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公开(公告)号：US5905129A
公开(公告)日：1999-05-18
申请号：US809298
申请日：1997-03-27
摘要： A thermoplastic norbornene resin having a number-average molecular weight (Mn) of 12,000 or more in terms of polyisoprene value measured by gel permeation chromatography and excellent in low birefringence property and resistance to deterioration with greases and oils is obtained by ring-opening polymerizing a polycyclic norbornene monomer containing at least 70% by weight of a norbornene monomer represented by the following formula I (for example, 1,4-methano-1,4,4a,9a-tetrahydrofluorene): ##STR1## (wherein the lower 6-membered ring structure may have a double bond) and hydrogenating the polymer so that the hydrogenation rate of double bond in the main chain is at least 98% and the hydrogenation rate of the 6-membered ring structure is at least 90%.
摘要翻译： PCT No.PCT / JP95 / 01992 Sec。 371日期1997年3月27日 102（e）1997年3月27日PCT PCT 1995年9月29日PCT公布。 公开号WO96 / 10596 日期1996年4月11日按照通过凝胶渗透色谱法测定的以聚异戊二烯值计的数均分子量（Mn）为12000以上的热塑性降冰片烯系树脂，具有优异的低双折射性和耐油脂变质性，得到了 开环聚合含有至少70重量％由下式I表示的降冰片烯单体的多环降冰片烯单体（例如，1,4-亚甲基-1,4,4a，9a-四氢芴）：（其中下部 6元环结构可以具有双键）和氢化聚合物，使得主链中双键的氢化率至少为98％，并且6元环结构的氢化率至少为90％。
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公开(公告)号：US20140005338A1
公开(公告)日：2014-01-02
申请号：US14003504
申请日：2012-03-08
申请人： Akihiko Yoshiwara , Yasuo Tsunogae
发明人： Akihiko Yoshiwara , Yasuo Tsunogae
IPC分类号： C08F232/08
CPC分类号： C08F232/08 , C08G61/08 , C08G2261/3325 , C08G2261/418
摘要： A polymerizable composition which contains a cycloolefin monomer and a ruthenium carbene complex which is expressed by the following general formula (I): (in which general formula (I), R1 and R2 respectively independently represent a hydrogen atom, halogen atom, or cyclic or chain C1 to C20 hydrocarbon group which may contain a halogen atom, oxygen atom, nitrogen atom, sulfur atom, phosphorus atom, or silicon atom; X1 and X2 respectively independently represent an anionic ligand; L1 and L2 respectively independently represent a neutral electron donor ligand; L2 is a group with a higher three-dimensionally bulk than L1, where L1 and L2 are at cis positions with each other; R1 and R2 may bond with each other to form an aliphatic ring or aromatic ring which may contain a hetero atom; and R1, R2, X1, X2, L1, and L2 may bond with each other in any combination to form a multidentate chelating ligand).
摘要翻译： 含有由以下通式（I）表示的环烯烃单体和钌卡宾络合物的可聚合组合物（其中通式（I），R 1和R 2分别独立地表示氢原子，卤素原子或环状或 可以含有卤素原子，氧原子，氮原子，硫原子，磷原子或硅原子的C1〜C20烃链; X1和X2分别独立地表示阴离子配体; L1和L2分别独立地表示中性给电子体配体 ; L2是具有比L1更高的三维体积的基团，其中L1和L2彼此是顺式位置; R1和R2可以彼此键合以形成可以含有杂原子的脂族环或芳香环; 并且R1，R2，X1，X2，L1和L2可以以任何组合彼此键合形成多齿螯合配体）。
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公开(公告)号：US20090221750A1
公开(公告)日：2009-09-03
申请号：US11886727
申请日：2006-03-20
CPC分类号： C08G81/021 , C08G61/06 , C08G61/08
摘要： A thermoplastic resin comprising a block copolymer or a graft copolymer possessing (A) a crystalline hydrogenated norbornene ring-opening polymer unit and (B) a non-crystalline polymer unit having a glass transition temperature of 40 to 300° C.; A method for producing thermoplastic resin comprising hydrogenating a block copolymer or a graft copolymer possessing a norbornene ring-opening polymer unit (C) and a polymer unit (D) which is converted into the above-mentioned non-crystalline polymer unit (B) after hydrogenation, in the presence of a hydrogenation catalyst; and a molding material comprising the thermoplastic resin are provided. The thermoplastic resin of the present invention excels in transparency, heat resistance, and mechanical strength.
