, wherein the solution including carboxylic acid and MgCl2 is concentrated; and precipitating the carboxylic acid from the solution including the carboxylic acid and MgCl2, thereby obtaining a carboxylic acid precipitate and a MgCl2 solution.
Abstract translation: 一种制备羧酸的方法，包括以下步骤：提供羧酸镁，其中对应于羧酸酯的羧酸选自2,5-呋喃二羧酸，富马酸，己二酸，衣康酸，柠檬酸 戊二酸，马来酸，丙二酸，草酸和具有多于10个碳原子的脂肪酸; 用氯化氢（HCl）酸化羧酸镁，从而得到包括羧酸和氯化镁（MgCl 2）的溶液; 任选的浓缩步骤，其中将包含羧酸和MgCl 2的溶液浓缩; 并从包括羧酸和MgCl 2的溶液中沉淀出羧酸，从而得到羧酸沉淀和MgCl 2溶液。
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10.发明申请Magnesium dichloride-water adducts and catalyst components obtained therefrom 审中-公开二氯化镁 - 水加合物和由其获得的催化剂组分
公开(公告)号：US20120283402A1
公开(公告)日：2012-11-08
申请号：US13517036
申请日：2010-12-17
Applicant: Daniele Evangelisti , Benedetta Gaddi , Diego Brita , Gianni Collina , Anna Fait
Inventor： Daniele Evangelisti , Benedetta Gaddi , Diego Brita , Gianni Collina , Anna Fait
CPC classification number: C01F5/30 , C01P2006/14 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6543 , C08F4/6545 , C08F2500/12 , C08F2500/18 , C08F4/022
Abstract: Solid adducts comprising MgCl2 and water and optionally an organic hydroxy compound (A) selected from hydrocarbon structures containing at least one hydroxy group, said compounds being present in molar ratio defined by the following formula MgCl2.(H20)n(A)p in which n is from 0.6 to 6, p ranges from 0 to 3, said adduct having a porosity (PF), measured by the mercury method and due to pores with radius equal to or lower than 1 μm, of at least 0.15 cm3/g with the proviso that when p is 0, (PF) is equal to or higher than 0.3 cm3/g.
Abstract translation: 包含MgCl 2和水以及任选的选自含有至少一个羟基的烃结构的有机羟基化合物（A）的固体加合物，所述化合物以下式MgCl 2（H 2 O）n（A）p定义的摩尔比存在，其中 n为0.6至6，p为0至3，所述加合物具有通过汞法测量的孔隙度（PF），并且由于半径等于或小于1μm的孔隙至少为0.15cm 3 / g， 条件是当p为0时，（PF）等于或高于0.3cm 3 / g。
