Process for the selective absorption of anions
    1.
    发明授权
    Process for the selective absorption of anions 失效
    阴离子选择性吸收的方法

    公开(公告)号:US5187200A

    公开(公告)日:1993-02-16

    申请号:US808884

    申请日:1991-12-18

    申请人: Norman B. Rainer

    发明人: Norman B. Rainer

    IPC分类号: B01J41/08 B01J45/00 B01J47/00

    摘要: A process for selectively removing anions from an aqueous solution involves contacting the solution for an effective period of time with a specialized polymer in a porous format. The polymer has ligand sites capable of forming coordination or complexation bonds with multi-valent metal cations which serve to activate the polymer with respect to chemical interaction with anions. The polymer, saturated with the multivalent metal cations, contains between 2% and 20% of metal cation based upon the dry weight of the polymer.

    摘要翻译: 从水溶液中选择性地除去阴离子的方法包括使溶液与多孔形式的特殊聚合物接触有效的时间段。 该聚合物具有能够与多价金属阳离子形成配位或络合键的配体位点,其用于在与阴离子的化学相互作用下活化聚合物。 基于聚合物的干重,用多价金属阳离子饱和的聚合物含有2%至20%的金属阳离子。

    Porous substances having ion exchange properties
    2.
    发明授权
    Porous substances having ion exchange properties 失效
    具有离子交换性能的多孔物质

    公开(公告)号:US3969261A

    公开(公告)日:1976-07-13

    申请号:US486819

    申请日:1974-07-10

    申请人: Francois Meiller

    发明人: Francois Meiller

    CPC分类号: B01J41/085 Y10T428/31663

    摘要: An ion exchange substance formed of a porous mineral support having a specific surface area greater than 10 sq.m/g and an organo silicon compound containing at least one amine group in an organic group attached to the silicon atom grafted onto the porous mineral support via the silicon atom of the organo silicon compound and an oxygen group on the support and in which the terminal radicals on the amino group are alkyl groups having from 1 to 3 carbon atoms. SPECIFICATION

    摘要翻译: 由比表面积大于10平方米/克的多孔矿物载体形成的离子交换物质和在与硅原子连接的有机基团中含有至少一个胺基的有机硅化合物接枝到多孔矿物载体上经由 有机硅化合物的硅原子和载体上的氧基,氨基上的末端基团是具有1至3个碳原子的烷基。

    Ion exchange materials
    4.
    发明授权
    Ion exchange materials 失效
    离子交换材料

    公开(公告)号:US4130512A

    公开(公告)日:1978-12-19

    申请号:US659496

    申请日:1976-02-19

    申请人: Michael Streat

    发明人: Michael Streat

    摘要: A process for the production of a particulate ion exchange material which comprises heating an inorganic material to produce a porous inert inorganic substrate, adsorbing an organic monomer into the substrate and polymerizing the adsorbed monomer so that the resultant polymer is retained within the pores of the substrate, and, if necessary, introducing ion exchange functional groups into the polymer.

    摘要翻译: 一种生产颗粒状离子交换材料的方法,包括加热无机材料以制备多孔惰性无机基材,将有机单体吸附到基材中并聚合吸附的单体,使得所得聚合物保留在基材的孔内 ,如果需要,将离子交换官能团引入到聚合物中。

    Process for recovering silver from photographic chemical effluent
    5.
    发明授权
    Process for recovering silver from photographic chemical effluent 失效
    从摄影化学废液中回收银的工艺

    公开(公告)号:US5294652A

    公开(公告)日:1994-03-15

    申请号:US19287

    申请日:1993-02-18

    申请人: Norman B. Rainer

    发明人: Norman B. Rainer

    摘要: A process for absorbing silver from photographic hypo solutions involves passing the hypo solution through a bed consisting of a multitude of a sponge product confined within a vessel. The sponge product is derived from an open-celled cellulosic sponge into which there has been incorporated 30% to 80% by weight of a polymer produced by the thermal interaction of polyethyleneimine (PEI) with a polycarboxylic acid. The polymer further contains an activating multivalent cation and between 90% and 300% water. Silver is eluted from the sponge product employing aqueous solutions of a complexing agent such as an ammonium compound or a cyanide compound. Following a water wash, the bed of sponge product is ready for its next cycle of silver absorption.

    摘要翻译: 从照相底层溶液中吸收银的方法包括使次溶液通过由限制在容器内的大量海绵产品组成的床。 海绵产品来源于开孔的纤维素海绵,其中掺入30%至80%重量的通过聚乙烯亚胺(PEI)与多元羧酸的热相互作用产生的聚合物。 聚合物还含有活化多价阳离子和90%至300%的水。 使用络合剂如铵化合物或氰化物化合物的水溶液,从海绵产品中洗脱银。 水洗后,海绵产品床准备下一次银吸收循环。

    Process for insolubilizing absorbed metal ions
    7.
    发明授权
    Process for insolubilizing absorbed metal ions 失效
    不溶解吸收金属离子的方法

    公开(公告)号:US5336704A

    公开(公告)日:1994-08-09

    申请号:US17598

    申请日:1993-02-16

    申请人: Norman B. Rainer

    发明人: Norman B. Rainer

    摘要: Metal cations absorbed within a hydrogel chelation polymer are insolubilized for safe disposal by treating the polymer with a precipitative anion such as carbonate, aluminate, hydroxide, phosphate, silicate, or sulfide. Further insolubilization of the metal cations may be achieved by subsequent treatment of the polymer with a water-dilutable prepolymer composition such as phenol-formaldehyde resin, then heating to cause cross-linking of the prepolymer. The hydrogel chelation polymer, containing metal sulfide formed by virtue of the insolubilization process, is useful in abstracting from water metals whose sulfides are less soluble than the metal sulfide initially within the polymer.

    摘要翻译: 通过用沉淀阴离子例如碳酸盐,铝酸盐,氢氧化物,磷酸盐,硅酸盐或硫化物处理聚合物,在水凝胶螯合聚合物内吸收的金属阳离子不溶解以便安全处理。 金属阳离子的进一步不溶化可以通过用水可稀释的预聚物组合物如苯酚 - 甲醛树脂随后处理聚合物,然后加热以引起预聚物的交联来实现。 含有由于不溶化过程形成的金属硫化物的水凝胶螯合聚合物可用于从最初在聚合物内的金属硫化物的硫化物溶解度较低的水金属中提取。

    Process for the production of silicon dioxide ion exchangers
    10.
    发明授权
    Process for the production of silicon dioxide ion exchangers 失效
    生产二氧化硅离子交换剂的方法

    公开(公告)号:US3936388A

    公开(公告)日:1976-02-03

    申请号:US364116

    申请日:1973-05-25

    摘要: An improved process for the production of silicon dioxide ion exchangers, which comprises the step of reacting silicon dioxide with benzyltrichlorosilane, in the absence of solvent and air, followed by hydrolysis, to produce a benzylated silicon dioxide whose benzyl groups can then be substituted with ion exchange reactive groups in a conventional manner.

    摘要翻译: 一种用于生产二氧化硅离子交换剂的改进方法,其包括在不存在溶剂和空气的情况下使二氧化硅与苄基三氯硅烷反应,然后水解的步骤,以产生苄基化的二氧化硅,其苄基可以被离子 以常规方式交换反应性基团。