摘要翻译： 包含具有（A）结晶氢化降冰片烯开环聚合物单元的嵌段共聚物或接枝共聚物的热塑性树脂和（B）玻璃化转变温度为40〜300℃的非结晶性聚合物单元。 一种制备热塑性树脂的方法，包括将具有降冰片烯开环聚合物单元（C）的嵌段共聚物或接枝共聚物和聚合物单元（D）氢化，所述聚合物单元（D）经过转化成上述非晶态聚合物单元（B） 在氢化催化剂的存在下进行氢化; 并且提供包含热塑性树脂的成型材料。 本发明的热塑性树脂的透明性，耐热性和机械强度优异。
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4.发明申请Process for producing cycloolefin addition polymer, catalyst for addition polymerization of cycloolefin, and transition metal compound 有权环烯加成聚合物的制造方法，环烯烃的加成聚合用催化剂和过渡金属化合物公开(公告)号：US20090124769A1
公开(公告)日：2009-05-14
申请号：US12073704
申请日：2008-03-07
申请人： Kei Nishii , Sigetaka Hayano , Yasuo Tsunogae
发明人： Kei Nishii , Sigetaka Hayano , Yasuo Tsunogae
CPC分类号： C07F7/28 , C08F4/65912 , C08F4/6592 , C08F210/02 , Y10S526/943 , C08F232/00
摘要： A process for producing a cycloolefin addition polymer comprising addition-polymerizing a cycloolefin in the presence of a catalyst comprising a combination of a specific transition metal compound of Group 4 of the Periodic Table, with an organoaluminum oxy compound, and/or a compound capable of reacting with the Group 4 transition metal compound to form an ion pair. The specific group 4 transition metal compound preferably has a structure such that the group 4 transition metal is bonded to a cyclopentadienyl ring in an η1 mode. The above-mentioned catalyst exhibits high activity for both of addition homopolymerization of a cycloolefin and addition copolymerization of a cycloolefin with an α-olefin.
摘要翻译： 一种制备环烯加成聚合物的方法，包括在包含周期表第4族的特定过渡金属化合物与有机铝氧化合物的组合的催化剂存在下，将环烯加成聚合，和/或能够 与第4族过渡金属化合物反应形成离子对。 特别的第4族过渡金属化合物优选具有使第4族过渡金属以eta1模式键合到环戊二烯基环上的结构。 上述催化剂对于环烯烃的加成均聚和环烯烃与α-烯烃的加成共聚均显示出高活性。
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公开(公告)号：US06713154B1
公开(公告)日：2004-03-30
申请号：US09445310
申请日：1999-12-06
IPC分类号： B32B310
CPC分类号： B32B15/085 , B32B27/32 , B32B27/325 , B32B2307/204 , B32B2307/206 , B32B2307/306 , B32B2307/7265 , B32B2457/08 , H01B3/44 , H05K1/032 , Y10T428/24273 , Y10T428/24322 , Y10T428/3175
摘要： An insulating material comprising a cycloolefin polymer, specifically, an interlayer insulating material for a high-density assembly board having interlayer-connecting via holes at most 200 &mgr;m in diameter, comprising a cycloolefin polymer containing at least 50 mol % of a repeating unit derived from a cycloolefin monomer; a dry film formed from a curable resin composition comprising a polymer having a number average molecular weight within a range of 1,000 to 1,000,000 as measured by gel permeation chromatography, and a hardener; and a resin-attached metal foil obtained by forming a film of a cycloolefin polymer on one side of a metal foil. Laminates, multi-layer laminates and build-up multi-layer laminates making use of these materials, and production processes thereof.
摘要翻译： 一种包含环烯烃聚合物的绝缘材料，特别是用于高密度组装板的层间绝缘材料，其具有直径最大为200μm的夹层连接通孔，其包含含有至少50mol％重复单元的环烯烃聚合物 环烯烃单体; 由通过凝胶渗透色谱法测定的数均分子量在1,000〜1,000,000范围内的聚合物的固化性树脂组合物形成的干膜和硬化剂; 以及通过在金属箔的一面上形成环烯烃聚合物膜而获得的树脂附着金属箔。 使用这些材料的层压板，多层层压板和堆积多层层压板及其制造方法。
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公开(公告)号：US09045617B2
公开(公告)日：2015-06-02
申请号：US13521262
申请日：2011-01-14
申请人： Yasuo Tsunogae , Yoshihisa Takeyama
发明人： Yasuo Tsunogae , Yoshihisa Takeyama
IPC分类号： C08F232/04 , C08K3/04 , C08K3/36 , C08F4/78 , C08L7/00
CPC分类号： C08K3/04 , C08G2261/3321 , C08G2261/418 , C08K3/36 , C08L65/00
摘要： There is provided a ring-opening polymer of cyclopentene wherein a cis ratio of the cyclopentene-derived structural units is 30% or more, a weight average molecular weight (Mw) is 100,000 to 1,000,000, and a functional group containing a structure represented by the general formula (1) or (2) is included at an end of the polymer chain. —Y—H (1) (in the above general formula (1), Y represents an oxygen atom or a sulfur atom.) —NH-Q (2) (in the above general formula (2), Q represents a hydrogen atom or a hydrocarbon group or a silyl group which may have a substituent group.)
摘要翻译： 提供环戊烯的开环聚合物，其中环戊烯衍生的结构单元的顺式比例为30％以上，重均分子量（Mw）为100,000〜1,000,000，以及含有由 通式（1）或（2）包括在聚合物链的末端。 -Y-H（1）（在上述通式（1）中，Y表示氧原子或硫原子。）-NH-Q（2）（在上述通式（2）中，Q表示氢原子 或可以具有取代基的烃基或甲硅烷基。）
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公开(公告)号：US20090275719A1
公开(公告)日：2009-11-05
申请号：US12223324
申请日：2007-01-26
IPC分类号： C08F32/04
CPC分类号： C08J5/18 , B32B27/08 , B32B27/18 , B32B27/20 , B32B27/22 , B32B27/306 , B32B27/32 , B32B27/325 , B32B27/34 , B32B2255/10 , B32B2255/20 , B32B2307/202 , B32B2307/308 , B32B2307/40 , B32B2307/412 , B32B2307/714 , B32B2307/7242 , B32B2307/7265 , B32B2307/734 , B32B2457/202 , C08F232/08 , C08J2345/00 , Y10T428/10 , Y10T428/31938
摘要： [Problems] To provide a film comprising a norbornene (NB) compound addition polymer that is excellent in chemical resistance, optical properties and the like, has a high Tg, a low water absorption ratio and a low linear expansion coefficient, and is soluble in an ordinary solvent.[Means for Solving Problems] A film comprising a NB compound addition polymer essentially consisting of repeating units derived from NB compound monomers, wherein the addition polymer has a specific Mw and has a sum of the units (A1) and (A2) of 70% by mol or more based on the total units, wherein the molar number of each unit satisfies the following equations: 70/30≦[{(A1)+(A2)}/(B)]≦100 and 10/90≦(A1)/(A2)≦98/2, or the addition polymer has a specific Mw and Mn and essentially consists of the units (A1) and (B), wherein the molar number of each unit satisfies the following equation: 70/30≦[(A1)/(B)]≦98/2: (A1) a unit derived from a NB compound monomer (a1) consisting of carbon atoms and hydrogen atoms with all the carbon atoms being involved in constitution of a condensed ring skeleton; (A2) a unit derived from a monomer having a structure wherein a part of hydrogen atoms of the monomer (a1) is substituted with only a hydrocarbon group having 2 or less carbon atoms; and (B) a unit derived from a monomer having a structure wherein a part of hydrogen atoms of the monomer (a1) is substituted with only a functional group having 2 or less carbon atoms, or with only a functional group having 2 or less carbon atoms and a hydrocarbon group having 2 or less carbon atoms.
摘要翻译： [问题]为了提供具有耐化学性，光学特性等优异的降冰片烯（NB）化合物加成聚合物的膜，具有高Tg，低吸水率和低线膨胀系数，并且可溶于 普通溶剂。 解决问题的手段一种包含NB化合物加成聚合物的膜，其基本上由衍生自NB化合物单体的重复单元组成，其中加成聚合物具有特定的Mw，单元（A1）和（A2）之和为70％ 其中每个单位的摩尔数满足以下等式：70/30 <= [{（A1）+（A2）} /（B）] <= 100和10/90 < =（A1）/（A2）<= 98/2，或加成聚合物具有特定的Mw和Mn，并且基本上由单元（A1）和（B）组成，其中每个单元的摩尔数满足以下等式： 70/30 <= [（A1）/（B）] <= 98/2：（A1）衍生自由碳原子和氢原子构成的NB化合物单体（a1）的单元，其全部碳原子参与构成 的稠环骨架; （A2）来自具有单体（a1）的一部分氢原子仅被碳原子数2以下的烃基取代的单体的单元， 和（B）单体衍生自单体的单体，其中单体（a1）的一部分氢原子仅被碳原子数2以下的官能团取代，或者仅具有碳原子数为2以下的官能团 原子和碳原子数为2以下的烃基。
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8.发明申请Norbornene Compound Addition Polymer, Process for Producing the Same, Molded Article Comprised of the Polymer, and Use Thereof 审中-公开降冰片烯化合物加成聚合物，其制造方法，由聚合物组成的成型品及其用途公开(公告)号：US20090269601A1
公开(公告)日：2009-10-29
申请号：US11992307
申请日：2006-08-28
申请人： Atsushi Ishiguro , Shingo Okuno , Yasuo Tsunogae
发明人： Atsushi Ishiguro , Shingo Okuno , Yasuo Tsunogae
CPC分类号： G02B1/04 , C08F6/02 , C08F232/08 , Y10T428/31855 , C08L23/18 , C08L45/00
摘要： [PROBLEMS] To provide: a norbornene compound addition polymer which has excellent heat resistance and suffers no decrease in the excellent transparency and mechanical properties even when exposed to high temperatures during molding, processing, or use; and a process for producing the polymer.[MEANS FOR SOLVING PROBLEMS] The norbornene compound addition polymer comprises, as an essential ingredient, repeating structural units derived from a substituted norbornene compound monomer, wherein the total content of atoms of the transition metals in Group 10 of the Periodic Table, halogen atoms, phosphorus atoms, aluminum atoms, boron atoms, and sulfur atoms is 50 wt. ppm or lower. The process for producing a norbornene compound addition polymer comprises bringing a norbornene compound addition polymer comprising, as an essential ingredient, repeating structural units derived from a substituted norbornene compound monomer into contact with an ion-exchanging lamellar inorganic compound.
摘要翻译： 提供：即使在模塑，加工或使用中暴露于高温下，具有优异的耐热性也不会降低优异的透明性和机械性能的降冰片烯化合物加成聚合物; 和聚合物的制造方法。 解决问题的手段降冰片烯化合物加成聚合物作为必要成分，含有衍生自取代的降冰片烯化合物单体的重复结构单元，其中周期表第10族中的过渡金属的原子总量，卤素原子， 磷原子，铝原子，硼原子和硫原子为50重量％。 ppm以下。 制备降冰片烯化合物加成聚合物的方法包括使作为主要成分的降冰片烯化合物加成聚合物包含重复取代的降冰片烯化合物单体的结构单元与离子交换层状无机化合物接触。
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9.发明授权Norbornene ring-opened polymer hydrogenated product and process for producing same 有权降冰片烯开环聚合物氢化产物及其制备方法公开(公告)号：US07608671B2
公开(公告)日：2009-10-27
申请号：US10567964
申请日：2004-08-12
申请人： Shigetaka Hayano , Yasuo Tsunogae
发明人： Shigetaka Hayano , Yasuo Tsunogae
CPC分类号： C08G61/06 , C08G61/08 , C08G2261/3324 , C08G2261/3325 , C08G2261/418
摘要： A norbornene ring-opened polymer hydrogenated product having a syndiotactic structure and a process for producing the same are disclosed. The ring-opened polymer hydrogenated product contains a repeating unit originating from a polycyclic norbornene monomer with three or more rings in the polymer repeating units, having a weight average molecular weight of 500 to 1,000,000, and having a racemo diad proportion of 51% or more. The process comprises a step of polymerizing a polycyclic norbornene monomer having three or more rings by solution polymerization using a group 6 transition metal compound with a hydroxyl group-containing aryloxy group or the like bonded thereto as a polymerization catalyst to obtain a ring-opened polymer and a step of hydrogenating double bonds in the main chain of the ring-opened polymer.
摘要翻译： 公开了具有间同立构结构的降冰片烯开环聚合物氢化物及其制造方法。 开环聚合物氢化物含有在聚合物重复单元中具有三个以上环的多环降冰片烯单体的重复单元，其重均分子量为500〜1,000,000，并且具有51％以上的摩尔二烯比例 。 该方法包括通过溶液聚合将具有三个或更多个环的多环降冰片烯单体用作为聚合催化剂的含有含羟基的芳氧基等的第六族过渡金属化合物聚合，得到开环聚合物 以及在开环聚合物的主链中氢化双键的步骤。
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10.发明授权Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymer of cycloolefins and hydrogenation products thereof by using the complex as catalyst 失效钌络合物，其制备方法以及通过使用络合物作为催化剂制备环烯烃的开环聚合物及其氢化产物的方法公开(公告)号：US07084222B2
公开(公告)日：2006-08-01
申请号：US10489921
申请日：2002-09-19
申请人： Masato Sakamoto , Seiji Okada , Yasuo Tsunogae , Shintaro Ikeda , Wolfgang A. Herrmann , Karl Oefele
发明人： Masato Sakamoto , Seiji Okada , Yasuo Tsunogae , Shintaro Ikeda , Wolfgang A. Herrmann , Karl Oefele
CPC分类号： C07D239/04 , C07D233/02 , C07F15/0046 , C08G61/08
摘要： The present invention relates to ruthenium complex compound wherein a heteroatom-containing carbene compound having a six-membered ring structure is bonded to ruthenium and a process for the preparation thereof; a process for producing ring-opened cyclic olefin polymer by subjecting a cyclic olefin to ring-opening metathesis polymerization in the presence of such a ruthenium complex compound; and a process for producing hydrogenated product of ring-opened cyclic olefin polymers by hydrogenating the carbon-carbon double bonds of the above ring-opened polymers. The invention gives hydrogenated product of ring-opened cyclic olefin polymers having physical properties different from those of hydrogenated product of ring-opened polymers of the prior art. Particularly, the use of dicyclopentadiene can give a hydrogenated product of ring-opened cyclic olefin polymer excellent in heat resistance, and this product can be advantageously used as parts or formed products for medical appliances or electrical components.
摘要翻译： 本发明涉及具有六元环结构的含杂原子的卡宾化合物与钌结合的钌络合物及其制备方法， 在这种钌络合物的存在下，通过使环状烯烃进行开环易位聚合来制造开环式环烯烃聚合物的方法; 以及通过氢化上述开环聚合物的碳 - 碳双键来制备开环环烯烃聚合物的氢化产物的方法。 本发明提供了具有与现有技术的开环聚合物的氢化产物不同的物理性质的开环环烯烃聚合物的氢化产物。 特别地，二环戊二烯的使用可以得到耐热性优异的开环式环状烯烃聚合物的氢化物，该产品可有利地用作医疗器具或电子部件的部件或成形品。
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